Evidence of bioalteration of natural basaltic rocks, presently receiving much attention, has so far been restricted to in situ oceanic crust and ophiolites in which fresh glass is still present. Here we present evidence of preserved bio-signatures in the chilled margin of pillow lavas of an old (443 Ma) ophiolite that has suffered pervasive lower greenschist facies metamorphism and deformation. X-ray mapping of initial alteration zones shows the remains of organic carbon associated with highly-concentrated Fe and S. Bioproduction of CO2 is further reflected in the low δ13C values of calcite extracted from pillow rims, compatible with microbe-induced fractionation during oxidation of organic matter. We attribute these effects to growth of sulphate-reducing bacteria at the early stage of ophiolite formation. During energy metabolism these bacteria reduce sulphate to H2S and oxidize organic matter to CO2 . Hydrogen sulphide will eventually react with iron and form pyrite, and carbon dioxide is precipitated as calcium carbonate. The results of this study may thus trigger the search for bio-signatures in glassy volcanic rocks of any age.

The Outer Hebrides Fault Zone is a major ESE-dipping detachment exposed within basement gneisses of the Archaean–Palaeoproterozoic Lewisian Complex, northwest Scotland. The fault zone exhibits a long-lived displacement history and was active during Proterozoic, end-Silurian, Carboniferous and Mesozoic times. The earliest deformation event preserved onshore was associated with top-to-the-NW ductile thrusting. A previous study proposed that thrust-related protomylonitic and mylonitic fabrics are cross-cut by amphibolites (‘Younger Basics’) and Laxfordian granite and pegmatite sheets. This evidence was used to suggest that ductile thrusting occurred during the Palaeoproterozoic Inverian event at c. 2500 Ma. Our observations demonstrate, however, that mylonitic fabrics within the ductile thrust zone are superimposed on all components of the gneiss complex including amphibolites and Laxfordian intrusions. It therefore follows that the Outer Hebrides Fault Zone cannot be older than c. 1685 Ma, the age of recently dated Laxfordian granites in the Outer Hebrides. Geochronological studies have shown that the basement blocks of the northern Outer Hebrides and Scottish mainland have different geological histories and were amalgamated during Proterozoic times at or after c. 1700 Ma. We propose that early ductile thrusting along the Outer Hebrides Fault Zone formed part of this amalgamation process leading to burial and reheating of the footwall gneisses in Lewis and north Harris. This would account for the c. 1100 Ma thermal event recorded by previous workers and implies that ductile thrusting along the Outer Hebrides Fault Zone is of Grenvillian age.

Mesozoic picritic and alkali basalts from central Lebanon represent a significant part of an extension-related Upper Jurassic to Upper Cretaceous discontinuous volcanic belt which occurs throughout the Middle East. Volcanism was associated with an episode of intraplate extension that followed a period of continental break-up, where Mesozoic micro-continental blocks separated from Gondwana as the Neotethys ocean opened in Jurassic times. This volcanic episode produced mafic lava flows ranging in thickness from 5 to 20 m, along with some minor pyroclastic flows. These flows are stratigraphically intercalated with thick carbonate platform deposits. The basalts are made up of about 15–20% olivine (Fo78–91), 30–35% clinopyroxene (salite), 40–50% plagioclase (An56–71) and opaque Fe–Ti oxides (∼5%). Geochemically, the rocks exhibit a relatively wide range of SiO2 (40.4 to 50.5 wt%) and MgO (5.1 to 15.5 wt%) contents, are relatively enriched in TiO2 (1.7 to 3.7 wt%) and vary in composition from alkali picrite and basanite to alkali basalt. The Mg numbers range from 0.56 to 0.70, with an average of 0.63. The rocks are enriched in incompatible trace elements such as Zr (86–247 ppm), Nb (16–66 ppm) and Y (19–30 ppm). Such compositions are typical of those of HIMU-OIB and plume-related magmas. The REE patterns are fractionated ((La/Yb)N = 11), LREE enriched, and are generally parallel to subparallel. Elemental ratios such as K/P (1.1–4.7), La/Ta (11–13), La/Nb (0.57–0.70), Nb/Y (0.68–1.55) and Th/Nb (0.20–0.36) suggest that crustal contamination was minor or absent. This may be related to a rapid ascent of the magma, in agreement with the nature (mafic, oceanic-like) and the small thickness (about 12 km) of the Mesozoic crust of the Eastern Mediterranean region. The 143Nd/144Nd isotopic compositions of the lavas range from 0.512826 to 0.512886, and 87Sr/86Sr from 0.702971 to 0.703669, suggesting a HIMU-like mantle source. Trace element compositions indicate a melt segregation depth of 100–110 km, well within the garnet lherzolite stability field. The geochemical characteristics of the rocks are typical of within-plate alkali basalts, and suggest that the magmas were derived from a fertile, possibly plume-related, enriched mantle source. Petrogenetic modelling indicates that the magmas were produced by very small degrees of batch partial melting (F = 1.5%) of a primitive garnet-bearing mantle source (garnet lherzolite).

Fossil plants are described from the upper part of the Devonian Lolén Formation, Sierra de la Ventana, Buenos Aires Province, Argentina, in the area of Estancia Las Acacias. The sequence is composed mainly of dark grey shales, and fossils were found in a single horizon where thin interlayered beds of fine reddish-brown micaceous sandstones appear where the environment of marine deposition became more shallow. The age of the Lolén Formation is presently established on the basis of brachiopods, these being characteristic elements of the Malvinokaffric realm from the Gondwana Lower Devonian (Emsian). The fossil plants are remarkably preserved given that they are in rocks that have undergone intense deformation. The plants are identified as Haplostigma sp. and Haskinsia cf. H. colophylla, and suggest a Middle Devonian age (Givetian) for the fossil-bearing levels. Haskinsia, identified on the basis of leaf morphology, is the first well-delimited Middle Devonian lycopsid genus described from Argentina, and the record from the most southerly palaeolatitude. During the Middle Devonian, Haskinsia was distributed in tropical, warm temperate and high southern latitude, ?cool temperate zones.

Melting of Torridonian arkoses, due to intrusion of shallow bodies of mafic melts on the Isle of Rum, was locally extensive, reaching up to 95 vol.%. Crystallization (to form granophyre) of these highly melted rocks was generally static in the vicinity of minor intrusions, although disruption of bedding is apparent in the aureole of the main mafic pluton. A distinctive millimetre- to centimetre-scale spherulitic texture developed during solidification of the partially melted arkose, in both the aureole of the main intrusion, and also in those of associated minor gabbro plugs. The spherulites are formed of radiating, fan-shaped intergrowths of plagioclase and quartz set in a matrix of quartz, plagioclase and K-feldspar. The importance of nucleation rates in determining texture development is demonstrated by a dominance of Na-rich compositions in the first feldspar to form, even in non-spherulitic rocks. It is suggested that the spherulites formed by the early growth of metastable plagioclase due to difficulties in nucleating feldspar.

Arc-flank volcaniclastic sedimentation in the Murihiku Terrane of New Zealand lasted about 120 million years from Late Permian to Early Cretaceous time. Despite the effects of pervasive zeolite-facies alteration, whole-rock geochemical parameters for sandstones, siltstones and tuffs record changes in source-rock composition, both in time and along the length of the depositional basin. Sandstones are considered to give a more reliable indication of the state of evolution of the source volcanic arc than do the siltstones. The siltstones commonly contain detrital white mica flakes that are generally lacking in the sandstones, and are possibly of distal continental origin. Some also contain very fine felsic ash particles. Average abundances and normalized multi-element diagrams are used to estimate proportions of three model end-member source constituents, average upper-continental crust (UCC), high-K rhyolite (RHY) and basaltic andesite (AND). Sandstone provenance for the Southland Syncline sector changed from a predominantly basaltic-andesite source in Late Permian to early Middle Triassic time, for example, UCC:RHY:AND = 0:17:83 in the Early to early Middle Triassic, to highly felsic in the Middle to Late Triassic, reaching UCC:RHY:AND = 2:74:24 in the Late Triassic Oretian Stage. A UCC component became increasing significant from latest Triassic upward and the proportion of mafic to felsic volcanism increased again, with UCC:RHY:AND = 15:30:35 in the Middle Jurassic Temaikan Stage. Mix modelling suggests that along-arc source proportions varied, with greater mafic and upper continental crust contributions in the northern Kawhia segment than in the Southland segment. These patterns may be explained by deposition at an oceanic Aleutian-type arc margin, with transition to a continental oceanic arc character induced either by arc evolution and dissection, forearc sliver translation, or underplating of rafted microcontinental fragments.

A new genus and species of primitive cryptodiran turtle, Siamochelys peninsularis n. g. n. sp., from the Middle Jurassic Mab Ching locality, in the southern peninsula of Thailand, is described on the basis of complete shells. They are characterized by a combination of primitive features (the presence of a pair of mesoplastra meeting on the midline) and a series of derived characters (loose plastron–carapace attachment, short diamond-shaped entoplastron, dorsal thickening of the lateral edge of the second to seventh peripheral plates, expanded seventh to eleventh peripheral plates, extension of the anal scute to the hyo-hypoplastral suture or onto the hypoplastron, midline sulcus sinusoidal), and thus closely resemble Chengyuchelys, from the Middle Jurassic of China, and more particularly Xinjiangchelys and its relatives from the Middle and Late Jurassic of China and Central Asia. This supports a Middle Jurassic age for the locality and suggests that the Sibumasu (Shan-Thai) block was in contact with the Asian mainland by that time.

Thick granitoid sheets represent a considerable percentage of Palaeozoic crustal sections exposed in Calabria. High thermal gradients are recorded in upper and lower crustal regional metamorphic rocks lying at the roof and base of the granitoids. Ages of peak metamorphism and emplacement of granitoids are mostly overlapping, suggesting a connection between magma intrusion and low-pressure metamorphism. To analyse this relationship, thermal perturbation following granitoid emplacement has been modelled. The simulation indicates that, in the upper crust, the thermal perturbation is short-lived. In contrast, in the lower crust temperatures greater than 700°C are maintained for 12 Ma, explaining granulite formation, anatexis and the following nearly isobaric cooling. An even longer perturbation can be achieved introducing the effect of mantle lithosphere thinning into the model.

Structures deforming Llandovery turbidites of the Gala Group in the Southern Uplands terrane are spectacularly exposed in the Berwickshire coastal section, southeastern Scotland. The upward-facing, upright to NW-vergent folds and associated structures appear to record a single regional phase of subhorizontal NW–SE contractional deformation, with a steeply dipping direction of bulk finite extension. These structures are markedly different from those developed in rocks correlated with the Upper Llandovery Hawick Group exposed some 5 km to the south in the Eyemouth–Burnmouth coastal section. Here a highly domainal system of sinistral transpressional strain occurs, with zones of steeply plunging curvilinear folds, clockwise cleavage transection and bedding-parallel sinistral detachment faults. The markedly different bulk strain patterns in the Berwickshire coastal sections are thought to reflect the regionally diachronous nature of transpressional deformation in the Southern Uplands terrane. There are striking similarities in the structures recognized in the Berwickshire coastal sections and those developed in stratigraphically equivalent units along strike in southwestern Scotland and Northern Ireland. This confirms the lateral structural continuity and correlation of tracts and tract boundaries along the entire length of the Southern Uplands terrane. The regional structure suggests that a phase of top-to-the-NW backthrusting and backfolding associated with the southern margin of the Gala Group outcrop marks the transition from orthogonal contraction to sinistral transpression in the Southern Upland thrust wedge during late Llandovery times.