The concentration field of mixing layers subject to stabilizing and destabilizing streamwise curvature was investigated at post-mixing-transition conditions. A set of operating conditions was implemented, identical to those at which straight layers were previously investigated in the same facility, in order to compare the effects of hydrodynamic instabilities upon scalar mixing. Quantitative imaging of planar laser-induced fluorescence was used for (i) passive scalar measurements, and (ii) chemical product measurements. Similar to the straight mixing layer, the results for the curved layers show that beyond the mixing transition the layer continues to evolve, and undergoes a small change in its scalar structure. At conditions just past the mixing transition both stable and unstable layers have average mixed-fluid compositions which are uniform across the layer, and average chemical product concentration profiles which are symmetric. At more fully developed conditions, the scalar field evolved: the average mixed-fluid concentration developed a small lateral variation, while the chemical product concentration profiles became asymmetric. Similar to the straight layer, the mixture-fraction PDF is believed to be of the tilted type for the most fully developed layer examined, with the marching PDF being a poor representation. Consistent with previous investigations, the growth rate of the unstable layer was found to be higher than that of straight or stable layers. The most important result is that the measured mixing efficiency of all the layers (curved and straight) was found to be the same: both the total mixed-fluid composition, and the volume fraction of mixed fluid were the same for all unstable, stable, and straight layers. The amount of mixed fluid (and of chemical product formed) was larger for the unstable layer, but always in a fixed proportion to the layer's thickness. The lack of increase in the mixing efficiency for the unstable layer is surprising, given that previous hydrodynamic measurements had shown enhanced turbulent transport for the unstable case. Thus, for all liquid shear layers studied, the rate of scalar mixing appears to be directly proportional to the entrainment rate (which essentially determines the layer's growth rate), and not to any hydrodynamic measures.