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Dielectric anomaly and magnetic response of epitaxial orthorhombic YMnO3 thin films

Published online by Cambridge University Press:  31 January 2011

X. Martí*
Affiliation:
Institut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Cientificas (CSIC), Campus UAB, Bellaterra 08193, Spain
V. Skumryev
Affiliation:
Institut Català de Recerca i Estudis Avançats (ICREA), Barcelona, Spain; and Departament de Física, Universitat Autònoma de Barcelona, Bellaterra 08193, Spain
V. Laukhin
Affiliation:
Institut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Cientificas (CSIC), Campus UAB, Bellaterra 08193, Spain; and Institut Català de Recerca i Estudis Avançats (ICREA), Barcelona, Spain
F. Sánchez
Affiliation:
Institut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Cientificas (CSIC), Campus UAB, Bellaterra 08193, Spain
M.V. García-Cuenca
Affiliation:
Departament de Física Aplicada I Óptica, Universitat de Barcelona, Diagonal 647, Barcelona 08028, Spain
C. Ferrater
Affiliation:
Departament de Física Aplicada I Óptica, Universitat de Barcelona, Diagonal 647, Barcelona 08028, Spain
M. Varela
Affiliation:
Departament de Física Aplicada I Óptica, Universitat de Barcelona, Diagonal 647, Barcelona 08028, Spain
J. Fontcuberta
Affiliation:
Institut de Ciència de Materials de Barcelona Consejo Superior de Investigaciones Cientificas (CSIC), Campus UAB, Bellaterra 08193, Spain
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The structure, magnetic response, and dielectric response of the grown epitaxial thin films of the orthorhombic phase of YMnO3 oxide on Nb:SrTiO3 (001) substrates have been measured. We have found that a substrate-induced strain produces an in-plane compression of the YMnO3 unit cell. The magnetization versus temperature curves display a significant zero-field cooling (ZFC)-field cooling hysteresis below the Néel temperature (TN ≈ 45 K). The dielectric constant increases gradually (up to 26%) below the TN and mimics the ZFC magnetization curve. We argue that these effects could be a manifestation of magnetoelectric coupling in YMnO3 thin films and that the magnetic structure of YMnO3 can be controlled by substrate selection and/or growth conditions.

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Articles
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Bertaut, E.F., Forrat, F.Fang, P.: A new class of ferroelectrics: Rare earth and yttrium manganites. Compt. Rend. 256, 1958 1963Google Scholar
2Pauthenet, R.Veyret, C.: Magnetostatic properties of rare earth manganites. J. Phys. E: Sci. Instrum. 31, 236 1965Google Scholar
3Kimura, T., Goto, T., Shintani, H., Ishizaka, K., Arima, T.Tokura, Y.: Magnetic control of ferroelectric polarization. Nature 426, 55 2003CrossRefGoogle ScholarPubMed
4Van Aken, B.B., Palstra, T.T.M., Filippetti, A.Spalding, N.A.: The origin of ferroelectricity in magnetoelectric YMnO3. Nat. Mater. 3, 164 2004CrossRefGoogle ScholarPubMed
5Mostovoy, M.: Ferroelectricity in spiral magnets. Phys. Rev. Lett. 96, 067601 2006CrossRefGoogle ScholarPubMed
6Wood, V.E., Austin, A.E.Collings, E.W.: Magnetic properties of heavy rare earth orthomanganites. J. Phys. Chem. Solids 34, 859 1973CrossRefGoogle Scholar
7Salvador, P.A., Doan, T.D., Mercey, B.Raveau, B.: Stabilization of YMnO3 in a perovskite structure as a thin film. Chem. Mater. 10, 2592 1998CrossRefGoogle Scholar
8Yu Gorbenko, O., Samoilenkov, S.V., Graboy, I.E.Kaul, A.R.: Epitaxial stabilization of oxides in thin films. Chem. Mater. 14, 4026 2002CrossRefGoogle Scholar
9Martí, X., Sánchez, F., Fontcuberta, J., García-Cuenca, M.V., Ferrater, C.Varela, M.: Exchange bias between magnetoelectric YMnO3 and ferromagnetic SrRuO3 epitaxial films. J. Appl. Phys. 99, 302 2006CrossRefGoogle Scholar
10Lorenz, B., Wang, Y.Q., Sun, Y.Y.Chu, W.: Large magnetodielectric effects in orthorhombic HoMnO3 and YMnO3. Phys. Rev. B 70, 212412 2004CrossRefGoogle Scholar
11Quezel, S., Rossat-Mignod, J.Bertaut, E.F.: Magnetic structure of rare earth orthomanganites: 1. YMnO3. Solid State Commun. 14, 941 1974CrossRefGoogle Scholar
12Muñoz, A., Alonso, J.A., Casais, M.T., Martínez-Lope, M.J., Martínez, J.L.Fernández-Díaz, M.T.: The magnetic structure of YMnO3 perovskite revisited. J. Phys.: Condens. Matter 14, 3285 2002Google Scholar
13Brinks, H.W., Rodríguez-Carvajal, J., Fjellvag, H., Kjekshus, A.Hauback, B.C.: Crystal and magnetic structure of orthorhombic HoMnO3. Phys. Rev. B 63, 094411 2001CrossRefGoogle Scholar
14Martí, X., Sánchez, F., Skumryev, V., Laukhin, V., García-Cuenca, M.V., Ferrater, C., Varela, M.Fontcuberta, J.: Crystal texture selection in epitaxies of orthorhombic antiferromagnetic YMnO3 films. Thin Solid Films, submitted for publicationGoogle Scholar
15Skumryev, V., Martí, X., Sánchez, F., Laukhin, V.Fontcuberta, J.: in preparationGoogle Scholar
16Nair, S.Banerjee, B.: Probing a ferromagnetic critical regime using nonlinear susceptibility. Phys. Rev. B: Condens. Matter 68, 094408 2003CrossRefGoogle Scholar
17Sinha, G.Majumdar, A.K.: Linear and non-linear AC susceptibilities in different magnetic phases of Fe-rich gamma-FeNiCr alloys. J. Magn. Magn. Mater. 185, 18 1998CrossRefGoogle Scholar
18Catalan, G.: Magnetocapacitance without magnetoelectric coupling. Appl. Phys. Lett. 88, 102902 2006CrossRefGoogle Scholar