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Validation of analytical method and evaluation of clothianidin residues in rice in a typical Chinese field ecosystem

Published online by Cambridge University Press:  25 October 2017

Z. Y. ZHANG ,
Z. T. ZHENG ,
G. Y. ZHU ,
X. Y. YU ,
D. L. WANG  and
X. J. LIU
Z. Y. ZHANG*
Affiliation:
Key Laboratory of Food Quality and Safety of Jiangsu Province State Key Laboratory Breeding Base/Key Laboratory of Control Technology and Standard for Agro-product Safety and Quality, Ministry of Agriculture of P. R. China, Nanjing 210014, China
Z. T. ZHENG
Affiliation:
Institute for the Control of Agrochemicals, Ministry of Agriculture of P. R. China, Beijing 100125, China
G. Y. ZHU
Affiliation:
Institute for the Control of Agrochemicals, Ministry of Agriculture of P. R. China, Beijing 100125, China
X. Y. YU
Affiliation:
Key Laboratory of Food Quality and Safety of Jiangsu Province State Key Laboratory Breeding Base/Key Laboratory of Control Technology and Standard for Agro-product Safety and Quality, Ministry of Agriculture of P. R. China, Nanjing 210014, China
D. L. WANG
Affiliation:
Key Laboratory of Food Quality and Safety of Jiangsu Province State Key Laboratory Breeding Base/Key Laboratory of Control Technology and Standard for Agro-product Safety and Quality, Ministry of Agriculture of P. R. China, Nanjing 210014, China
X. J. LIU
Affiliation:
Key Laboratory of Food Quality and Safety of Jiangsu Province State Key Laboratory Breeding Base/Key Laboratory of Control Technology and Standard for Agro-product Safety and Quality, Ministry of Agriculture of P. R. China, Nanjing 210014, China
*
*To whom all correspondence should be addressed. Email: [email protected]
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Summary

A liquid chromatography mass spectrometry method for determination of clothianidin in brown rice, straw, rice hull, paddy water and paddy sediment was developed and residue levels were determined in the different components. The limit of quantification was set at 0·01 mg/kg for the matrices studied. Clothianidin degradation in straw, paddy water and soil was studied, and clothianidin residues in brown rice, straw, hull and paddy soil were determined. Concurrent recoveries were between 85·6 and 92·5%, with relative standard deviations ranging from 1·3 to 6·8% at three fortification levels between 0·01 and 5·0 mg/kg. The half-lives in straw, paddy water and paddy sediment were found to be 1·9–4·9, 4·1–5·0 and 4·9–6·3 days, respectively. The maximum residues in brown rice, straw, hull and paddy soil samples were 0·38, 1·88, 1·38 and 0·14 mg/kg, respectively.

Type
Crops and Soils Research Papers
Information
The Journal of Agricultural Science , Volume 155 , Issue 9 , November 2017 , pp. 1371 - 1380
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Copyright
Copyright © Cambridge University Press 2017 

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References

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