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Ag/AgBr coupled low crystalline Nb2O5 as an effective photocatalyst for the degradation of rhodamine B

Published online by Cambridge University Press:  17 June 2020

Peng Zhang Open the ORCID record for Peng Zhang [Opens in a new window] ,
Xiaojuan Jian ,
Jianhong Tan ,
Yuanming Ran  and
Guoqing Zhang
Peng Zhang
Affiliation:
College of Materials Science and Engineering, Yangtze Normal University, Chongqing408100, China Helmholtz-Zentrum Berlin for Materials and Energy, Institute of Applied Materials, Berlin14109, Germany
Xiaojuan Jian
Affiliation:
College of Materials Science and Engineering, University of Science & Technology Beijing, Beijing100083, China
Jianhong Tan*
Affiliation:
College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing408100, China
Yuanming Ran
Affiliation:
College of Materials Science and Engineering, Yangtze Normal University, Chongqing408100, China
Guoqing Zhang
Affiliation:
College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing408100, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A novel Ag/AgBr/Nb2O5 heterojunction photocatalyst was successfully developed via a facile solvothermal method combined with deposition–precipitation. The morphology and composition of the Ag/AgBr/Nb2O5 photocatalyst were investigated by transmission electron microscopy and X-ray energy-dispersive spectrometry, respectively. The results showed that metallic Ag was formed on the surface of the AgBr by an in situ photoreaction. The low crystalline Nb2O5 (L-Nb2O5) substrate provides the photocatalyst with a high specific area and numerous active sites for catalysis, while the combination of the Ag/AgBr with L-Nb2O5 effectively facilitates the separation of photo-generated charge carriers. The photocatalytic activities of the samples were measured using the degradation of an aqueous solution of rhodamine B under different LEDs with UV (365 nm), yellow (595 nm), and white (400 nm ≤ λ ≤ 800 nm) light. The Ag/AgBr/L-Nb2O5 photocatalyst displayed a much higher photocatalytic activity than bare L-Nb2O5 under UV and visible-light irradiation.

Keywords

photodegradationlow crystallineAg/AgBr/Nb2O5 photocatalyst
Type
Article
Information
Journal of Materials Research , Volume 35 , Issue 13: Focus Section: Interactions of Shear Transformation Bands , 14 July 2020 , pp. 1692 - 1702
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Copyright © Materials Research Society 2020

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References

Kodama, R., Terada, Y., Nakai, I., Komaba, S., and Kumagai, N.: Electrochemical and in situ XAFS-XRD investigation of Nb2O5 for rechargeable lithium batteries. J. Electrochem. Soc. 153, 583–588 (2006).CrossRefGoogle Scholar
Ramakrishna, S., Le Viet, A., Reddy, M.V., Jose, R., and Chowdari, B.V.R.: Nanostructured Nb2O5 polymorphs by electrospinning for rechargeable lithium batteries. J. Phys. Chem. C 114, 664–674 (2010).Google Scholar
Wang, X., Li, G., Chen, Z., Augustyn, V., Ma, X., Wang, G., Dunn, B., and Lu, Y.: High-performance supercapacitors based on nanocomposites of Nb2O5 nanocrystals and carbon nanotubes. Adv. Energy Mater. 1, 1089–1093 (2011).CrossRefGoogle Scholar
Tao, Y., Wei, Y., Liu, Y., Wang, J., Qiao, W., Ling, L., and Long, D.: Kinetically-enhanced polysulfide redox reactions by Nb2O5 nanocrystals for high-rate lithium-sulfur battery. Energy Environ. Sci, 9, 3230–3239 (2016).CrossRefGoogle Scholar
Silva, R.M., Noremberg, B.S., Marins, N.H., Milne, J., Zhitomirsky, I., and Carreño, N.L.V.: Microwave-assisted hydrothermal synthesis and electrochemical characterization of niobium pentoxide/carbon nanotubes composites. J. Mater. Res. 34, 592–599 (2019).CrossRefGoogle Scholar
Liu, H., Gao, N., Liao, M., and Fang, X.: Hexagonal-like Nb2O5 Nanoplates-based photodetectors and photocatalyst with high performances. Sci. Rep. 5, 7716 (2015).CrossRefGoogle Scholar
Zhang, P., Wang, M., Wang, J., Teng, X., Zhang, S., Xie, H., and Ding, S.: Facile synthesis and characterization of low crystalline Nb2O5 ultrafine nanoparticles as a new efficient photocatalyst. J. Non-Cryst. Solids 500, 371–376 (2018).CrossRefGoogle Scholar
Özer, N., Chen, D.G., and Lampert, C.M.: Preparation and properties of spin-coated Nb2O5 films by the sol-gel process for electrochromic applications. Thin Solid Films 277, 162-168 (1996).CrossRefGoogle Scholar
Yoshimura, K., Miki, T., Iwama, S., and Tanemura, S.: Characterization of niobium oxide electrochromic thin films prepared by reactive d.c. magnetron sputtering. Thin Solid Films 281–282, 235–238 (1996).CrossRefGoogle Scholar
Zhou, Y., Qiu, Z., Lü, M., Zhang, A., and Ma, Q.: Preparation and spectroscopic properties of Nb2O5 nanorods. J. Lumin. 128, 1369–1372 (2008).CrossRefGoogle Scholar
Esteves, A., Oliveira, L.C.A., Ramalho, T.C., Goncalves, M., Anastacio, A.S., and Carvalho, H.W.P.: New materials based on modified synthetic Nb2O5 as photocatalyst for oxidation of organic contaminants. Catal. Commun. 10, 330–332 (2008).CrossRefGoogle Scholar
Lin, H.Y., Yang, H.C., and Wang, W.L.: Synthesis of mesoporous Nb2O5 photocatalysts with Pt, Au, Cu and NiO cocatalyst for water splitting. Catal. Today 174, 106–113 (2011).CrossRefGoogle Scholar
Zarrin, S. and Heshmatpour, F.: Photocatalytic activity of TiO2/Nb2O5/PANI and TiO2/Nb2O5/RGO as new nanocomposites for degradation of organic pollutants. J. Hazard. Mater. 351, 147–159 (2018).CrossRefGoogle ScholarPubMed
Oliveira, L.C.A., Oliveira, H.S., Mayrink, G., Mansur, H.S., Mansur, A.A.P., and Moreira, R.L.: One-pot synthesis of CdS@Nb2O5 core-shell nanostructures with enhanced photocatalytic activity. Appl. Catal. B Environ. 152–153, 403–412 (2014).CrossRefGoogle Scholar
Lam, S.M., Sin, J.C., Satoshi, I., Abdullah, A.Z., and Mohamed, A.R.: Enhanced sunlight photocatalytic performance over Nb2O5/ZnO nanorod composites and the mechanism study. Appl. Catal. A Gen. 471, 126–135 (2014).CrossRefGoogle Scholar
Shao, R., Zeng, X., Cao, Z., Dong, H., Wang, L., Wang, F., Liu, J., Li, Z., and Liang, Q.: A novel Ag3PO4/ Nb2O5 fiber composite with enhanced photocatalytic performance and stability. RSC Adv. 5, 102101–102107 (2015).CrossRefGoogle Scholar
Cheng, Q., Deng, X., Zhang, H., Guo, R., Cui, Y., Ma, Q., Zhang, X., Cheng, X., Xie, M., and Li, B.: Microwave assisted construction of Ag-AgBr/reduced TiO2 nano-tube arrays photoelectrode and its enhanced visible light photocatalytic performance for degradation of 4-chlorophenol. Sep. Purif. Technol. 193, 255–263 (2018).CrossRefGoogle Scholar
Zhang, P., Dong, Z., Ran, Y., Xie, H., Lu, Y., and Ding, S.: Preparation and photocatalytic application of AgBr modified Bi2WO6 nanosheets with high adsorption capacity. J. Mater. Res. 33, 3953–3962 (2018).CrossRefGoogle Scholar
Miao, X., Ji, Z., Wu, J., Shen, X., Wang, J., Kong, L., Liu, M., and Song, C.: G-C3N4/AgBr nanocomposite decorated with carbon dots as a highly efficient visible-light-driven photocatalyst. J. Colloid Interface Sci. 502, 24–32 (2017).CrossRefGoogle ScholarPubMed
Cai, Y., Chang, S., Liu, Y., Shen, Y., Li, F., Li, L., Zhu, S., and Zheng, X.: Hydrothermal-photoreduction synthesis of novel Ag@AgBr/BiVO4 plasmonic heterojunction photocatalysts with enhanced activity under white light emitting diode (wLED) irradiation. J. Mater. Sci. Mater. Electron. 29(20), 17602–17611 (2018).CrossRefGoogle Scholar
Wen, X.J., Niu, C.G., Zhang, L., Liang, C., Guo, H., and Zeng, G.-M.: Photocatalytic degradation of ciprofloxacin by a novel Z-scheme CeO2-Ag/AgBr photocatalyst: Influencing factors, possible degradation pathways, and mechanism insight. J. Catal. 358, 141–154 (2018).CrossRefGoogle Scholar
Guo, F., Shi, W., Wang, H., Han, M., Guan, W., Huang, H., Liu, Y., and Kang, Z.: Study on highly enhanced photocatalytic tetracycline degradation of type II AgI/CuBi2O4 and Z-scheme AgBr/CuBi2O4 heterojunction photocatalysts. J. Hazard. Mater. 349, 111–118 (2018).CrossRefGoogle Scholar
Chen, X., Yu, T., Fan, X., Zhang, H., Li, Z., Ye, J., and Zou, Z.: Enhanced activity of mesoporous Nb2O5 for photocatalytic hydrogen production. Appl. Surf. Sci. 253, 8500–8506 (2007).CrossRefGoogle Scholar
Liu, X., Zhu, Y., Li, W., Wang, F., Li, H., Ren, C., and Zhao, Y.: A novel Ag@AgBr-Ag2Mo3O10 ternary core-shell photocatalyst: Energy band modification and additional superoxide radical production. Appl. Surf. Sci. 458, 1–9 (2018).CrossRefGoogle Scholar
Xu, Y., Liu, Q., Liu, C., Zhai, Y., Xie, M., Huang, L., Xu, H., Li, H., and Jing, J.: Visible-light-driven Ag/AgBr/ZnFe2O4 composites with excellent photocatalytic activity for E. coli disinfection and organic pollutant degradation. J. Colloid Interface Sci. 512, 555–566 (2018).CrossRefGoogle ScholarPubMed
Kang, Y., Yang, Y., Yin, L.-C., Kang, X., Liu, G., and Cheng, H.-M.: An amorphous carbon nitride photocatalyst with greatly extended visible-light-responsive range for rhotocatalytic hydrogen generation. Adv. Mater. 27, 4572–4577 (2015).CrossRefGoogle ScholarPubMed
Chen, Z.P., Xing, J., Jiang, H.B., and Yang, H.G.: Disordered Co1.28Mn1.71O4 as a visible-light-responsive photocatalyst for hydrogen evolution. Chem. Eur. J. 19, 4123–4127 (2013).CrossRefGoogle ScholarPubMed
Das, D., Banerjee, D., Das, B., Das, N.S., and Chattopadhyay, K.K.: Effect of cobalt doping into graphitic carbon nitride on photo induced removal of dye from water. Mater. Res. Bull. 89, 170–179 (2017).CrossRefGoogle Scholar
Li, T., Luo, S., and Yang, L.: Microwave-assisted solvothermal synthesis of flower-like Ag/AgBr/BiOBr microspheres and their high efficient photocatalytic degradation for p-nitrophenol. J. Solid State Chem. 206, 308–316 (2013).CrossRefGoogle Scholar
Li, H., Zhu, H., Wang, M., Min, X., Fang, M., Huang, Z., Liu, Y., and Wu, X.: A new Ag/Bi7Ta3O18 plasmonic photocatalyst with a visible-light-driven photocatalytic activity. J. Mater. Res. 32, 3650–3659 (2017).CrossRefGoogle Scholar
Jiang, X., Ma, Y., Zhao, C., Chen, Y., Cui, M., Yu, J., Wu, Y., and He, Y.: Synthesis of flower-like AgI/Bi5O7I hybrid photocatalysts with enhanced photocatalytic activity in rhodamine B degradation. J. Mater. Res. 33, 2385–2395 (2018).CrossRefGoogle Scholar
Wu, C.: Facile room temperature synthesis of Ag@AgBr core-shell microspheres with high visible-light-driven photocatalytic performance. J. Mater. Res. 30, 677–685 (2015).CrossRefGoogle Scholar
Zhang, F., Wang, L., Xiao, M., Liu, F., Xu, X., and Du, E.: Construction of direct solid-state Z-scheme g-C3N4/BiOI with improved photocatalytic activity for microcystin-LR degradation. J. Mater. Res. 33, 201–212 (2018).CrossRefGoogle Scholar
Rouquerol, J., Rouquerol, F., Llewellyn, P., Maurin, G., and Sing, K.S.W.: Adsorption by Powders and Porous Solids (Acad. Press, London, UK, 2014), pp. 159, 189.Google Scholar
Guo, S., Zhang, X., Zhou, Z., Gao, G., and Liu, L.: Facile preparation of hierarchical Nb2O5 microspheres with photocatalytic activities and electrochemical properties. J. Mater. Chem. A 2, 9236–9243 (2014).CrossRefGoogle Scholar
Xue, J., Wang, R., Zhang, Z., and Qiu, S.: Facile preparation of C, N co-modified Nb2O5 nanoneedles with enhanced visible light photocatalytic activity. Dalt. Trans. 45, 16519–16525 (2016).CrossRefGoogle ScholarPubMed
Tian, G., Fu, H., Jing, L., and Tian, C.: Synthesis and photocatalytic activity of stable nanocrystalline TiO2 with high crystallinity and large surface area. J. Hazard. Mater. 161, 1122–1130 (2009).CrossRefGoogle Scholar
Zhang, Y., Han, C., Zhang, G., Dionysiou, D.D., and Nadagouda, M.N.: PEG-assisted synthesis of crystal TiO2 nanowires with high specific surface area for enhanced photocatalytic degradation of atrazine. Chem. Eng. J. 268, 170–179 (2015).CrossRefGoogle Scholar
Yao, W., Zhang, B., Huang, C., Ma, C., Song, X., and Xu, Q.: Synthesis and characterization of high efficiency and stable Ag3PO4/TiO2 visible light photocatalyst for the degradation of methylene blue and rhodamine B solutions. J. Mater. Chem. 22, 4050 (2012).CrossRefGoogle Scholar
Tang, J., Zou, Z., and Ye, J.: Photophysical and photocatalytic properties of AgInW2O8. J. Phys. Chem. B 107, 14265–14269 (2003).CrossRefGoogle Scholar
Castro, I.A., Avansi, W., and Ribeiro, C.: WO3/TiO2 heterostructures tailored by the oriented attachment mechanism: Insights from their photocatalytic properties. CrystEngComm 16, 1514–1524 (2014).CrossRefGoogle Scholar
Ran, J., Zhang, J., Yu, J., and Qiao, S.Z.: Enhanced visible-light photocatalytic H2 production by ZnxCd1−xS modified with earth-abundant nickel-based cocatalysts. ChemSusChem 7, 3426–3434 (2014).CrossRefGoogle Scholar
Hou, Y., Laursen, A.B., Zhang, J., Zhang, G., Zhu, Y., Wang, X., Dahl, S., and Chorkendorff, I.: Layered nanojunctions for hydrogen-evolution catalysis. Angew. Chem. Int. Ed. 52, 3621–3625 (2013).CrossRefGoogle ScholarPubMed
Li, Q., Meng, H., Yu, J., Xiao, W., Zheng, Y., and Wang, J.: Enhanced photocatalytic hydrogen-production performance of graphene-ZnxCd1-xS composites by using an organic S source. Chem. A Eur. J. 20, 1176–1185 (2014).CrossRefGoogle ScholarPubMed
Trasatti, S.: The absolute electrode potential: An explanatory note (Recommendations 1986). Pure Appl. Chem. 58, 955–966 (1986).CrossRefGoogle Scholar
Kim, Y., Atherton, S., Brigham, E., and Mallouk, T.: Sensitized layered metal oxide semiconductor particles for photochemical hydrogen evolution from nonsacrificial electron donors. J. Phys. Chem. 97, 11802–11810 (1993).CrossRefGoogle Scholar
Wang, S., Li, D., Yang, C., Sun, G., Zhang, J., Xia, Y., Xie, C., Yang, G., Zhou, M., and Liu, W.: A novel method for the synthesize of nanostructured MgFe2O4 photocatalysts. J. Sol-Gel Sci. Technol. 84, 169–179 (2017).CrossRefGoogle Scholar
Li, X., Xie, J., Jiang, C., Yu, J., and Zhang, P.: Review on design and evaluation of environmental photocatalysts. Front. Environ. Sci. Eng. 12, 14 (2018).CrossRefGoogle Scholar
Wu, F., Li, X., Liu, W., and Zhang, S.: Highly enhanced photocatalytic degradation of methylene blue over the indirect all-solid-state Z-scheme g-C3N4-RGO-TiO2 nanoheterojunctions. Appl. Surf. Sci. 405, 60–70 (2017).CrossRefGoogle Scholar
Shen, R., Jiang, C., Xiang, Q., Xie, J., and Li, X.: Surface and interface engineering of hierarchical photocatalysts. Appl. Surf. Sci. 471, 43–87 (2019).CrossRefGoogle Scholar
Li, W., He, S., Xu, W., Li, J., and Wang, X.: Synthesis of BiOCl-Ag/AgBr heterojunction and its photoelectrochemical and photocatalytic performance. Electrochim. Acta 283, 727–736 (2018).CrossRefGoogle Scholar
Li, X., Chen, D., Li, N., Xu, Q., Li, H., He, J., and Lu, J.: AgBr-loaded hollow porous carbon nitride with ultrahigh activity as visible light photocatalysts for water remediation. Appl. Catal. B Environ. 229, 155–162 (2018).CrossRefGoogle Scholar
Li, X., Yu, J., Jaroniec, M., and Chen, X.: Cocatalysts for selective photoreduction of CO2 into solar fuels. Chem. Rev. 119, 3962–4179 (2019).CrossRefGoogle ScholarPubMed
Ke, X., Dai, K., Zhu, G., Zhang, J., and Liang, C.: In situ photochemical synthesis noble-metal-free NiS on CdS-diethylenetriamine nanosheets for boosting photocatalytic H2 production activity. Appl. Surf. Sci. 481, 669–677 (2019).CrossRefGoogle Scholar
Liu, H., Wang, M., Wang, Y., Liang, Y., Cao, W., and Su, Y.: Ionic liquid-templated synthesis of mesoporous CeO2-TiO2 nanoparticles and their enhanced photocatalytic activities under UV or visible light. J. Photochem. Photobiol. A Chem. 223, 157–164 (2011).CrossRefGoogle Scholar