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Rheological and structural studies on heat-induced gelation of concentrated skim milk

Published online by Cambridge University Press:  01 June 2009

Atsumi Tobitani
Affiliation:
Technical Research Institute, Snow Brand Milk Products Co. Ltd, 1-1-2 Minamidai, Kawagoe, Saitama 350-11, Japan
Haruyoshi Yamamoto
Affiliation:
Technical Research Institute, Snow Brand Milk Products Co. Ltd, 1-1-2 Minamidai, Kawagoe, Saitama 350-11, Japan
Toshiaki Shioya
Affiliation:
Technical Research Institute, Snow Brand Milk Products Co. Ltd, 1-1-2 Minamidai, Kawagoe, Saitama 350-11, Japan
Simon B. Ross-Murphy
Affiliation:
Division of Life Sciences, King's College London, Campden Hill Road, Kensington, London W8 7AH, UK

Summary

Heat-induced gelation of milk was studied using both rheological and structural techniques. The sample was a conventional skim milk, concentrated with an ultrafiltration membrane, which formed gels when heated at appropriate pH. We investigated some factors that are considered to affect the gelation, such as concentration, pH and rennet treatment. The gelation process was monitored with a high precision oscillatory shear rheometer and the structure of gels was evaluated with quasi-elastic laser light scattering. From these results the gelation and phase separation behaviour were determined. By combining the results for different concentrations a phase diagram was obtained, which indicated that skim milk had a two-phase region on the higher temperature side. The effects of pH and rennet treatment were also evaluated with the aid of this phase diagram. The results were discussed on the basis of concepts of the phase behaviour of polymers, which were successfully developed in polymer physics.

Type
Original Articles
Copyright
Copyright © Proprietors of Journal of Dairy Research 1995

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References

REFERENCES

Burchard, W. 1994 Light scattering techniques. In Physical Techniques for the Study of Food Biopolymers, pp.151213 (Ed. Ross-Murphy, S. B.). Glasgow: Blackie Academic and ProfessionalCrossRefGoogle Scholar
Candau, S., Bastide, J. & Delsanti, M. 1982 Structural, elastic, and dynamic properties of swollen polymer networks. Advances in Polymer Science 44 2771CrossRefGoogle Scholar
Chambon, F. & Winter, H. H. 1985 Stopping of crosslinking reaction in a PDMS polymer at the gel point. Polymer Bulletin 13 499503Google Scholar
Clark, A. H & Ross-Murphy, S. B. 1987 Structural and mechanical properties of biopolymer gels. Advances in Polymer Science 83 57192CrossRefGoogle Scholar
Coniglio, A., Stanley, H. E. & Klein, W. 1982 Solvent effect on polymer gels: a statistical–mechanical model. Physical Review B 25 68056821CrossRefGoogle Scholar
De Gennes, P. G. 1979 Scaling Concepts in Polymer Physics, Chapter V. New York: Cornell University PressGoogle Scholar
Eliassaf, J. & Silberberg, A. 1962 The gelation of aqueous solutions of polymethacrylic acid. Polymer 3 555564.CrossRefGoogle Scholar
Ferry, J. D. 1980 Viscoelastic Properties of Polymers. New York: John WileyGoogle Scholar
Flory, P. J. 1953 Principles of Polymer Chemistry. New York: Cornell University PressGoogle Scholar
Gordon, M. & Ross-Murphy, S. B. 1975 The structure and properties of molecular trees and networks. Pure and Applied Chemistry 43 126CrossRefGoogle Scholar
Hegg, P.-O. 1982 Conditions for the formation of heat-induced gels of some globular food proteins. Journal of Food Science 47 12411244CrossRefGoogle Scholar
Horne, D. S. 1989 Application of fractal concepts to the study of caseinate aggregation phenomena. Journal of Dairy Research 56 535541CrossRefGoogle Scholar
Horne, D. S. 1991 Light scattering studies of milk gel systems. In Food Polymers, Gels and Colloids, pp. 404414 (Ed. Dickinson, E.). Cambridge: Royal Society of ChemistryCrossRefGoogle Scholar
Horne, D. S. & Davidson, C. M. 1990 The use of dynamic light-scattering in monitoring rennet curd formation. Milchwissenschaft 45 712715Google Scholar
Kato, A., Nagase, Y., Matsudomi, N. & Kobayashi, K. 1983 Determination of molecular weight of soluble ovalbumin aggregates during heat denaturation using low angle laser light scattering technique. Agricultural and Biological Chemistry 47 18291834Google Scholar
Ma, C.-Y. & Holme, J. 1982 Effect of chemical modifications on some physicochemieal properties and heatcoagulation of egg albumen. Journal of Food Science 47 14541459CrossRefGoogle Scholar
Mori, T., Nakamura, T. & Utsumi, S. 1982 Gelation mechanism of soybean 11S globulin: formation of soluble aggregates as transient intermediates. Journal of Food Science 47 2630CrossRefGoogle Scholar
Nakamura, K., Takahashi, I., Sakurai, M. & Nakagawa, T. 1992 The viscoelastic properties of aqueous poly(methacrylic acid) solutions and their relations to thermoreversible gelation. Polymer Journal 24 14191427CrossRefGoogle Scholar
Nieuwenhuijse, J. A., Van Vliet, T. & Walstra, P. 1992 Kinetic aspects of the heat-induced coagulationof concentrated skim milk. Netherlands Milk and Dairy Journal 46 4568Google Scholar
Parker, T. G. & Dalgleish, D. G. 1977 The potential application of the theory of branching process to theassociation of milk protein. Journal of Dairy Research 44 7984CrossRefGoogle Scholar
Paul, D. R. & Barlow, J. W. 1982 Polymer blends. Introductory overview and future developments. In Polymer Compatibility and Incompatibility—Principles and Practices, pp. 123 (Ed. Šole, K.). Chur: Harwood Academic PublishersGoogle Scholar
Payens, T. A. J. 1976 On the enzyme-triggered clotting of casein; a preliminary account. Netherlands Milk and Dairy Journal 30 5559Google Scholar
Ross-Murphy, S. B. 1991 Incipient behaviour of gelatin gels. Rheologica Acta 30 401411CrossRefGoogle Scholar
Ross-Murphy, S. B. 1994 Rheological techniques. In Physical Techniques for The Study of Food Biopolymers, pp. 343392 (Ed. Ross-Murphy, S. B.). Glasgow: Blackie Academic and ProfessionalCrossRefGoogle Scholar
Sharma, S. K., Hill, A. R. & Mittal, G. S. 1993 Effect of milk concentration, pH and temperature on aggregation kinetics and coagulation properties of ultrafiltered (UF) milk. Food Research International 26 8187CrossRefGoogle Scholar
Stauffer, D., Coniglio, A. & Adam, M. 1982 Gelation and critical phenomena. Advances in Polymer Science 44 103158CrossRefGoogle Scholar
Steventon, A. J., Gladden, L. F. & Fryer, P. J. 1991 A percolation analysis of the concentration dependence of the gelation of whey protein concentrates. Journal of Texture Studies 22 201218CrossRefGoogle Scholar
Tanaka, T. & Benedek, G. B. 1975 Observation of protein diffusivity in intact human and bovine lenses withapplication to cataract. Investigative Ophthalmology 14 449456Google ScholarPubMed
Tanaka, T. & Swislow, G. 1979 Phase separation and gelation in gelatin gels. Physical Review Letters 42 15561559CrossRefGoogle Scholar
Tokita, M., Niki, R. & Hikichi, K. 1984 Percolation theory and elastic modulus of gel. Journal of the Physical Society of Japan 53 480482CrossRefGoogle Scholar
Van Hooydonk, A. C. M. & Walstra, P. 1987 Interpretation of the kinetics of the renneting reaction in milk. Netherlands Milk and Dairy Journal 41 1947Google Scholar
Walstra, P., Van Vliet, T. & Bremer, L. G. B. 1991 On the fractal nature of particle gels. In Food Polymers, Gels and Colloids, pp. 369382 (Ed. Dickinson, E.). Cambridge: Royal Society of Chemistry (SpecialPublication no. 82)CrossRefGoogle Scholar