The mid-Tournaisian black radiolarian cherts of the Lydiennes Formation are exposed in deep-shelf successions of the Puech de la Suque and Col des Tribes sections of the Mont Peyroux Nappe area in the Montagne Noire, southern France. This interval represents the mid-Tournaisian anoxic event that is also termed the Lower Alum Shale Event. This event is associated with a global marine transgression that was characterized by increased productivity and drastic facies changes from pelagic carbonate sedimentation to the widespread deposition of black organic-rich siliceous shales and radiolarites in many parts of the world. In the present study, high-resolution inorganic geochemistry and framboidal pyrite analyses were employed to decipher changes in depositional conditions during the mid-Tournaisian anoxic event in the Montagne Noire. The results show that the total organic carbon contents of sediments associated with the Lower Alum Shale Event vary from 0.09 to 1.9 wt %. These low to moderate total organic carbon contents, high U/Th, low Corg/P and intermediate V/Cr ratios, enrichment in redox-sensitive trace elements, such as U, Mo and V, as well as varying sizes of pyrite framboids, indicate periodic dysoxic to anoxic bottom-water conditions during deposition of the studied sediments. Anomalous Hg spikes (>500 ppb) are also reported in the mid-Tournaisian deep-water marine succession of the Montagne Noire in the present study, which confirm a possible influence of increased regional volcanic activity during this environmental turnover.

In the Yili terrane at Awulale mountain, most shoshonitic lavas are related to post-collision extension and were extruded during the Late Carboniferous to Early Permian (310–280 Ma). Herein, we evaluate a small-volume occurrence of shoshonitic magmas in the southern Yili terrane formed c. 346 Ma ago. The high MgO (Mg#) and positive Hf isotope values of the shoshonitic magmas indicate the input of juvenile mantle-derived material. Still, their high Ba–Sr signatures were likely inherited from the partial melting of previously metasomatized lithospheric mantle. We argue the shoshonitic magmatic activity recorded a syn-subduction extensional history in the Yili terrane. This interpretation is consistent with the magmatic records from Early Carboniferous A-type granite and magnesian andesite found in the Zhaosu–Adentao–Dahalajunshan area of the southern Yili terrane. Combined with the geological development in this area, we propose that the emergence of the shoshonitic rocks records either the retreat of the trench or the rollback of the Junggar oceanic slab that occurred at or before the 346.1 ± 3.1 Ma age of the rocks.

Subduction-related kimberlite-borne eclogite xenoliths of the Precambrian age may provide significant information about the evolution and recycling of a subducting crust as exhumed/orogenic eclogites of the pre-Mesoproterozoic time-frame are globally rare. In this paper, we report a kimberlite-borne eclogite xenolith from the diamondiferous Kalyandurg kimberlite cluster of the Eastern Dharwar Craton, India, which contains a plethora of ultra-high-pressure minerals such as coesite, majoritic garnet, and supersilicic K-rich omphacite. The presence of these ultra-high-pressure minerals is confirmed by in situ X-ray diffractometry, laser Raman spectra and electron probe microanalysis. The presence of coesite undisputedly pinpoints a subduction origin for the eclogite at ∼2.8 GPa pressure, which corresponds to ∼100 km depth. The geothermobarometric estimations involving garnet–omphacite–kyanite–coesite reveal that such an eclogitic assemblage equilibrated at ∼5–8 GPa (∼175–280 km) pressure during ultra-deep subduction. The textural relationship between omphacite, coarse-grained garnet and majoritic garnet coupled with the laser Raman spectra and geobarometric estimations obtained from the majoritic garnet demonstrate that the majoritic garnet formed at ∼8–19 GPa (∼280–660 km) owing to disassociation of omphacite and coarse-grained garnet to majoritic garnet during increment of pressure up to the mantle transition zone. Thus, the mineralogical and geothermobarometric data suggest that the studied eclogite possibly travelled down to the mantle transition zone before it was rapidly carried up by a pre-Mesoproterozoic mantle plume, and subsequently entrained as a xenolith by the Mesoproterozoic (∼1.1 Ga) kimberlite.

The Pliocene–Quaternary volcanic rocks which outcrop between Qorveh and Bijar are part of post-collisional within-plate volcanic activity in northern Iran. These mafic alkaline rocks form part of the northern arm of the Sanandaj–Sirjan (Hamedan–Tabriz) zone. Thermobarometry on equilibrium clinopyroxene – whole-rock pairs yields pressures and temperatures of 4–6 (±1.8) kbar and 1182–1213 (±27) °C, respectively; olivine – whole-rock (melt) equilibrium thermometry yields crystallization temperatures of 1212–1264 (±27) °C. Field relationships, including the presence of pyroxenitic xenoliths, and geochemical evidence (e.g. high FeO/MnO, and low CaO compared to lavas derived from peridotite sources) suggest a pyroxenitic mantle source for the studied rocks. Variation of trace elements and isotopic ratios (i.e. Ce/Pb, Ba/La, 87Sr/86Sr) indicate that this pyroxenite mantle source was generated by interaction between melted sediments of the subducted Neo-Tethys slab with ambient peridotitic lithospheric mantle. The resulting metasomatized lithosphere is denser and has a lower viscosity than the peridotitic mantle, and tectonic disturbance can cause it to fall into the depths of the mantle. The descending volatile-rich material starts to melt with increasing temperature. Modelling of rare earth element (REE) abundances suggests that <1 % partial melting of the descending pyroxenite could create the Plio-Quaternary alkali basaltic magma of the Qorveh–Bijar. The geochemical evidence for lithospheric foundering, and hence drip magmatism, in the Qorveh–Bijar volcanic belt is supported by seismographic studies indicating thinned lithosphere beneath the study area.

Efficient extraction of oxygen from ambient waters played a critical role in the development of early arthropods. Maximizing gill surface area enhanced oxygen uptake ability but, with gills necessarily exposed to the external environment, also presented the issue of gill contamination. Here we document setae inserted on the dorsal surface of walking legs of the benthic-dwelling middle Cambrian Olenoides serratus and on the gill shaft of the Late Ordovician Triarthrus eatoni. Based on their physical positions relative to gill filaments, we interpret these setae to have been used to groom the gills, removing particles trapped among the filaments. The coordination between setae and gill filaments is comparable to that seen among modern crustaceans, which use a diverse set of setae-bearing appendages to penetrate between gill filaments when grooming. Grooming is known relatively early in trilobite evolutionary history and would have enhanced gill efficiency by maximizing the surface area for oxygen uptake.

Many studies have improved our understanding of the mode of preservation at the Crato fossil Lagerstätte. The high degree of preservation of the Crato mineralized insects is thought to be a consequence of the diffusion of ions through carcasses and envelopment by bacteria that, in turn, created microenvironmental conditions that led to mineralization, mainly pyritization. Pyritized insects have been oxidized by in situ weathering to more stable oxide/hydroxy minerals during Quaternary time. This transformation is essential to maintain the palaeontological information acquired during microbially induced pyritization in an oxidizing atmosphere. However, intense weathering can diminish or obscure the morphological fidelity, and little attention has been paid to the post-diagenetic processes experienced by these fossils. Here, we aim to determine the degree of alteration undergone by Crato pyritized insects using the following combination of analytical tools: scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transform infrared and Raman spectroscopy. Our results show that well-preserved insects are preferentially replaced by haematite and poorly preserved fossils are replaced by goethite. In addition, we recorded three types of post-diagenetic alteration: insects with iron-oxide overgrowths; insects associated with black coatings, sometimes with the formation of dendrites; and insects preserved as an impression, where only the outline of the body remains. All of these alterations have the potential to distort or tarnish palaeontological information. Here, we measured the effects of such telodiagenetic alterations at macro and micro scales. Therefore, this taphonomic approach has wide applicability wherever fine-grained deposits bearing mineralized insects are found.

Fossils are more and more used in phylogenetic evolutionary studies either for clade calibration, or as terminals in a dataset including morphological characters. The strength of these methodological advances relies however on the quality and completeness of the fossil record. For crickets (Insecta, Orthoptera, Gryllidea), few ancient (pre-Cenozoic) well-preserved fossils are known, except for isolated wings often classified in purely fossil groups and a few fossils found in Cretaceous amber. Here, we present two remarkable fossils from mid-Cretaceous amber of France, that were imaged using X-ray synchrotron microtomography and exhibit an exquisite preservation allowing description with a precision similar to that of extant taxa. Palaeonemobius occidentalis Laurent and Desutter-Grandcolas, gen. nov., sp. nov. and Picogryllus carentonensis Josse and Desutter-Grandcolas, gen. nov., sp. nov. are the oldest representatives of the Nemobiinae and Podoscirtinae subfamilies of the Trigonidiidae and Oecanthidae families respectively. P. carentonensis Josse and Desutter-Grandcolas, gen. nov., sp. nov. is also the smallest adult male with a full stridulatory apparatus ever documented in crickets (body length 3.3 mm), and the first taxon of the cricket clade for which male genitalia can be partly described. We discuss the significance of Cretaceous fossils of crickets for future evolutionary studies of this clade.

Loose limestone blocks of a newly recognized hydrocarbon-seep deposit from the lower Oligocene Jansen Creek Member of the Makah Formation were collected on a beach terrace close to the mouth of Bullman Creek in Washington State, USA. The limestone consists largely of authigenic carbonate phases, including 13C-depleted fibrous cement forming banded and botryoidal crystal aggregates with δ13C values as low as –23.5 ‰. Lipids extracted from the limestone yielded molecular fossils of anaerobic methanotrophic archaea (ANME), dominated by compounds of an ANME-2/DSS consortium with δ13C values as low as −106 ‰, indicating formation at an ancient methane seep. The fossil inventory of the seep deposit is remarkable, consisting almost solely of echinoid remains, whereas typical seep biota are absent. Varying preservation of the echinoid fossils indicates parautochthonous deposition, corroborated by evidence for high fluid flow at the ancient seep, possibly responsible for displacement of echinoids after death. Although a full taxonomic description of the echinoids cannot be given, almost all fossils were assigned to one taxon of irregular spatangoids, except for a single regular echinoid. Abundance and lifestyle of the irregular spatangoids in the Bullman Creek echinoid seep deposit resemble those of the fossil Tithonia oxfordiana from an upper Jurassic seep deposit in France and extant Sarsiaster griegii from modern seeps in the Gulf of Mexico. The Bullman Creek echinoid deposit probably represents a fossil analogue of the Gulf of Mexico Sarsiaster mass occurrence, indicating that the adaptation of spatangoid echinoids to chemosynthesis-based ecosystems ranges back at least to the earliest Oligocene.

The Precambrian Southern Granulite Terrane (SGT) of south India is well-known for the preservation of high- to ultrahigh-temperature (HT-UHT) granulites, prominently exposed in its central part forming a linear belt referred to as the Kambam UHT belt. This belt also hosts widespread occurrences of mafic granulites that are observed in close spatial association with the HT-UHT granulites. This study presents detailed petrology, geochemistry and geochronology of representative mafic granulites from the area to understand their petrogenesis and tectonic setting. The results demonstrate that mafic granulites are low- to medium-K tholeiites, with continental arc affinity, formed by the partial melting of a subduction-modified enriched mantle source. The composition of the parent mantle source is modelled with a spinel/garnet lherzolite contribution ratio between 100/0 and 70/30, suggesting the mixing of spinel and garnet bearing melts during asthenosphere upwelling. Zircon U–Pb geochronology of mafic granulites constrains their emplacement between 612 Ma and 625 Ma, that subsequently underwent metamorphism between 581 Ma and 531 Ma. This overlaps with the timing of HT-UHT metamorphism in the Kambam UHT belt bracketed between 593 and 532 Ma. Zircon Hf isotopic studies reveal parent magma generation from reworked melting sources involving Archean and Proterozoic components. These results propose an alternative heat source for the formation of HT-UHT granulites in the Kambam UHT belt which can be designated as a major terrane boundary within the SGT.

This paper focuses on one orogenic belt that formed during the Rinconada phase on the final stage of the Famatinian orogeny, between 445 and 410 Ma, which is well exposed at Sierra de Ramaditas and neighbouring ranges in western Argentina. The Ramaditas Complex is formed by metasedimentary and meta-ultrabasic rocks and amphibolites. This complex forms the upper nappe of a thrust stack resulting from westward thrusting. Deformation consists of an early high-temperature S1 foliation (stromatic migmatites), coeval with thrusting and metamorphism. Metamorphism attained peak P–T conditions of 6.0–6.9 kbar and 795–810 °C, at c. 440 Ma, i.e. coincident with the Rinconada orogenic phase. The lower unit and intermediate nappes crop out in the nearby sierras of Maz and Espinal and underwent low- to medium-grade Silurian metamorphism, respectively, together with the upper nappe, defining an inverted Barrovian-type metamorphism with T decreasing and P increasing downwards across the thrust stack (i.e. westward). We argue that the Rinconada orogenic phase developed near the continental margin of SW Gondwana, during a magmatic lull following accretion of the Precordillera terrane to the continental margin at c. 470 Ma. The active margin jumped to the west after accretion, and flat-slab subduction resumed in the early Silurian, provoking thrusting and imbrication of nappe stack under the still hot root (800–900 °C) of the older Famatinian magmatic arc. This ‘hot-iron’ process explains both the inverted Barrovian-type metamorphism and the missing overburden of 21 to 24 km implied by the P estimate.

This paper reports geochemical characteristics of mafic gneisses and granulites collected from four localities in central Dronning Maud Land to evaluate the tectonic setting of their precursor rocks. Precursor rocks for the mafic gneisses and granulites in central Dronning Maud Land were formed in different geological backgrounds and tectonic settings. The mafic gneisses and granulites in the Schirmacher Hills were derived from basaltic rocks in a back-arc setting. Published U–Pb zircon ages and the geochemical variation of the basement rocks indicate their emplacement between 800 and 650 Ma, close to peak metamorphism. While similar protoliths were recognized in the inland nunataks of Hochlinfjellet, in Filchnerfjella the mafic gneisses/granulites were derived from basaltic rocks formed in marginal continental arcs or island arcs. Highly disturbed trace-element patterns indicate that the metamorphic process influenced the geochemical composition during the prograde metamorphic stage. Our results imply that the outcrops in central Dronning Maud Land with different metamorphic ages contain mafic gneisses/granulites from precursor rocks formed under different tectonic settings.

We present U–Pb dates from peridotitic pyrope-rich garnet from four mantle xenoliths entrained in a kimberlite from Bultfontein, South Africa. Garnet dates magmatic emplacement due to the high mantle residence temperatures of the source material prior to eruption, which were most likely above the closure temperature for the pyrope U–Pb system. We determine a U–Pb date of 84.0 ± 8.1 Ma for the emplacement of the Bultfontein kimberlite from garnet in our four xenolith samples. The date reproduces previous dates obtained from other mineral-isotope systems (chiefly Rb–Sr in phlogopite). Garnet can be dated despite extremely low concentrations of U (median ∼0.05 μg/g), because concentrations of common Pb are often low or non-detectable. This means that sub-concordant garnets can be dated with moderate precision using very large laser-ablation spots (130 μm) measured by quadrupole inductively coupled plasma – mass spectrometry (LA-Q-ICP-MS). Our strategy demonstrates successful U–Pb dating of a U-poor mineral due to high initial ratios of U to common Pb in some grains, and the wide spread of isotopic compositions of grains on a concordia diagram. In addition, the analytical protocol is not complex and uses widely available analytical methods and strategies. This new methodology has some advantages and disadvantages for dating kimberlite emplacement versus established methods (U-based decay systems in perovskite and zircon, or Rb- or K-based systems in phlogopite). However, this method has unique promise for its potential application to detrital diamond prospecting and, more speculatively, to the dating of pyrope inclusions in diamond.

The Shyok Suture Zone is an oceanic remnant of the Neo-Tethyan ocean sandwiched between the Ladakh Batholiths to the south and Karakoram Batholith to the north. The Tirit granitoids in this suture are dark-coloured, relatively rich in ferromagnesian minerals and range from granodiorite–tonalite to gabbro–diorite in composition. Mafic igneous enclaves are quite common and they are intruded by NW–SE parallel doleritic and aplitic dykes. The Tirit granitoids have a wide range of major oxide compositions (SiO2 = 52.1–72.11 wt %, TiO2 = 0.21–1.23 wt %, Al2O3 = 11.42–13.52 wt %, MgO = 1.69–10.69 wt % and CaO = 3.24–9.31 wt %) and show calc-alkaline, metaluminous, I-type characteristics, transitional between primitive and mature arc continental plutons. Rare earth elements (REE) show considerable enrichment in light REE (LREE) as compared to the heavy REE (HREE). Late Cretaceous U/Pb dates (74–68 Ma) show that they formed during the pre-collision northward movement of India. The Tirit dykes are only slightly younger and probably part of the same episode.