We present the results of an experimental investigation of the striking flow structures that may arise when a vertical jet of fluid impinges on a thin fluid layer overlying a horizontal boundary. Ellegaard et al. (Nature, vol. 392, 1998, p. 767; Nonlinearity, vol. 12, 1999, p. 1) demonstrated that the axial symmetry of the circular hydraulic jump may be broken, resulting in steady polygonal jumps. In addition to these polygonal forms, our experiments reveal a new class of steady asymmetric jump forms that include structures resembling cat's eyes, three- and four-leaf clovers, bowties and butterflies. An extensive parameter study reveals the dependence of the jump structure on the governing dimensionless groups. The symmetry-breaking responsible for the asymmetric jumps is interpreted as resulting from a capillary instability of the circular jump. For all steady non-axisymmetric forms observed, the wavelength of instability of the jump is related to the surface tension, $\sigma$, fluid density $\rho$ and speed $U_v$ of the radial outflow at the jump through $\lambda\,{=}\,(74\pm7)\sigma/(\rho U_v^2)$.