Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-20T08:38:05.329Z Has data issue: false hasContentIssue false
  • English
  • Français

Czochralski growth and spectroscopic investigations of Yb3+, La3+:Na2SO4(I) and Nd3+:Na2SO4(I)

Published online by Cambridge University Press:  31 January 2011

Patric Mikhail ,
Reto Basler  and
Jürg Hulliger
Patric Mikhail
Affiliation:
Department of Chemistry and Biochemistry, University of Berne, Freiestrasse 3, CH-3012 Berne, Switzerland
Reto Basler
Affiliation:
Department of Chemistry and Biochemistry, University of Berne, Freiestrasse 3, CH-3012 Berne, Switzerland
Jürg Hulliger
Affiliation:
Department of Chemistry and Biochemistry, University of Berne, Freiestrasse 3, CH-3012 Berne, Switzerland
Get access

Abstract

Ln3+-stabilized Na2SO4 (phase I) single crystals were grown by the Czochralski method. Differential thermal analysis revealed the influence of the ionic radius of Ln3+ on the stabilization of Na2SO4(I). Distribution coefficients (∼0.8–1.1) were measured by the inductively coupled plasma optical emission spectroscopy method and x-ray fluorescence spectroscopy. Spectroscopic investigations yielded absorption cross sections of 0.6 × 10−20 cm2 (π-polarized, 928.5 nm) and 1.5 × 10−20 cm2 (π-polarized, 797.3 nm) for Yb3+, La3+:Na2SO4 and Nd3+:Na2SO4, respectively. Crystal growth of Gd3+-stabilized Na2SO4(I) provides an interesting new material for stimulated Raman scattering experiments.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 10 , October 1999 , pp. 4093 - 4097
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Bogomolova, G.A., Vylegzhanin, D.N., and Kaminskii, A.A, Sov. Phys. JEPT 42, 440 (1976).Google Scholar
2.Kuleshov, N.V., Lagatsky, A.A., Podlipensky, A.V., and Mikhailov, V.P., Opt. Lett. 22, 1317 (1997).CrossRefGoogle Scholar
3.Sumida, D.S., Fan, T.Y., and Hutcheson, R., OSA Proc. Adv. Solid State Lasers 24, 348 (1995).Google Scholar
4.DeLoach, L.D., Payne, S.A., Smith, L.K., Kway, W.L., and Krupke, W.F., J. Opt. Soc. Am. B 11, 269 (1994).CrossRefGoogle Scholar
5.Schaffers, K.I., DeLoach, L.D., and Payne, S.A., IEEE J. Quantum Electron. 32, 741 (1996).CrossRefGoogle Scholar
6.Loutts, G.B. and Chai, B.H.T, SPIE—Int. Soc. Opt. Eng. 1863, 31 (1993).Google Scholar
7.Caprez, A., Mikhail, P., Schwecke, C., and Hulliger, J., J. Mater. Res. 12, 3210 (1997).CrossRefGoogle Scholar
8.Payne, S.A., DeLoach, L.D., Smith, L.K., Kway, W.L., Tassano, J.B., Krupke, W.F., Chai, B.H.T, Loutts, G., J. Appl. Phys. 76, 497 (1994).CrossRefGoogle Scholar
9.Gloster, L.A.W, Cormont, P., Cox, A.M., King, T.A., and Chai, B.H.T, Opt. Commun. 146, 177 (1998).CrossRefGoogle Scholar
10.Iwai, M., Kobayashi, T., Furuya, H., Mori, Y., and Sasaki, T., Jpn. J. Appl. Phys. 36, 276 (1997).CrossRefGoogle Scholar
11.Aka, G., Kahn-Harari, A., Vivien, D., Benitez, J.M., Salin, F., and Godard, J., Eur. J. Solid State Inorg. Chem. 33, 727 (1996).Google Scholar
12.Chai, B., Ye, Q., Eichenholtz, J.M., Hammons, D.A., Jang, W.K., Shah, L., Luntz, G.M., and Richardson, M., Invited Paper at ICONO'98, XVI International Conference on Coherent and Nonlinear Optics, Moscow, Russia (1998).Google Scholar
13.Dharmasena, G. and Frech, R., J. Chem. Phys. 99, 8929 (1993).CrossRefGoogle Scholar
14.Rasmussen, S.E., Jørgensen, J.E., and Lundtoft, B., J. Appl. Crystallogr. 29, 42 (1996).CrossRefGoogle Scholar
15.Mehrotra, B.N., Hahn, Th., Arnold, H., and Eysel, W., Acta Crystallogr. A31, S79 (1975).Google Scholar
16.Naruse, H., Tanaka, K., Morikawa, H., Marumo, F., and Mehrotra, B.N., Acta Crystallogr. B43, 143 (1987).CrossRefGoogle Scholar
17.Fischmeister, H.F., Mh. Chemie 93, 420 (1962).Google Scholar
18.Keester, K.L., Eysel, W., and Hahn, Th., Acta Crystallogr. A31, S79 (1975).Google Scholar
19.Eysel, W., Höfer, H.H., Keester, K.L., and Hahn, Th., Acta Crystallogr. B41, 5 (1985).CrossRefGoogle Scholar
20.Höfer, H.H., Eysel, W., and von Alpen, U., J. Solid State Chem. 36, 365 (1981).CrossRefGoogle Scholar
21.Fedorov, P.P., Polkhovskaya, T.M., Sobolev, B.P., Ivanov-Shits, A.K., and Sorokin, N.I., Sov. Phys. Crystallogr. 28, 353 (1983).Google Scholar
22. Powder Diffraction File, Card No. 31–535 (Joint Committee for Powder Diffraction Standards, 1990).Google Scholar
23.Libnitz, E. and Tittel, M., J. Prakt. Chem. 6, 46 (1958).CrossRefGoogle Scholar
24. Powder Diffraction File, Card No. 29–1291, (Joint Committee for Powder Diffraction Standards, 1990).Google Scholar
25.Armbruster, Th., Basler, R., Mikhail, P., and Hulliger, J., J. Solid State Chem. 145, 309 (1999).CrossRefGoogle Scholar
26.Zagumennyi, A.I. and Shcherbakov, I.A., Proc. SPIE—Int. Soc. Opt. Eng. 2777, 200 (1996).Google Scholar
27.Zagumennyi, A.I., Zavartsev, Y.D., Studenikin, P.A., Shcherbakov, I.A., Umyskov, A.F., Popov, P.A., and Ufimtsev, V.B., SPIE—Int. Soc. Opt. Eng. 2698, 182 (1996).Google Scholar
28.Kaminskii, A.A., Bagayev, S.N., Hulliger, J., Eichler, H., Findeisen, J., and Macdonald, R., Appl. Phys. B 67, 157 (1998).CrossRefGoogle Scholar
29.Findeisen, J., Hulliger, J., Kaminskii, A.A., Eichler, H.J., Macdonald, R., Franz, P., and Peuser, P., Phys. Status Solidi, A 172, R5 (1999).3.0.CO;2-8>CrossRefGoogle Scholar
30.Franz, P., Egger, P., Hulliger, J., Findeisen, J., Kaminskii, A.A., and Eichler, H.J., Phys. Status Solidi B 210, R7 (1998).3.0.CO;2-E>CrossRefGoogle Scholar
31.Kaminskii, A.A. (private communication).Google Scholar