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Evidence of the Kuwaiti oil fires in the Dasuopu glacier ice core, central Himalaya

Published online by Cambridge University Press:  08 September 2017

Kang Shichang
Affiliation:
Laboratory of Ice Core and Cold Regions Environment, Cold and Arid Regions Environment and Engineering Research Institute, CAS, Lanzhou 730000, People’s Republic of China Institute for Quaternary and Climate Studies, University of Maine, Orono, Maine 04469-5790, U.S.A.
Qin Dahe
Affiliation:
Laboratory of Ice Core and Cold Regions Environment, Cold and Arid Regions Environment and Engineering Research Institute, CAS, Lanzhou 730000, People’s Republic of China
Paul A. Mayewski
Affiliation:
Institute for Quaternary and Climate Studies, University of Maine, Orono, Maine 04469-5790, U.S.A.
Xie Shucheng
Affiliation:
Laboratory of Ice Core and Cold Regions Environment, Cold and Arid Regions Environment and Engineering Research Institute, CAS, Lanzhou 730000, People’s Republic of China
Duan Keqin
Affiliation:
Laboratory of Ice Core and Cold Regions Environment, Cold and Arid Regions Environment and Engineering Research Institute, CAS, Lanzhou 730000, People’s Republic of China
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Abstract

Type
Correspondence
Copyright
Copyright © International Glaciological Society 2001

The Editor,

Journal of Glaciology

Sir,

During the Persian Gulf War in 1990–91, more than 740 oil wells in Kuwait were sabotaged (Reference Ferek, Hobbs, Herring and LaursenFerek and others, 1992), and more than 600 wells were set afire. The world, and in particular the Middle East, was left with one of the largest man-made environmental disasters, producing a pronounced impact on regional and global climate and environment (Reference BakanBakan and others, 1991). Oil fire products during the Persian Gulf War migrated over the Northern Hemisphere. The smoke aerosol from long-range transport of Kuwaiti oil fires was observed in Japan (Reference OkadaOkada and others, 1992), Pakistan (Reference Limaye, Suomi, Velden and TripoliLimaye and others, 1991), Hawaii (Reference Lowenthal, Borys and ChowLowenthal and others, 1992), as well asWyoming in the U.S.A. (Reference Deshler and HofmannDeshler and Hofmann, 1992).

In summer 1997, a 15 m ice core, covering the period 1988–97, was collected from 7000 m a.s.l. on a relatively flat portion of Dasuopu glacier (28°23′ N, 85°44′ E) on the northwest margin of Mount Xixiabangma in the central Himalaya. Detailed methods of ice-core sampling and chemical analysis are described by Reference Shichang, Wake, Dahe, Mayewski and TandongKang and others (2000), along with a discussion of monsoon and dust signals in the core. Profiles of δ 18O and major-ion (Ca2+, NO3 and S04 2−) concentrations against water-equivalent depth are shown in Figure 1. In general, variations of SO4 2− are in agreement with those of Ca2+ and NO3 in the ice core, mainly reflecting dust input from central Asia (Reference Shichang, Wake, Dahe, Mayewski and TandongKang and others, 2000). The highest SO4 2− concentration, 730.7 ppb (marked by an arrow in Figure 1), in the core is recorded during early 1991. The lowest SO4 2− concentration is 6.1 ppb, and mean SO4 2− is 122.9 ppb (std dev. 132.2). Ca2+ and NO3 concentrations during early 1991 do not have anomalous peaks. Thus, the 1991 SO4 2− is unique and appears not to be related to dust deposition.

Fig. 1. Depth profiles of δ 18O and ionic concentrations with depth (water equivalent) in the Dasuopu ice core. Dating was performed by counting seasonal peaks of δ 18O and major ions. The coarse solid line is a weighted smoothing (5 points smoothing). Dashed lines indicate annual layers.

In june 1991, the explosive eruption of Mount Pinatubo, Philippines, injected an estimated (18 ± 2) × 106 t of SO2 directly into the atmosphere (Reference KruegerKrueger and others, 1995). The volcanic aerosol mass was dispersed gradually in the global atmosphere, covering the entire Earth by mid-1992 (Reference Hitchman, McKay and TrepteHitchman and others, 1995). Pinatubo volcanic signals were identified in South Pole snow, which occurred from early or mid-1992 to mid-1994 (Reference Cole-Dai and Mosley-ThompsonCole-Dai and Mosley-Thompson, 1999). Though we cannot confirm when volcanic aerosol was transported to the Dasuopu core site, it was probably later than June 1991. However, the highest SO4 2− value in the Dasuopu core is recorded in early 1991 (Fig. 1). Thus, we consider that the 1991 spike of SO4 2− concentration is not related to the Pinatubo eruption.

We assume that the SO4 2− peak in 1991 in the Dasuopu ice core is related to the Kuwaiti oil fire products during the Persian Gulf War. Firstly, the Kuwaiti oil wells were set afire in early 1991 (Reference Ferek, Hobbs, Herring and LaursenFerek and others, 1992) and the aerosol smoke from oil fires was transported to the Himalayan region by a southern westerly jet, which only took 1–2 days (Reference Bodhaine, Harris, Ogren and HofmannBodhaine and others, 1992). Secondly, measurements of organic matter in the same core indicate that concentrations of some organic compounds from petroleum residues were higher during 1988–92 than in 1997 (Reference Shucheng, Tandong, Shichang, Keqin, Baiqin and ThompsonXie and others, 2000). Thirdly, chemical analysis of smoke plumes from the Kuwaiti oil fires shows that SO2 concentrations are 1–2 orders of magnitude higher than NOx, and SO4 2− is the dominant species among major ions in smoke plumes (Reference Ferek, Hobbs, Herring and LaursenFerek and others, 1992). These points suggest that pollutants from Kuwaiti oil fires were transported to Dasuopu glacier by the westerly jet and recorded in snow at 7000 m a.s.l. in the Himalaya. Thus, ice-core records from the Himalaya provide a unique opportunity to recover pollutant signals and reconstruct environmental changes in the past.

Acknowledgements

This research is supported by the Chinese Academy of Sciences (KZCX2-305, KZ951-A1-402, KZCX2-301/108, KZCX1-10-02), the NKBRSF Project of China (G1999043400) and the National Nature Science Foundation of China (49871022).

10 September 2001

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Figure 0

Fig. 1. Depth profiles of δ18O and ionic concentrations with depth (water equivalent) in the Dasuopu ice core. Dating was performed by counting seasonal peaks of δ18O and major ions. The coarse solid line is a weighted smoothing (5 points smoothing). Dashed lines indicate annual layers.