Published online by Cambridge University Press: 21 April 2006
The equilibrium shape and stability of menisci formed at the contact line between two vertically aligned cylinders were investigated by developing a general bifurcation analysis from the classic equation of Young-Laplace. It was found that the maximum amount of liquid that can be held at the contact line is determined by the existence of a bifurcation of the equilibrium solutions. The onset of instability is characterized by a translationally symmetric bifurcation that always precedes the instability to asymmetric perturbations. The maximum stable liquid retention is a strong function of the ratio of gravitational to surface-tension forces, indicating that gravity acts as a destabilizing force. The effect of contact angle on the maximum liquid retention is more complex: when the gravitational effects are small, an increase in contact angle results in a decrease in liquid retention; on the other hand, when the gravitational effects are appreciable, a maximum value of the liquid retention is obtained for intermediate values of the contact angle.