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Study of the fouling of a mineral microfiltration membrane using scanning electron microscopy and physicochemical analyses in the processing of milk

Published online by Cambridge University Press:  01 June 2009

Claudine Vetier
Affiliation:
Laboratoire de Technologie Alimentaire, Groupe de Recherche et de Développement sur les Membranes, Université des Sciences et Techniques du Languedoc, 34060 Montpellier, France
Michel Bennasar
Affiliation:
Laboratoire de Technologie Alimentaire, Groupe de Recherche et de Développement sur les Membranes, Université des Sciences et Techniques du Languedoc, 34060 Montpellier, France
Blas Tarodo de la Fuente
Affiliation:
Laboratoire de Technologie Alimentaire, Groupe de Recherche et de Développement sur les Membranes, Université des Sciences et Techniques du Languedoc, 34060 Montpellier, France

Summary

Soluble proteins and Ca and P salts in the fouling deposit on a mineral microfiltration membrane obtained in static conditions were analysed and compared with those found using dynamic filter conditions in a laboratory pilot installation for milk processing. The serum milk proteins were retained by the porous micellar deposit under both static and dynamic conditions, resulting in progressive fouling of the dynamic micellar membrane, enabling milk to be processed with a mineral microfiltration membrane. Ca and P salts increased fouling probably by allowing better adsorption of casein micelles on the alumina and by acting as intermicellar bonds in the deposit. Fat globules modified porosity, permeability and resistance to matter transfer of the deposit. The dynamic conditions gave a deposit of the same type and structure as with the static conditions although made thinner by the velocity effect.

Type
Original articles
Copyright
Copyright © Proprietors of Journal of Dairy Research 1988

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References

REFERENCES

Alais, C. 1984 Science du Lait-Principes des Techniques Laitières, 4th edn.París: SEPAICGoogle Scholar
Aschaffenburg, R. & Drewry, J. 1959 New procedure for the routine determination of the various non-casein proteins of milk. 15th International Dairy Congress, London 3 16311637.Google Scholar
Association Française De Normalisation 1980 [Determination of total nitrogen content.] [Milk and milk products – methods of analysis] pp. 4852. Paris: AFNORGoogle Scholar
Baklouti, S., Aimar, P. & Sanchez, V. 1984 [Adsorption and transfer of material during ultrafiltration.] Lait 64 206216CrossRefGoogle Scholar
Bennasar, M., Gillot, J., Garcera, D. & Tarodo De La Fuente, B. 1984 [Study of a new membrane for the ultrafiltration of milk and optimization of its geometry.] Proceedings, Congrès FILTRA 84 pp. 173190. Paris: Société Française de FiltrationGoogle Scholar
Carroll, R. J., Thompson, M. P. & Nutting, G. C. 1968 Glutaraldehyde fixation of casein micelles for electron microscopy. Journal of Dairy Science 51, 19031908CrossRefGoogle Scholar
Cheryan, M. & Merin, U. 1981 The effect of protein-mineral-membrane interactions on the fouling of ultrafiltration membranes. Fundamentals and Applications of Surface Phenomena Associated with Fouling and Cleaning in Food Processing, Proceedings, Tylösand pp. 204214. (Eds Hallström, B., Lund, D. B. and Ch., Trägårdh). Lund: Division of Food Engineering, Lund UniversityGoogle Scholar
Clifton, M. 1982 Polarisation de concentration dans divers procédés de séparation à membrane. Thesis, University of ToulouseGoogle Scholar
Dejmek, P. 1975 Permeability of the concentration polarization layer in UF of macromolecules. Symposium International: Séparations par membranes, échange d'ions et cryoconcentration dans l'Industrie alimentaire pp. A2.1–A2.26. Paris: Association pour la Promotion Industrie AgricultureGoogle Scholar
Gillot, J. & Garcera, D. 1984 [New ceramic filtration media for tangential microfiltration and ultrafiltration.] Congrès FILTRA 84 pp. 161172. Paris: Société Française de FiltrationGoogle Scholar
Glover, F. A. & Brooker, B. E. 1974 The structure of the deposit formed on the membrane during the concentration of milk by reverse osmosis. Journal of Dairy Research 41, 8993CrossRefGoogle Scholar
Hickey, M. W., Hill, R. D. & Smith, B. R. 1980 Investigations into the ultrafiltration and reverse osmosis of wheys. I. The effects of certain pretreatments New Zealand Journal of Dairy Science and Technology 15, 109121Google Scholar
Kaláb, M. 1981 Electron microscopy of milk products: a review of techniques. Scanning Electron Microscopy III 453472Google Scholar
Kaláb, M. 1984 Artefacts in conventional scanning electron microscopy of some milk products. Food Microstructure 3, 95111Google Scholar
Kessler, H. G. 1981 Food Engineering and Dairy Technology pp. 82118. Freising: Verlag A. KesslerGoogle Scholar
Lee, D. N. & Merson, R. L. 1975 Examination of Cottage cheese whey proteins by scanning electron microscopy: relationship to membrane fouling during ultrafiltration. Journal of Dairy Science 58, 14231432CrossRefGoogle ScholarPubMed
Lee, D. N., Miranda, M. G. & Merson, R. L. 1975 Scanning electron microscope studies of membrane deposits from whey ultrafiltration. Journal of Food Technology 10, 139146CrossRefGoogle Scholar
Linden, G. 1971 [Use of atomic absorption spectrophotometry in food industry laboratories.] Industries Alimentaires et Agricoles 88 793802Google Scholar
McGann, T. C. A. & Pyne, G. T. 1960 The colloidal phosphate of milk. III. Nature of its association with casein. Journal of Dairy Research 27 403417CrossRefGoogle Scholar
Pien, J. 1969 [Determination of phosphorus in milk.] Lait 49 175188CrossRefGoogle Scholar
Porter, M. C. 1972 Concentration polarization with membrane ultrafiltration. Industrial and Engineering Chemistry, Process Design and Development 11 234248Google Scholar
Skudder, P. J., Glover, F. A. & Green, M. L. 1977 An examination of the factors affecting the reverse osmosis of milk with special reference to deposit formation. Journal of Dairy Research 44 293307CrossRefGoogle Scholar
Vetier, C., Bennasar, M. & Tarodo De La Fuente, B. 1986 [Study of the interactions between milk constituents and mineral membranes for microfiltration.] Lait 66 269287CrossRefGoogle Scholar