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Characterization of YBa2Cu4O8 high temperature electrical properties and thermodynamic stability

Published online by Cambridge University Press:  31 January 2011

B-S. Hong  and
T.O. Mason
B-S. Hong
Affiliation:
Department of Materials Science and Engineering and Materials Research Center, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208
T.O. Mason
Affiliation:
Department of Materials Science and Engineering and Materials Research Center, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208
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Abstract

Via in situ electrical property measurements (conductivity, Seebeck coefficient) over the temperature range 500–800 °C and oxygen partial pressure range 10−4-1 atm, the equilibrium transport properties and stability range of YBa2Cu4O8 were determined. YBa2Cu4O8 behaves like the intrinsically mixed-valent compound, magnetite (Fe3O4), with small variations in electrical properties with changes in oxygen partial pressure. The decomposition boundary to YBa2Cu3O6+y (or YBa2Cu3.5O7.5±z) and CuO occurs at log(po2, atm) = −1.24 × 104/T(K) + 11.01(773 ⋚ T(K) ⋚ 1073).

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Articles
Information
Journal of Materials Research , Volume 6 , Issue 10 , October 1991 , pp. 2054 - 2058
Copyright
Copyright © Materials Research Society 1991

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