Summary. The reactions involved in oil generation are of great economic importance, but remain to be studied in detail. We have investigated the rates of three reactions which occur before and during the early stages of oil formation, and have used the predicted thermal and subsidence history of stretched basins to estimate the six reaction constants. Two of the reactions are isomerization reactions, at C-20 in a sterane and at C-22 in a hopane hydrocarbon. The third reaction converts C-ring monoaromatic to triaromatic steroid hydrocarbons. No single measure of maturity can describe the progress of these reactions. In old basins, such as the North Sea, both isomerization reactions are almost complete before appreciable aromatization has occurred, whereas in young basins, such as the Pannonian Basin in Hungary, aromatization is almost complete before appreciable isomerization of the steranes has occurred. We show that the calculated progress of these reactions agrees well with that observed in both basins if the frequency factors and activation energies are 6 x 10-3 s-1 and 91 kJ mol-1, 0.016 s-1 and 91 kJ mol-1, 1.8 x 1024 s-1 and 200 kJ mol-1 for the isomerization of steranes, of hopanes, and the aromatization of steroid hydrocarbons respectively. The rate of conversion of the R to the S form was taken to be 1.174 and 1.564 times that of the reverse reactions for sterane and hopane isomerizations respectively, and the aromatization reaction was assumed to be irreversible. All three reactions were assumed to be first order and unimolecular. The aromatization rate is consistent with laboratory observations. The rate of hopane isomerization is not, and different reaction mechanisms probably dominate at different temperatures. The same constants can be used to predict the progress of the reactions in basins which have been uplifted by inversion, such as the Lower Saxony Basin in West Germany. The geochemical observations provide estimates of the amount and time of uplift which agree with those from geological studies. Geochemical observations from the eastern part of the Paris Basin suggest that this region has also been uplifted by between 1 and 2 km.

Summary. The submarine crystal-rich volcaniclastics of the Lower Devonian Merrions Tuff contain concentrations of angular to euhedral volcanic quartz, plagioclase and orthoclase. Lithic fragments, largely altered vitriclasts, are minor components and the average matrix content is 37.6%. Associated dacite/andesite and rhyodacitic lavas have average groundmass contents of 64.2%. Rare shards in the graded, pelitic tops of the thick volcaniclastic sedimentation units suggest that the mode of fragmentation originally was by explosive magmatic eruptions. The sedimentology of the volcaniclastics suggests subsequent redeposition by cold-state mass-flow processes. The volcaniclastics form an isotopically coherent suite and so redeposition must have occurred essentially contemporaneously with eruption.

The high crystal fragment concentration in these volcaniclastics is higher than lavas and ignimbrites and suggests some process whereby the groundmass fraction of the erupting magma is selectively removed, so concentrating the crystal fraction. The crystal-rich character of the crystal-tuffs is not simply due to explosive eruption. Several primary and secondary factors/processes could have interacted to ultimately produce the crystal-rich character, these being: (i) eruption of highly crystallized magmas (≤ 65% phenocrysts), (ii) concentration of crystals in primary eruption columns, (iii) concentration of crystals in any resulting pyroclastic flows, fine vitric ashes being elutriated out and being carried away in accompanying, trailing ash clouds, (iv) concentration of crystals in secondary eruption columns generated by the flow of hot pyroclastic flows into the ocean, and (v) concentration of crystals by the elutriation of fines into the trailing fine sediment cloud accompanying submarine mass flows resulting from the slumping of volcaniclastic aggregates from shallow marine/subaerial settings.

Regionally mappable, silicic, outflow ignimbrite sheets are interbedded with fluvial volcanogenic conglomerates and sandstones of the Late Carboniferous Currabubula Formation of north-eastern N.S.W. Four of the most widespread of these ignimbrites are described and defined as members. The oldest member is comprised of many thin, originally non-welded flow units. Interbedded accretionary lapilli horizons may indicate phreatomagmatic activity at vent during the eruption in addition to local rain-flushing of co-ignimbrite ash clouds. Of the three other members, two are multiple flow-unit sheets, 160–180 m in aggregate thickness. Substantial portions of these sheets were originally welded. The remaining member is a simple welded ignimbrite characterized by abundant spherulites and lithophysae. Irregular pre-eruption topography and contemporaneous erosion were responsible for thickness variations of the ignimbrite sheets. Some palaeovalleys, now delineated by the ignimbrites, persisted in spite of repeated pyroclastic influxes. Relic pumice, shards and crystal fragments are ubiquitous components of the sedimentary facies of the Currabubula Formation, and were probably derived from originally poorly consolidated pyroclastic deposits such as airfall ash layers and non-welded ignimbrites. No surface trace of the sources of these ignimbrites exists. However, internal facies, thickness variations and volumes of the ignimbrites indicate that they periodically emanated from a multiple-caldera terrain which was continuously active during the Late Carboniferous, and located several kilometres to the west of present exposures.

Summary. The kimberlite pipe at De Beers Mine, Kimberley is a complex, multiple structure. Three concordant argon-40/argon-39 age spectra have been obtained from samples from the 720 m level in the East Peripheral kimberlite. Each spectrum is dominated by a major plateau-feature between 84 and 89 Ma and none shows significant evidence of either excess argon or argon loss discrepancy. The available evidence suggests that the K-Ar age of normal magmatic emplacement-cooling of the East Peripheral kimberlite at De Beers Mine was close to 86 ± 2 Ma.