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Nonlinear rheology of a dilute emulsion of surfactant-covered spherical drops in time-dependent flows

Published online by Cambridge University Press:  31 July 2002

P. VLAHOVSKA
Affiliation:
Department of Chemical Engineering, Yale University, New Haven, CT 06520-8286, USA
J. BŁAWZDZIEWICZ
Affiliation:
Department of Chemical Engineering, Yale University, New Haven, CT 06520-8286, USA Present address: Department of Mechanical Engineering, Yale University, New Haven, CT 06520-8286, USA.
M. LOEWENBERG
Affiliation:
Department of Chemical Engineering, Yale University, New Haven, CT 06520-8286, USA

Abstract

The effect of an insoluble surfactant on the rheological behaviour of a dilute emulsion is theoretically studied under low-capillary-number conditions. The dynamics depends on three dimensionless time-scale parameters that characterize the strength of the mechanisms that control the magnitude of the distortion of the surfactant distribution on the drop interface. These mechanisms include Marangoni relaxation, drop rotation by the imposed flow, and oscillations of the imposed flow. The interaction of the time scales gives rise to a complex rheological behaviour. The evolution of the system is described by a nonlinear matrix equation derived by expanding the fluid velocity and surfactant distribution in spherical harmonics. Analytical expansions are developed for conditions where the surfactant distribution is only slightly perturbed, which occurs when one of the time-scale parameters is small.

Type
Research Article
Copyright
© 2002 Cambridge University Press

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