Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-04T21:57:38.414Z Has data issue: false hasContentIssue false

Changes in soil pH and exchangeable calcium in two liming experiments on contrasting soils over 12 years

Published online by Cambridge University Press:  27 March 2009

J. Bolton
Affiliation:
Rothamsted Experimental Station, Harpenden, Herts. A15 2JQ

Summary

Soils were analysed from two long-term liming experiments on a sandy-clay loam at Rothamsted and a loamy sand at Woburn. Plots given four levels of limestone factorially combined with phosphate and potassium fertilizers (with magnesium subplots in 1974) were cropped with beans, barley, potatoes and oats from 1963 to 1974.

The smallest limestone applications (5 t CaCO3/ha) increased soil pH the following year to values predicted by lime-requirement determinations using a standard advisory method. The larger limestone applications (10 and 20 t/ha) increased pH proportionally less. Soil pH decreased after the first year with 5 t/ha in both experiments but increased at the 20 t/ha rate for 6 years in the sandy-clay loam and for 3 years in the loamy sand before starting to decline.

Exchangeable calcium (soluble in N ammonium acetate) decreased at approximately linear rates in all plots of both experiments from the first year. Slopes of the regressions were smaller at low than at higher rates of liming, depending primarily on the average pH. Rates of CaCO3 losses from the surface 23 cm of soil ranged from 225 to 823 kg/ha per year at Rothamsted and from 307 to 852 kg/ha per year at Woburn.

Observed rates of Ca loss were compared with an empirical relationship suggested by Gasser (1973) between annual Ca losses and soil pH under average rainfall conditions and estimates based on a model system.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1977

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Adams, F. (1971). Ionic concentrations and activities in soil solutions. Proceedings of the Soil Science Society of America 35, 420–6.CrossRefGoogle Scholar
Bolton, J. (1971). Long-term liming experiments at Rothamsted and Woburn. Rothamsted Experimental Station. Report for 1970, Part II, 98112.Google Scholar
Bolton, J. (1972). Changes in magnesium and calcium in soils of the Broadbalk wheat experiment at Rothamsted from 1865 to 1966. Journal of Agricultural Science, Cambridge 79, 217–23.CrossRefGoogle Scholar
Crowther, E. M. (1936). The soils of the Woburn plots. In Fifty Years of Field Experiments at the Woburn Experimental Station (ed. Russel, E. J. and Voelcker, J. A.), pp. 315–45. London: Longmans Green and Co.Google Scholar
Gasser, J. K. R. (1973). An assessment of the importance of some factors causing loss of lime from agricultural soils. Experimental Husbandry 25, 8695.Google Scholar
Hall, A. D. & Miller, N. H. J. (1905). The effect of plant growth and manures upon the retention of bases by the soil. Proceedings of the Royal Society B 77, 132.Google Scholar
Heintze, S. G. (1949). Liming experiments on light land at Tunstall. 2. Soil reaction and loss of lime. Journal of the Royal Agricultural Society of England 110, 98103.Google Scholar
Metson, A. J. (1956). Methods of chemical analysis for soil survey samples. Bulletin. Soil Bureau Department of Scientific and Industrial Research, Wellington, New Zealand 12, p. 103.Google Scholar
Ministry of Agriculture, Fisheries and Food (1973). Fertilizer recommendations. Ministry of Agriculture, Fisheries and Food Bulletin 209.Google Scholar
Shoemaker, H. E., McLean, E. O. & Pratt, P. F. (1961). Buffer methods for determining the lime requirement of soils with appreciable amounts of extractable aluminium. Proceedings of the Soil Science Society of America 25, 274–7.CrossRefGoogle Scholar
Walker, T. W. (1953). The estimation of the lime requirements of soils. Soil and crop yield data from the Harper Adams and other liming experiments. Journal of Soil Science 3, 261–76.CrossRefGoogle Scholar
Williams, R. J. B. (1976). The chemical composition of rain, land-drainage and borehole water from Rothamsted, Broom's Barn, Saxmundham and Woburn Experimental Stations. In: Agriculture and water quality. Ministry of Agriculture, Fisheries and Food Bulletin 32, 174200.Google Scholar
Woodruff, C. M. (1948). Testing soils for lime requirement by means of a buffered solution and the glass electrode. Soil Science1 66, 5363.CrossRefGoogle Scholar