Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-23T15:14:46.409Z Has data issue: false hasContentIssue false
  • English
  • Français

Effects of titanium addition on microstructure and mechanical properties of CrFeNiTix (x = 0.2–0.6) compositionally complex alloys

Published online by Cambridge University Press:  05 March 2019

Shuo Gao ,
Teng Kong ,
Man Zhang ,
Xiao Chen ,
Yan Wei Sui Open the ORCID record for Yan Wei Sui [Opens in a new window] ,
Yao Jian Ren ,
Ji Qiu Qi ,
Fu Xiang Wei ,
Ye Zeng He  and
Qing Kun Meng
...Show all authors
Shuo Gao
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China; Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipments, Xu’zhou 221116, China; and Xuzhou City Key Laboratory of High Efficient Energy Storage Technology and Equipments, China University of Mining and Technology, Xu’zhou 221116, China
Teng Kong
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Man Zhang
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Xiao Chen
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Yan Wei Sui*
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China; Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipments, Xu’zhou 221116, China; and Xuzhou City Key Laboratory of High Efficient Energy Storage Technology and Equipments, China University of Mining and Technology, Xu’zhou 221116, China
Yao Jian Ren
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Ji Qiu Qi
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Fu Xiang Wei
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Ye Zeng He
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Qing Kun Meng
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
Zhi Sun*
Affiliation:
School of Materials Science and Engineering, China University of Mining and Technology, Xu’zhou 221116, China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
Get access

Abstract

CrFeNiTix (x = 0.2, 0.3, 0.4, 0.5, and 0.6 molar ratio) compositionally complex alloys were fabricated by vacuum arc melting to investigate the microstructure, hardness, and compressive properties. The results revealed that CrFeNiTix alloys consisted of the principal face-centered cubic (FCC) phase and body-centered cubic (BCC) solid solution, with an amount of (Ni, Ti)-rich hexagonal close-packed phase. CrFeNiTix alloys exhibited the typical dendrite. Ti0.2 and Ti0.3 alloys were composed of FCC and BCC solid solutions in the dendrite, as well as ε (Ni3Ti) and R (Ni2.67Ti1.33) phases in the inter-dendrite, simultaneously. For Ti0.4, Ti0.5, and Ti0.6 alloys, (Fe, Cr)-rich solid solution separated out and ε phase transformed into R phase gradually. Meanwhile, TEM analysis indicated that Ti0.4 alloy matrix consisted of the principal FCC phase containing (Ni, Ti)-rich intragranular nanoprecipitates. The hardness values of CrFeNiTix alloys were increased with the addition of Ti content and the high compressive strength of CrFeNiTix alloys was maintained, which was attributed to the solid solution strengthening and precipitation hardening.

Keywords

high-entropy alloycompositionally complex alloytransmission electron microscopymechanical propertyphase transformationmicrostructure
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 5: Focus Issue: Nanocrystalline High Entropy Materials: Processing Challenges and Properties , 14 March 2019 , pp. 819 - 828
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Yeh, J.W., Chen, S.K., Lin, S.J., Gan, J.Y., Chin, T.S., Shun, T.T., Tsau, C.H., and Chang, S.Y.: Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299–303 (2004).CrossRefGoogle Scholar
Lu, Z.P., Wang, H., Chen, M.W., Baker, I., Yeh, J.W., Liu, C.T., and Nieh, T.G.: An assessment on the future development of high-entropy alloys: Summary from a recent workshop. Intermetallics 66, 67–76 (2015).CrossRefGoogle Scholar
Tsai, M. and Yeh, J.: High-entropy alloys: A critical review. Mater. Res. Lett. 2, 107–123 (2014).CrossRefGoogle Scholar
Yeh, J.W.: Recent progress in high-entropy alloys. Ann. Chimie Sci. Matér. 31, 633–648 (2006).CrossRefGoogle Scholar
Ma, S.G. and Zhang, Y.: Effect of Nb addition on the microstructure and properties of AlCoCrFeNi high-entropy alloy. Mater. Sci. Eng., A 532, 480–486 (2012).CrossRefGoogle Scholar
Gali, A. and George, E.P.: Tensile properties of high- and medium-entropy alloys. Intermetallics 39, 74–78 (2013).CrossRefGoogle Scholar
Chou, H., Chang, Y., Chen, S., and Yeh, J.: Microstructure, thermophysical and electrical properties in AlxCoCrFeNi (0 ≤ x ≤ 2) high-entropy alloys. Mater. Sci. Eng., B 163, 184–189 (2009).CrossRefGoogle Scholar
Zhang, Y., Zuo, T., Cheng, Y., and Liaw, P.K.: High-entropy alloys with high saturation magnetization, electrical resistivity, and malleability. Sci. Rep. 3, 1455 (2013).CrossRefGoogle ScholarPubMed
Liu, B., Wang, J., Liu, Y., Fang, Q., Wu, Y., Chen, S., and Liu, C.T.: Microstructure and mechanical properties of equimolar FeCoCrNi high entropy alloy prepared via powder extrusion. Intermetallics 75, 25–30 (2016).CrossRefGoogle Scholar
Qiu, Y., Hu, Y.J., Taylor, A., Styles, M.J., Marceau, R.K.W., Ceguerra, A.V., Gibson, M.A., Liu, Z.K., Fraser, H.L., and Birbilis, N.: A lightweight single-phase AlTiVCr compositionally complex alloy. Acta Mater. 123, 115–124 (2017).CrossRefGoogle Scholar
Daoud, H.M., Manzoni, A.M., Wanderka, N., and Glatzel, U.: High-temperature tensile strength of Al10Co25Cr8Fe15Ni36Ti6 compositionally complex alloy (high-entropy alloy). Acta Mater. 123, 115–124 (2017).Google Scholar
Jensen, J.K., Welk, B.A., Williams, R.E.A., Sosa, J.M., Huber, D.E., Senkov, O.N., Viswanathan, G.B., and Fraser, H.L.: Characterization of the microstructure of the compositionally complex alloy Al1Mo0.5Nb1Ta0.5Ti1Zr1. Scr. Mater. 121, 1–4 (2016).CrossRefGoogle Scholar
Dong, Y., Gao, X., Lu, Y., Wang, T., and Li, T.: A multi-component AlCrFe2Ni2 alloy with excellent mechanical properties. Mater. Lett. 169, 62–64 (2016).CrossRefGoogle Scholar
Lu, Y.P., Dong, Y., Guo, S., Jiang, L., Kang, H.J., Wang, T.M., Wen, B., Wang, Z.J., Jie, J.C., Cao, Z.Q., Ruan, H.H., and Li, T.J.: A promising new class of high-temperature alloys: Eutectic high-entropy alloys. Sci. Rep. 4, 6200 (2014).CrossRefGoogle ScholarPubMed
Senkov, O.N., Senkova, S.V., Miracle, D.B., and Woodward, C.: Mechanical properties of low-density, refractory multi-principal element alloys of the Cr–Nb–Ti–V–Zr system. Mater. Sci. Eng., A 565, 51–62 (2013).CrossRefGoogle Scholar
Senkov, O.N., Senkova, S.V., Woodward, C., and Miracle, D.B.: Low-density, refractory multi-principal element alloys of the Cr–Nb–Ti–V–Zr system: Microstructure and phase analysis. Acta Mater. 61, 1545–1557 (2013).CrossRefGoogle Scholar
Manzoni, A., Daoud, H., Völkl, R., Glatzel, U., and Wanderka, N.: Phase separation in equiatomic AlCoCrFeNi high-entropy alloy. Ultramicroscopy 132, 212–215 (2013).CrossRefGoogle ScholarPubMed
Dong, Y., Lu, Y., Kong, J., Zhang, J., and Li, T.: Microstructure and mechanical properties of multi-component AlCrFeNiMox high-entropy alloys. J. Alloys Compd. 573, 96–101 (2013).CrossRefGoogle Scholar
Jiang, L., Jiang, H., Lu, Y., Wang, T., Cao, Z., and Li, T.: Mechanical properties improvement of AlCrFeNi2Ti0.5 high entropy alloy through annealing design and its relationship with its particle-reinforced microstructures. J Mater Sci Technol 31, 397–402 (2015).CrossRefGoogle Scholar
Chen, X., Qi, J.Q., Sui, Y.W., He, Y.Z., Wei, F.X., Meng, Q.K., and Sun, Z.: Effects of aluminum on microstructure and compressive properties of Al–Cr–Fe–Ni eutectic multi-component alloys. Mater. Sci. Eng., A 681, 25–31 (2017).CrossRefGoogle Scholar
Ren, B., Liu, Z.X., Cai, B., Wang, M.X., and Shi, L.: Aging behavior of a CuCr2Fe2NiMn high-entropy alloy. Mater. Des. 33, 121–126 (2012).CrossRefGoogle Scholar
Tang, W.Y., Chuang, M.H., Chen, H.Y., and Yeh, J.W.: Microstructure and mechanical performance of new Al0.5CrFe1.5MnNi0.5 high-entropy alloys improved by plasma nitriding. Surf. Coat. Technol. 204, 3118–3124 (2010).CrossRefGoogle Scholar
Shun, T., Chang, L., and Shiu, M.: Microstructures and mechanical properties of multiprincipal component CoCrFeNiTix alloys. Mater. Sci. Eng., A 556, 170–174 (2012).CrossRefGoogle Scholar
Bellen, P., Kumar, K.C.H., and Wollants, P.: Thermodynamic assessment of the Ni–Ti phase diagram. Z. Metallkd. 87, 972–978 (1996).Google Scholar
Jiang, L., Lu, Y.P., Dong, Y., Wang, T.M., Cao, Z.Q., and Li, T.J.: Annealing effects on the microstructure and properties of bulk high-entropy CoCrFeNiTi0.5 alloy casting ingot. Intermetallics 44, 37–43 (2014).CrossRefGoogle Scholar
Tadashi, F., Hiroshi, S., Kosuke, K., Mamoru, H., Takahiko, K., Kenta, Y., Yuichiro, K., Akihiko, C., and Seiichi, W.: CoCrFeNiTi-based high-entropy alloy with superior tensile strength and corrosion resistance achieved by a combination of additive manufacturing using selective electron beam melting and solution treatment. Mater. Lett. 189, 148–151 (2017).Google Scholar
Sui, Y.W., Gao, S., Chen, X., Qi, J.Q., Yang, F., He, Y.Z., Wei, F.X., Meng, Q.K., and Sun, Z.: Microstructures and electrothermal properties of AlxCrFeNi multi-component alloys. Vacuum 144, 80–85 (2017).CrossRefGoogle Scholar
Hung, W.J., Shun, T.T., and Chiang, C.J.: Effects of reducing Co content on microstructure and mechanical properties of CoxCrFeNiTi0.3 high-entropy alloys. Mater. Chem. Phys. 210, 170–175 (2018).CrossRefGoogle Scholar
Senkov, O.N. and Miracle, D.B.: Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys. Mater. Res. Bull. 36, 2183–2198 (2001).CrossRefGoogle Scholar
Takeuchi, A. and Inoue, A.: Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater. Trans. 46, 2817–2829 (2005).CrossRefGoogle Scholar
Liu, S., Gao, M.C., Liaw, P.K., and Zhang, Y.: Microstructures and mechanical properties of AlxCrFeNiTi0.25 alloys. J. Alloys Compd. 619, 610–615 (2015).CrossRefGoogle Scholar
Wang, C.T.A.W.: Microstructures, hardness and corrosion behaviors of FeCoNiNb0.5Mo0.5 and FeCoNiNb high-entropy alloys. Materials 11, 16 (2018).Google Scholar
Wang, Y.P., Li, B.S., Ren, M.X., Yang, C., and Fu, H.Z.: Microstructure and compressive properties of AlCrFeCoNi high entropy alloy. Mater. Sci. Eng., A 491, 154–158 (2008).CrossRefGoogle Scholar
Wang, J., Guo, T., Li, J., Jia, W., and Kou, H.: Microstructure and mechanical properties of non-equilibrium solidified CoCrFeNi high entropy alloy. Mater. Chem. Phys. 210, 192–196 (2018).CrossRefGoogle Scholar
Zuo, T.T., Li, R.B., Ren, X.J., and Zhang, Y.: Effects of Al and Si addition on the structure and properties of CoFeNi equal atomic ratio alloy. J. Magn. Magn. Mater. 371, 60–68 (2014).CrossRefGoogle Scholar
Jiang, S., Lin, Z., Xu, H., and Sun, Y.: Studies on the microstructure and properties of AlxCoCrFeNiTi1−x high entropy alloys. J. Alloys Compd. 741, 826–833 (2018).CrossRefGoogle Scholar
Praveen, S., Murty, B.S., and Kottada, R.S.: Alloying behavior in multi-component AlCoCrCuFe and NiCoCrCuFe high entropy alloys. Mater. Sci. Eng., A 534, 83–89 (2012).CrossRefGoogle Scholar
Wang, X.F., Zhang, Y., Qiao, Y., and Chen, G.L.: Novel microstructure and properties of multicomponent CoCrCuFeNiTix alloys. Intermetallics 15, 357–362 (2007).CrossRefGoogle Scholar
Samih, Y., Marcos, G., Stein, N., Allain, N., Fleury, E., Dong, C., and Grosdidier, T.: Microstructure modifications and associated hardness and corrosion improvements in the AISI 420 martensitic stainless steel treated by high current pulsed electron beam (HCPEB). Surf. Coat. Technol. 259, 737–745 (2014).CrossRefGoogle Scholar