Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-26T21:57:55.385Z Has data issue: false hasContentIssue false

The Saha equation and the adiabatic exponent in shock wave calculations

Published online by Cambridge University Press:  28 March 2006

Ralph A. Alpher
Affiliation:
General Electric Research Laboratory, Schenectady, New York

Abstract

The purpose of this note is to comment on the calculation of equilibrium gas dynamic parameters behind strong shock waves. The writer has been aroused by the appearance of a paper by Guman (1956) presenting a generalized computing scheme for ionizing shock waves in monatomic gases. In that paper the reader is not cautioned about including excited states in the Saha equation for the computation of the degree of ionization behind shock fronts at appropriate temperatures and densities. The same paper treats the adiabatic exponent γ = cp/cv as constant across strong shocks when at the same time it is implied that the computing scheme is of general validity. Hence, the unwary reader might attempt to apply the scheme in a regime where γ is not only no longer constant but is no longer a useful quantity for characterizing the shock conditions. Other authors (see, for example, Glass, Martin & Patterson (1953)) characterize flows in which a shock has excited internal degrees of freedom in terms of a variable specific heat ratio when in fact one cannot use this quantity in calculating shock front conditions.

Type
Research Article
Copyright
© 1957 Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aller, L. H. 1953 Astrophysics—The Atmospheres of the Sun and Stars. New York: Ronald Press.
Bethe, H. A. 1942 The specific heat of air up to 25000° C, Office of Scientific Research and Development, Rep no. 369.Google Scholar
Bethe, H. A. & Teller, E. 1940 Deviations from thermal equilibrium in shock waves, Ballistic Research Laboratories, Aberdeen Proving Ground, Maryland, Rep. no. X117.Google Scholar
Bond, J. W. 1954 The structure of a shock front in Argon, Los Alamos Scientific Laboratory, Rep. no. LA 1603.Google Scholar
Christian, R. H. & Yarger, F. L. 1955 J. Chem. Phys. 23, 2042.
Ecker, G. & Weizel, W. 1956 Ann. d. Phys. 17, 126.
Fowler, R. H. 1955 Statistical Mechanics. Cambridge University Press. (In this book the earlier work on Fermi, Urey and Planck on the computation of partition functions is also discussed.)
Fuchs, K., Lynch, G. J. & Peierls, R. 1942 The equation of state of air at high temperature, British Ministry of Supply, Department of Atomic Energy, BDDA 16, Rep. no. MS61 (U.S. Dept of Commerce PBL 87018).Google Scholar
Gilmore, F. R. 1955 Equilibrium composition and thermodynamic properties of air to 24000° K, Rand Corporation, Santa Monica, California, Rep. no. RM1543.Google Scholar
Guman, W. J. 1956 J. Appl. Phys. 27, 663.
Glass, I. I., Martin, W. & Patterson, G. N. 1953 A theoretical and experimental study of the shock tube, University of Toronto Institute of Aerophysics, Rep. no. 2.Google Scholar
Hirschfelder, J. L. & Curtiss, C. F. 1948 Thermodynamic properties of air at high temperatures, University of Wisconsin, Rep. no. CM-518.Google Scholar
Meghreblian, R. V. 1953 Thermodynamic functions of poly-electronic atoms at very high temperatures, California Institute of Technology, Ph.D. Thesis.
Resler, E. L., Lin, S. C. & Kantrowitz, A. 1952 J. Appl. Phys. 23, 1390.
Romig, M. L. 1956 J. Aero. Sci. 23, 185.
Sänger-Bredt, I. 1955 Z. angew. Math. Phys. 6, 35. (This paper is a very thorough discussion of the role of the adiabatic index in gas dynamics. The author specifically discusses isentropic flows which are generalized by means of an index σ, equivalent to γ’ in equation (8).)
Unsöld, A. 1948 Z. Astrophys. 24, 355.
Woolley, H. W. 1955 Thermodynamic functions of atomic ions. I. Fundamental theory, National Bureau of Standards, Washington, Rep. no. 4089.Google Scholar