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Ore genesis of the Huangshaping skarn W–Mo–Pb–Zn deposit, southern Hunan Province, China: insights from in situ LA-MC-ICP-MS sulphur isotopic compositions

Published online by Cambridge University Press:  07 April 2022

Teng Ding Open the ORCID record for Teng Ding [Opens in a new window] ,
Tingting Tan ,
Jia Wang ,
Dongsheng Ma ,
Jianjun Lu ,
Rongqing Zhang  and
Bin Wu
Teng Ding*
Affiliation:
Institute of Marine Geology, College of Oceanography, Hohai University, Nanjing210098, China State Key Laboratory for Mineral Deposits Research, Nanjing University, Nanjing210046, China
Tingting Tan
Affiliation:
Institute of Marine Geology, College of Oceanography, Hohai University, Nanjing210098, China
Jia Wang
Affiliation:
Institute of Marine Geology, College of Oceanography, Hohai University, Nanjing210098, China
Dongsheng Ma
Affiliation:
State Key Laboratory for Mineral Deposits Research, Nanjing University, Nanjing210046, China
Jianjun Lu
Affiliation:
State Key Laboratory for Mineral Deposits Research, Nanjing University, Nanjing210046, China
Rongqing Zhang
Affiliation:
State Key Laboratory for Mineral Deposits Research, Nanjing University, Nanjing210046, China
Bin Wu
Affiliation:
State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang330013, China
*
Author for correspondence: Teng Ding, Email: [email protected]
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Abstract

The Huangshaping deposit is unique in southern Hunan Province, China, as it hosts economic reserves of both W–Mo and Pb–Zn mineralization, which are usually associated with granite and granodiorite porphyry in this area, respectively. This study reports results of in situ LA-MC-ICP-MS sulphur isotopic composition analyses conducted on sulphides from both W–Mo and Pb–Zn mineralization from the Huangshaping deposit with the aim of constraining ore genesis for this deposit. All samples from the proximal W–Mo mineralization have relatively uniform and high δ34S values (8.7 ‰ to 16.0 ‰), close to the range for carbonate sediments in this deposit (13.8 ‰ to 18.1 ‰). These patterns suggest that the granite porphyry in this deposit was the sulphur source for W–Mo mineralization, and that the assimilation of evaporite from the carbonate sediments led to the high δ34S values of the granite porphyry. Sulphides from the Pb–Zn mineralization have δ34S values (2.2 ‰ to 10.3 ‰) lower than those of the W–Mo mineralization, and generally increase in this paragenetic order, with the lowest δ34S values being similar to those of the basement (3.8 ‰ to 7.7 ‰). These patterns indicate that the original sulphur for the Pb–Zn mineralization was most likely derived from the basement, with input of sulphur from the carbonate sediments increasing during the evolution of ore-forming fluids. On the basis of the measured sulphur isotopic compositions, it is suggested that the ore-forming materials for the W–Mo mineralization were derived from the granite porphyry, whereas ore-forming materials extracted from the basement dominated the Pb–Zn mineralization.

Keywords

W–Mo–Pb–Znsulphur isotopegranite porphyrybasementHuangshaping
Type
Original Article
Information
Geological Magazine , Volume 159 , Issue 6 , June 2022 , pp. 981 - 995
Copyright
© The Author(s), 2022. Published by Cambridge University Press

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