The South Dehshir Ophiolite, exposed along the southwestern margin of the Central Iranian microcontinent, comprises a mantle and a crustal sequence. This massif contains serpentinized peridotites, gabbros and diabase sheeted dykes cutting across wherlite, pegmatitic gabbro and plagiogranite, and is tectonically covered by radiolarites, pelagic limestones with Late Cretaceous microfauna and lavas. Under a microscope, the gabbros exhibit mesocumulate, adcumulate and hetradcumulate textures presumably formed in open magma chambers. Hypabyssal and lava samples show tholeiitic to calc-alkaline affinities, and their compositions cluster in the fields of arc or supra-subduction zone magmatism. Binary diagrams display compositional trends of magmatic differentiation, plotting away from the mid-ocean-ridge basalt (MORB) (tholeiitic) trend and following the arc (calc-alkaline) trend. Rare Earth element (REE) and spider diagrams display various enrichments at different levels. Moderate enrichment of the large-ion lithophile elements (LILE; Rb, Ba, Th, U, La, Sr) relative to the high-field-strength elements (HFSE; Nb, Ta) and slight depletion of Ti and Zr in some patterns may be attributed to variable influences of subduction components over the depleted mantle wedge. Elemental ratios display evidence for the contribution of both fluids and melt released from the subducted slab. Few patterns display ocean-island basalt (OIB) characteristics, possibly attributed to the involvement of local mantle plumes on the partial melting of the mantle wedge. This evidence indicates that the crustal rocks of the South Dehshir Ophiolite formed in a supra-subduction zone.

Recent finds of tetrapod ichnites in the red-bed and volcaniclastic succession of the Iberian Pyrenean Basin permits an assessment of the faunal diversity and palaeoenvironment of a late early Permian setting. The tetrapod ichnoassemblage is inferred with the aid of photogrammetry and constituted by Batrachichnus salamandroides, Limnopus isp., cf. Amphisauropus (these three ichnotaxa present associated swimming traces, assigned to Characichnos), cf. Ichniotherium, Dromopus isp., cf. Varanopus, Hyloidichnus isp. and Dimetropus leisnerianus. These ichnotaxa suggest the presence of temnospondyls, seymouriamorphs, diadectomorphs, araeoscelids, captorhinids and synapsid pelycosaurs as potential trackmakers. These faunas correlate to the late early Permian. Two ichnoassociations correspond to two different palaeoenvironments that were permanently or occasionally aquatic (meandering fluvial systems and unconfined runoff surfaces, respectively). Ichnotaxa in the fluvial system is more diverse and abundant than in the runoff surfaces system. The Iberian Pyrenean ichnoassemblage reveals the faunistic connection and similarities among nearing basins (Spain, southern France and Morocco) differing from the Central European basins (i.e. German Tambach Formation). Based on the palaeogeography and the climate models of the early Permian, we suggest the correlation of ichnofaunal composition with different palaeoclimate biomes. This results in a diffuse boundary of Gondwana–Laurasia land masses, indicating no geographic barriers but a possible climate control on the faunal distribution. Further studies, integrating data from distant tracksites, should refine these biome boundaries.

A new plant of Late Devonian (Famennian) age, Melvillipteris quadriseriata gen. et sp. nov., is reported from Melville Island, Nunavut, Canadian Arctic Archipelago. Main axes and two orders of lateral branches are recognized. The main axes are monopodial in habit, with a zigzag and/or upright appearance and dense adventitious roots attached on some internodes. First-order branches are inserted on the main axes in distichous pairs, showing a quadriseriate pattern (i.e. alternate pairs); they bear one or two sterile ultimate appendages on the proximal portions, and then distally bear alternate second-order branches. Second-order branches bear alternate ultimate appendages which may be fertile or sterile; the sterile ultimate appendages are composed of one or two successive dichotomies, terminating in oppositely recurved tips, and fertile appendages show an elaborate branching system. Each fertile appendage has an initial dichotomy forming two sister branches, each of which further divides three or four times to produce ultimate divisions terminated by sporangia. Two to four small fusiform sporangia are grouped in a truss which is supplied by penultimate division of the fertile appendage. The sporangia have a pointed tip and a longitudinal dehiscence. This new plant resembles other plants with a quadriseriate branching pattern (e.g. Rhacophyton Crépin, Cephalopteris Nathorst, Protocephalopteris Ananiev, Ellesmeris Hill, Scheckler & Basinger and Protopteridophyton Li & Hsü), and is assigned to the Rhacophytales. Its similarity to and divergence from the rhacophytaleans, cladoxylopsids and other related plants are discussed.

The sediments of organic-rich oil shales in the Bilong Co. area can be correlated with those of the early Toarcian anoxic black-shale events in Europe. The Bilong Co. sediments are rich in trace elements Se, Mo, Cd, As and Ni, and, to a lesser extent, Li, F, V, Co, Cu, Cs, Hg and Bi, in comparison to the upper continental crust. Thirty-two oil shale samples were collected from the Bilong Co. oil shale to evaluate the controlling factors of trace-element enrichment in the lower Toarcian anoxic sediments. Minerals identified in the Bilong Co. oil shale include calcite, quartz, illite, feldspar and dolomite, and trace amounts of siderite, magnesite, halite, haematite, zeolite, amphibole, gypsum, anhydrite, apatite, pyrite, sphalerite, barite and mixed-layer illite/smectite. Mineralogical and geochemical data show that seawater and hydrothermal activities are the dominant influences on the mineralogical composition and elevated trace-element concentrations in the oil shale. The clay minerals, quartz and feldspar in the Bilong Co. oil shale were derived from the Nadi Kangri volcanic rocks. Input of sediment from this source may have led to enrichment of trace elements Li, Cr and Cs in the oil shale. Carbonate minerals and nodular- and framboidal-pyrite are authigenic phases formed from seawater. The enrichment of V, Co, Ni, Cu, Mo, As, Se, Bi and U in the oil shale was owing to marine influence. Barite, sphalerite and fracture-filling pyrites were derived from hydrothermal solutions. High concentrations of F, Zn and Cd were probably derived from hydrothermal fluids.

The earliest known macroborings (Trypanites) from Baltica occur in early Cambrian phosphatized siltstone pebbles from Kopli quarry in Tallinn, Estonia. Trypanites borings also occur in Furongian phosphatized siltstone pebbles in northern Estonia. The intensity of bioerosion on these Cambrian pebbles is low compared to analogue substrates from Ordovician deposits of Baltica. These bored phosphatized siltstone pebbles show that bioerosion of hard substrates occurred in relatively cold climate epicontinental seas during Cambrian time.

The Collserola Range includes a representative stratigraphic succession of the Palaeozoic of the central part of the Catalan Coastal Ranges, ranging from Cambro-Ordovician to Carboniferous times. In this paper we present an up-to-date review of the stratigraphy and structure of the Palaeozoic of the Collserola Range, and provide geochemical and Sm–Nd isotope data to constrain the pre-Mesozoic crustal evolution of this sector of the Variscan Belt. Geochemical compositions indicate that the Palaeozoic siliciclastic rocks of the Collserola Range were fed by a relatively mature heterogeneous source of sediment, comprising quartz-rich sediments to intermediate igneous rocks. The siliciclastic rocks of the Collserola Range show great geochemical affinity with the turbidites of passive margins. The Sm–Nd signature of the siliciclastic rocks is compatible with those of the Palaeozoic and late Proterozoic fine-grained siliciclastic rocks of the neighbouring terrains of SW Europe. There is a small decrease of the εNdT with decreasing age of sedimentation from the Cambro-Ordovician to the Carboniferous, suggesting an increase of the amount of more ‘juvenile’ material. The presence of small volumes of alkaline basaltic rocks provides evidence for the input of juvenile material in the early Palaeozoic basin and suggests that an extensional tectonic regime prevailed during the Cambro-Ordovician sedimentation. From a geodynamic point of view, the overall analysis of the data implies that the Palaeozoic rocks of the Catalan Coastal Ranges were part of the Northern Gondwana passive margin before the closure of the Rheic Ocean and the subsequent Variscan Orogeny.

Fractures are important for shale-gas reservoirs with low matrix porosity because they increase the effective reservoir space and migration pathways for shale gas, thus favouring an increased volume of free gas and the adsorption of gases in shale reservoirs, and they increase the specific surface area of gas-bearing shales which improves the adsorption capacity. We discuss the characteristics and dominant factors of fracture development in a continental organic matter-rich shale reservoir bed in the Yanchang Formation based on observations and descriptions of fracture systems in outcrops, drilling cores, cast-thin sections and polished sections of black shale from the Upper Triassic Yanchang Formation in the SE Ordos Basin; detailed characteristics and parameters of fractures; analyses and tests of corresponding fracture segment samples; and the identification of fracture segments with normal logging. The results indicate that the mineral composition of the continental organic-matter-rich shale in the Yanchang Formation is clearly characterized by a low brittle mineral content and high clay mineral content relative to marine shale in the United States and China and Mesozoic continental shale in other basins. The total content of brittle minerals, such as quartz and feldspar, is c. 41%, with quartz and feldspar accounting for 22% and 19% respectively, and mainly occurring as plagioclase with small amounts of carbonate rocks. The total content of clay minerals is high at up to 52%, and mainly occurs as a mixed layer of illite-smectite (I/S) which accounts for more than 58% of the total clay mineral content. The Upper Triassic Yanchang Formation developed two groups of fracture (joint) systems: a NW–SE-trending system and near-E–W-trending system. Multiple types of fractures are observed, and they are mainly horizontal bedding seams and low-dip-angle structural fractures. Micro-fractures are primarily observed in or along organic matter bands. Shale fractures were mainly formed during Late Jurassic – late Early Cretaceous time under superimposed stress caused by regional WNW–ESE-trending horizontal compressive stress and deep burial effects. The extent of fracture development was mainly influenced by multiple factors (tectonic factors and non-tectonic factors) such as the lithology, rock mechanical properties, organic matter abundance and brittle mineral composition and content. Specifically, higher sand content has been observed to correspond to more rapid lithological changes and more extensive fracture development. In addition, higher organic matter content has been observed to correspond to greater fracture development, and higher quartz, feldspar and mixed-layer I/S contents have been observed to correspond to more extensive micro-fracture development. These results are consistent with the measured mechanical properties of the shale and silty shale, the observations of fractures in cores and thin-sections from more than 20 shale-gas drilling wells, and the registered anomalies from gas logging.

Nearly 70 new Nd isotope analyses are presented for plutonic orthogneisses from the Grenvillian Central Metasedimentary Belt (CMB) in order to test a back-arc aulacogen model for its origin. Nd isotope signatures of metaplutonic rocks are used as probes of the formation age of the crust at depth, revealing sharp boundaries between old crustal blocks and juvenile (1.2–1.35 Ga) Elzevirian-age crust. Firstly, a hidden block of old crustal basement is revealed between areas of juvenile crust south of Douglas, Ontario. Secondly, TDM ages refine the boundary between juvenile crust and old basement (1.35–1.55 Ga) within the Weslemkoon batholith, showing this pluton to be a polygenetic stitching pluton that straddles a hidden crustal boundary. Finally, the CMB boundary zone is shown to form a sharp age boundary between juvenile and old crustal domains, and is interpreted as a reactivated rift-bounding normal fault. When the distribution of rift-related alkaline rocks is compared with these crustal boundaries, the Bancroft nepheline syenite suite is centrally located in a juvenile ensimatic zone between blocks of old basement. Such a location, near the axis of a juvenile crustal segment, implies emplacement late in the rifting process. Similarly, the Blue Mountain nepheline syenite appears to post-date an earlier rifting event to the southeast. Hence, a multi-stage model is proposed for the evolution of a back-arc aulacogen, which is consistent with the distribution of marble and volcanic/plutonic units in the CMB. The model places the Bancroft nepheline syenites in a precise plate tectonic context for the first time.

Central Mexico was subject to active tectonics related to subduction processes while it occupied a position in western equatorial Pangea during early Mesozoic time. The subduction of the palaeo-Pacific plate along the western North American and South American active continental margins produced volcanic arc successions which were subsequently rifted and re-incorporated to the continental margin. In this context, the fringing arcs are important in unravelling the continental accretionary record. Using petrographic analysis, detrital zircon geochronology and structural geology, this paper demonstrates that the Guerrero Arc (Guerrero Terrane) formed on top of a felsic volcaniclastic unit (Middle Jurassic La Pimienta Formation) and siliciclastic strata (Upper Triassic Zacatecas Formation and Arteaga Complex) of continental Mexican provenance, deposited across the continental margin and oceanic substrate. This assemblage was rifted away from continental Mexico to form an intervening oceanic assemblage (Upper Jurassic – Lower Cretaceous Las Pilas Volcanosedimentary Complex of the Arperos Basin), then accreted back more or less at the same place, all above the same east-dipping subduction zone. The accretion of the Guerrero Arc to the Mexican continental mainland (Sierra Madre Terrane) caused the deposition of a siliciclastic unit (La Escondida Phyllite), which recycled detritus from the volcaniclastic and siliciclastic underlying strata.

An extensive study of the microstructure, nanostructrure and crystallographic properties of six taxa belonging to four different genera of Devonian and Carboniferous Syringoporicae showing dense phaceloid (Pleurosiphonella), pseudocerioid (Neomultithecopora) and cerioid growth patterns (Roemeria and Roemeripora) has been done in order to disclose the similarities and differences in the growth processes at the biomineral scale and understand the growth processes that provide organisms with an evolutionary advantage to colonize different habitats. All the skeletons have similarities regarding the biocrystallization process, showing that the Syringoporicae skeletons are a product of matrix-mediated biocrystallization. Micro- and nanotextural features are common in all of the skeletons studied, showing that they were composed of hierarchical structures. All studied taxa possess a complex nanostructure composed of co-oriented rounded nanocrystals with different sizes and morphologies, depending on the taxon. The identified microstructures include granules, lamellae, fibres and hyaline elements. The crystallographic techniques demonstrate that all of them except the hyaline elements are biogenic in origin. Granules could be aborted fibres during the growth of two corallites in contact. On the other hand, the study of the biomineral properties suggests that the skeleton structure is a reflection of the genetic code. The median lamina was formed by the joint crystallization of both polyps at the same time. The variation in the internal structural organization (phaceloid, pseudocerioid or cerioid) was conditioned by the environment (stressful situations or feeding strategies); on the contrary, the final structure is controlled by genetics and their crystallographic properties are characteristic for each internal structural organization.

By using strontium isotopic ratios of dental enamel from molars, we were able to reconstruct the migration context for three individuals of a Columbian mammoth population (Mammuthus columbi) around Laguna de las Cruces, San Luis Potosí, central México. A three-step leaching procedure was applied to eliminate secondary Sr contributions in the molar enamel. One of the studied individuals showed 87Sr/86Sr ratios similar to those obtained from soils and plants from Laguna de las Cruces and was identified as local, whereas the other two mammoths had different molar 87Sr/86Sr values, indicative of migration and mobility contexts.

Early faunas with Watsonella crosbyi with or without Aldanella spp. have been equated with the Siberian Tommotian Stage (uppermost Terreneuvian) and used to define a proposed Cambrian Stage 2 base. Much earlier Terreneuvian occurrences are now shown by recovery of these micromolluscs below the I’ carbon excursion in the Siberian ‘Nemakit-Daldynian’ Stage and comparable δ13C excursions in the middle Meishucunian (China) and middle Chapel Island Formation (Avalonia). This δ13C excursion, a reliable Stage 2 marker, lies in a c. 10 Ma interval in the Cambrian Radiation in which long-ranged small shelly fossil taxa provide limited biostratigraphic resolution.