Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-22T15:59:52.483Z Has data issue: false hasContentIssue false

Fractures, fluid flow and inherited structures in geothermal systems: inputs from the Fe-ore deposits of eastern Elba Island (Northern Apennines, Italy)

Published online by Cambridge University Press:  30 May 2022

Martina Zucchi*
Affiliation:
Department of Earth and Geoenvironmental Sciences, University of Bari, Bari, Italy
Andrea Brogi
Affiliation:
Department of Earth and Geoenvironmental Sciences, University of Bari, Bari, Italy IGG-CNR, Institute of Geosciences and Earth Resources, Pisa, Italy
Domenico Liotta
Affiliation:
Department of Earth and Geoenvironmental Sciences, University of Bari, Bari, Italy IGG-CNR, Institute of Geosciences and Earth Resources, Pisa, Italy
Alfredo Caggianelli
Affiliation:
Department of Earth and Geoenvironmental Sciences, University of Bari, Bari, Italy
Andrea Dini
Affiliation:
IGG-CNR, Institute of Geosciences and Earth Resources, Pisa, Italy
Gennaro Ventruti
Affiliation:
Department of Earth and Geoenvironmental Sciences, University of Bari, Bari, Italy
Giovanni Ruggieri
Affiliation:
IGG-CNR, Institute of Geosciences and Earth Resources, Firenze, Italy
Paola Francesca Matera
Affiliation:
Department of Earth and Geoenvironmental Sciences, University of Bari, Bari, Italy
*
Author for correspondence: Martina Zucchi, Email: [email protected]

Abstract

Geothermal systems in terrains affected by polyphase deformation have reservoirs with a 3D geometry that is always difficult to predict. In this paper we describe a fossil exhumed geothermal system exposed in eastern Elba Island that developed in a polyphase folded and faulted setting, which can help us to understand how geothermal fluids circulate in geological bodies with inherited structures. Geothermal circulation at Elba allowed the deposition of Fe-ore deposits (haematite/magnetite and pyrite) and altered rock volumes, which represent tracers of the palaeo-fluid flow. Normal and oblique-slip faults dissected a polyphase folded metasiliciclastic succession and produced a secondary permeability in the range of 5 × 10−13 to 5 × 10−16 m2. From the permeable fault zones acting as feeder conduits, geothermal fluids permeated the hydraulically connected metasiliciclastic rock bodies previously deformed by two generations of folds. Geothermal fluids followed the already defined geometry, thus giving rise to apparent folded mineralized levels. Fluid migration into the metasiliciclastic rocks was possible due to their chemical aggression, which favoured the dissolution and reprecipitation of quartz, and Fe-oxide and sulphide deposition. Renewed fluids maintained their chemical properties (pH value and temperature, mostly). This conclusion provides inputs for reconstructing geothermal conceptual models and evaluating the geothermal potentiality of exploitable areas developing in similar geological settings.

Type
FLUID FLOW AND MINERALIZATION IN FAULTS AND FRACTURES
Copyright
© The Author(s), 2022. Published by Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Alçiçek, H, Bülbül, A and Alçiçek, MC (2016) Hydrogeochemistry of the thermal waters from the Yenice Geothermal Field (Denizli Basin, southwestern Turkey). Journal of Volcanology and Geothermal Research 309, 118–38.CrossRefGoogle Scholar
Alçiçek, H, Bülbül, A, Brogi, A, Liotta, D, Ruggieri, G, Capezzuoli, E, Meccheri, M, Yavuzer, İ and Alçiçek, MC (2018) Origin, evolution and geothermometry of the thermal waters in the Gölemezli Geothermal Field, Denizli Basin (SW Anatolia, Turkey). Journal of Volcanology and Geothermal Research 349, 130. doi: 10.1016/j.jvolgeores.2017.07.021.CrossRefGoogle Scholar
Alçiçek, H, Bülbül, A, Yavuzer, İ and Alçiçek, MC (2019) Origin and evolution of the thermal waters from the Pamukkale Geothermal Field. Journal of Volcanology and Geothermal Research 372, 4870. doi: 10.1016/j.jvolgeores.2018.09.011.CrossRefGoogle Scholar
Aldinucci, M, Brogi, A and Sandrelli, F (2005) The metamorphic units of the eastern side of Monte Leoni (Northern Apennines, Italy). Bollettino della Società Geologica Italiana 124, 313–32.Google Scholar
Anderson, GM and Burnham, CW (1965) The solubility of quartz in supercritical water. American Journal of Science 263, 494511.CrossRefGoogle Scholar
Barbier, E (2002) Geothermal energy technology and current status: an overview. Renewable and Sustainable Energy Reviews 6, 365.CrossRefGoogle Scholar
Barboni, M, Annen, C and Schoene, B (2015) Evaluating the construction and evolution of upper crustal magma reservoirs with coupled U/Pb zircon geochronology and thermal modeling: a case study from the Mt. Capanne pluton (Elba, Italy). Earth and Planetary Science Letters 432, 436–48.CrossRefGoogle Scholar
Barchi, MR (2010) The Neogene–Quaternary evolution of the Northern Apennines: crustal structure, style of deformation and seismicity. In The Neogene–Quaternary Evolution of the Northern Apennines: Crustal Structure, Style of Deformation, Seismicity (eds Beltrando, M, Peccerillo, A, Mattei, M, Conticelli, S and Doglioni, C). Journal of the Virtual Explorer 36. doi: 10.3809/jvirtex.2009.00220.Google Scholar
Bartole, R (1995) The North-Tyrrhenian–northern Apennines post-collisional system: constraints for a geodynamic model. Terra Nova 1, 730.CrossRefGoogle Scholar
Batini, F, Brogi, A, Lazzarotto, A, Liotta, D and Pandeli, E (2003) Geological features of the Larderello–Travale and Mt. Amiata geothermal areas (southern Tuscany, Italy). Episodes 26, 239–44.CrossRefGoogle Scholar
Belkin, HE, Cavarretta, G, De Vivo, B and Tecce, F (1988) Hydrothermal phlogopite and anhydrite from the SH2 well, Sabatini volcanic district, Latium, Italy: fluid inclusions and mineral chemistry. American Mineralogist 73, 775–97.Google Scholar
Benvenuti, M, Dini, A, D’Orazio, M, Chiarantini, L, Corretti, A and Costagliola, P (2013) The tungsten and tin signature of iron ores from Elba Island (Italy): a tool for provenance studies of iron production in the Mediterranean Region. Archeometry 55, 479506.CrossRefGoogle Scholar
Bianco, C, Brogi, A, Caggianelli, A, Giorgetti, G, Liotta, D and Meccheri, M (2015) HP-LT metamorphism in Elba Island: implications for the geodynamic evolution of the inner Northern Apennines (Italy). Journal of Geodynamics 91, 1325.CrossRefGoogle Scholar
Bianco, C, Godard, G, Halton, A, Brogi, A, Liotta, D and Caggianelli, A (2019) The lawsonite-glaucophane blueschists of Elba Island (Italy). Lithos 348–349, 105198. doi: 10.1016/j.lithos.2019.105198.CrossRefGoogle Scholar
Bodechtel, J (1965) Zur Genesis der Eisenerze der Toskana und der Insel Elba. Neues Jahrbuch für Mineralogie – Abhandlungen 103, 147–62.CrossRefGoogle Scholar
Bons, PD, Elburg, MA and Gomez-Rivas, E (2012) A review of the formation of tectonic veins and their microstructures. Journal of Structural Geology 43, 3362.CrossRefGoogle Scholar
Bortolotti, V, Fazzuoli, M, Pandeli, F, Principi, G, Babbini, A and Corti, S (2001) Geology of Central and Eastern Elba Island Italy. Ofioliti 26, 97150.Google Scholar
Brigatti, MF, Malferrari, D, Laurora, A and Elmi, C (2011) Structure and mineralogy of layer silicates: recent perspectives and new trends in layered mineral structures and their application in advanced technologies. In Layered Mineral Structures and their Application in Advanced Technologies (eds Brigatti, MF and Mottana, A), pp. 171. European Mineralogical Union Notes in Mineralogy vol. 11. Twickenham: European Mineralogical Union and the Mineralogical Society of Great Britain and Ireland. doi: 10.1180/EMU-notes.11.CrossRefGoogle Scholar
Brigatti, MF and Poppi, L (1993) Crystal chemistry of Ba-rich trioctahedral micas-1M. European Journal of Mineralogy 5, 857–71.CrossRefGoogle Scholar
Brogi, A (2006) Foliation relationships and structural facing vs. vergence determinations in refolded low-grade metamorphic rocks: an example from the Tuscan Metamorphic ‘Basement’ (Northern Apennines, Italy). Journal of Structural Geology 28, 115–28. doi: 10.1016/j.jsg.2005.07.009.CrossRefGoogle Scholar
Brogi, A (2008) Kinematics and geometry of Miocene low-angle detachments and exhumation of the metamorphic units in the hinterland of the Northern Apennines (Italy). Journal of Structural Geology 30, 220.CrossRefGoogle Scholar
Brogi, A (2020) Late evolution of the inner Northern Apennines from the structure of the Monti del Chianti-Monte Cetona ridge (Tuscany, Italy). Journal of Structural Geology 141, 104205. doi: 10.1016/j.jsg.2020.104205.CrossRefGoogle Scholar
Brogi, A, Alçiçek, MC, Liotta, D, Capezzuoli, E, Zucchi, M and Matera, PF (2021) Step-over fault zones controlling geothermal fluid-flow and travertine formation (Denizli Basin, Turkey). Geothermics 89, 101941. doi: 10.1016/j.geothermics.2020.101941.CrossRefGoogle Scholar
Brogi, A and Giorgetti, G (2012) Tectono-metamorphic evolution of the siliciclastic units in the Middle Tuscan Range (inner Northern Apennines): Mg–carpholite bearing quartz veins related to syn-metamorphic syn-orogenic foliation. Tectonophysics 526–529, 167–84. doi: 10.1016/j.tecto.2011.09.015.CrossRefGoogle Scholar
Brogi, A, Lazzarotto, A, Liotta, D and Ranalli, G (2005) Crustal structures in the geothermal areas of southern Tuscany (Italy): insights from the CROP 18 deep seismic reflection lines. Journal of Volcanology and Geothermal Research 148, 6080.CrossRefGoogle Scholar
Brogi, A and Liotta, D (2008) Highly extended terrains, lateral segmentation of the substratum, and basin development: the Middle-Late Miocene Radicondoli Basin (inner northern Apennines, Italy). Tectonics 27, TC5002. doi: 10.1029/2007TC002188.CrossRefGoogle Scholar
Brogi, A, Liotta, D, Ruggieri, G, Capezzuoli, E, Meccheri, M and Dini, A (2016) An overview on the characteristics of geothermal carbonate reservoirs in southern Tuscany. Italian Journal of Geosciences 135, 1729. doi: 10.3301/IJG.2014.41.CrossRefGoogle Scholar
Brunet, C, Monié, P, Jolivet, L and Cadet, JP (2000) Migration of compression and extension in the Tyrrhenian Sea, insights from 40Ar/39Ar ages on micas along a transect from Corsica to Tuscany. Tectonophysics 321, 127–55.CrossRefGoogle Scholar
Caggianelli, A, Ranalli, G, Lavecchia, A, Liotta, D and Dini, A (2014) Post-emplacement thermo-rheological history of a granite intrusion and surrounding rocks: the Monte Capanne pluton, Elba Island, Italy. In Deformation Structures and Processes within the Continental Crust (Llan-Fúnez, S, Marcos, A and Bastida, F), pp. 129–43. Geological Society of London, Special Publication no. 394.Google Scholar
Caggianelli, A, Zucchi, M, Bianco, C, Brogi, A and Liotta, D (2018) Estimating P-T metamorphic conditions on the roof of a hidden granitic pluton: an example from the Mt. Calamita promontory (Elba Island, Italy). Italian Journal of Geosciences 137, 238–53. doi: 10.3301/IJG.2018.11.CrossRefGoogle Scholar
Calcagnile, G and Panza, GF (1981) The main characteristics of the lithosphere asthenosphere system in Italy and surrounding regions. Pure and Applied Geophysics 119, 865–79.CrossRefGoogle Scholar
Capezzuoli, E, Spina, A, Brogi, A, Liotta, D, Bagnoli, G, Zucchi, M, Molli, G and Regoli, R (2021) Reconsidering the Variscan basement of Southern Tuscany (Inner Northern Apennines). Geosciences 11, 84. doi: 10.3390/geosciences11020084.CrossRefGoogle Scholar
Cappetti, G, Parisi, L, Ridolfi, A and Stefani, G (1995) Fifteen years of reinjection in the Larderello-Valle Secolo area: analysis of the production data. In Proceedings of the World Geothermal Congress WGC95, Florence, Italy, May 18–31, 3, pp. 17972000.Google Scholar
Carmignani, L, Decandia, FA, Disperati, L, Fantozzi, PL, Lazzarotto, A, Liotta, D and Meccheri, M (1994) Tertiary extensional tectonics in Tuscany (Northern Apennines, Italy). Tectonophysics 238, 295310. doi: 10.1016/0040-1951(94)90061-2.CrossRefGoogle Scholar
Carmignani, L and Kligfield, R (1990) Crustal extension in the Northern Apennines: transition from compression to extension in the Alpi Apuane Core Complex. Tectonics 9, 1275–303.CrossRefGoogle Scholar
Carosi, R, Iacopini, D and Montomoli, C (2004) Asymmetric fold development in the Variscan Nappes of central Sardinia (Italy). Tectonics 336, 939–49.Google Scholar
Cashman, P, Faulds, JE and Hinz, NH (2012) Regional variations in structural controls on geothermal systems in the Great Basin. Geothermal Resources Council Transactions 36, 2530.Google Scholar
Cassinis, R, Scarascia, S and Lozej, A (2003) The deep crustal structure of Italy and surrounding areas from seismic refraction data; a new synthesis. Italian Journal of Geosciences 122, 365–76.Google Scholar
Cavarretta, G, Gianelli, G, Scandiffio, G and Tecce, F (1985) Evolution of the Latera geothermal system II: metamorphic, hydrothermal mineral assemblages and fluid chemistry. Journal of Volcanology and Geothermal Research 26, 337–64.CrossRefGoogle Scholar
Collettini, C and Holdsworth, RE (2004) Fault zone weakening processes along low-angle normal faults: insights from the Zuccale Fault, Isle of Elba, Italy. Journal of the Geological Society, London 161, 1039–51.CrossRefGoogle Scholar
Conti, P, Costantini, A, Decandia, FA, Elter, FM, Gattiglio, M, Lazzarotto, A, Meccheri, M, Pandeli, E, Rau, A, Sandrelli, F, Tongiorgi, M and Di Pisa, A (1991) Structural frame of the Tuscan Palaeozoic: a review. Bollettino della Società Geologica Italiana 100, 523–41.Google Scholar
Cortecci, G, Lattanzi, P and Tanelli, G (1985) C- and O-isotope and fluid inclusion studies of carbonates from pyrite and polymetallic ore deposits and associated country rocks (Southern Tuscany, Italy). Chemical Geology: Isotope Geoscience Section 58, 121–8.CrossRefGoogle Scholar
Costantini, A, Decandia, FA, Lazzarotto, A and Sandrelli, F (1988) L’Unità di Monticiano-Roccastrada fra la Montagnola Senese e il Monte Leoni (Toscana meridionale). Atti Ticinensi di Scienze della Terra 31, 382420.Google Scholar
Cox, SF, Knackstedt, MA and Braun, J (2001) Principles of structural control on permeability and fluid flow in hydrothermal systems. In Structural Controls on Ore Genesis (eds Richards, JP and Tosdal, RM), pp. 124. Reviews in Economic Geology vol. 14. Society of Economic Geologists. Google Scholar
Craig, JW, Faulds, JE, Hinz, NH, Earney, TE, Schermerhorn, WD, Siler, DL, Glen, JM, Peacock, J, Coolbaugh, MF and Deoreo, SB (2021) Discovery and analysis of a blind geothermal system in Southeastern Gabbs valley, Western Nevada, USA. Geothermics 97, 102177. doi: 10.1016/j.geothermics.2021.102177.CrossRefGoogle Scholar
Curewitz, D and Karson, JA (1997) Structural settings of hydrothermal outflow: fracture permeability maintained by fault propagation and interaction. Journal of Volcanology and Geothermal Research 79, 149–68. doi: 10.1016/S0377-0273(97)00027-00029.CrossRefGoogle Scholar
Debenedetti, A (1952) Osservazioni geologiche nelle zone minerarie dell’Isola d’Elba. Bollettino della Società Geologica Italiana 74, 5383.Google Scholar
Deino, A, Keller, JVA, Minelli, G and Pialli, G (1992) Datazioni 40Ar/39Ar del metamorfismo dell’Unità di Ortano-Rio Marina (Isola d’Elba): risultati preliminari. Studi Geologici Camerti 2, 187–92.Google Scholar
Deschamps, Y, Dagallier, G, Macaudier, J, Marignac, C, Maine, B and Saupé, F (1983) Le gisement de Pyrite-Hématite de ValleGiove (Rio Marina, Ile d’Elbe, Italie). Contribution à la connaissance des gisements de Toscane – I. Partie 1. Schweizerische Mineralogische und Petrographische 63, 149–65.Google Scholar
Dini, A (2003) Ore deposits, industrial minerals and geothermal resources. Periodico di Mineralogia 72, 4152.Google Scholar
Dini, A, Gianelli, G, Puxeddu, M and Ruggieri, G (2005) Origin and evolution of Pliocene–Pleistocene granites from the Larderello geothermal field (Tuscan Magmatic Province, Italy). Lithos 81, 131.CrossRefGoogle Scholar
Dini, A, Innocenti, F, Rocchi, S, Tonarini, S and Westerman, DS (2002) The magmatic evolution of the late Miocene laccolith-pluton-dike granitic complex of Elba Island, Italy. Geological Magazine 139, 257–79.CrossRefGoogle Scholar
Dini, A, Westerman, DS, Innocenti, F and Rocchi, S (2008) Magma emplacement in a transfer zone: the Miocene mafic Orano dyke swarm of Elba Island, Tuscany, Italy In Structure and Emplacement of High-Level Magmatic Systems (eds Thomson, K and Petford, N), pp. 131–48. Geological Society of London, Special Publication no. 302.Google Scholar
Ducoux, M, Branquet, Y, Jolivet, L, Arbaret, L, Grasemann, B, Rabillard, A, Gumiaux, C and Drufin, S (2016) Synkinematic skarns and fluid drainage along detachments: the West Cycladic Detachment System on Serifos Island (Cyclades, Greece) and its related mineralization. Tectonophysics 695, 126. doi: 10.1016/j.tecto.2016.12.008.CrossRefGoogle Scholar
Duranti, S, Palmeri, R, Pertusati, PC and Ricci, CA (1992) Geological evolution and metamorphic petrology of the basal sequences of Eastern Elba (Complex II). Acta Vulcanologica 2, 213–29.Google Scholar
Durney, DW and Kisch, HJ (1994) A field classification and intensity scale for first generation cleavages. Journal of Australian Geology and Geophysics 15, 257–95.Google Scholar
Faulds, JE, Coolbaugh, MF, Blewitt, G and Henry, CD (2004) Why is Nevada in hot water? Structural controls and tectonic model of geothermal systems in the northwestern Great Basin. Geothermal Resources Council Transactions 28, 649–54.Google Scholar
Faulds, JE, Coolbaugh, MF, Vice, GS and Edwards, ML (2006) Characterizing structural controls of geothermal fields in the northwestern Great Basin: a progress report. Geothermal Resources Council Transactions 30, 6976.Google Scholar
Fournier, RO, Rosenbauer, RJ and Bischoff, JL (1982) The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars. Geochimica et Cosmochimica Acta 46, 1975–8.CrossRefGoogle Scholar
Gagnevin, D, Daly, JS, Horstwood, MSA and Whitehouse, MJ (2011) In-situ zircon U–Pb, oxygen and hafnium isotopic evidence for magma mixing and mantle metasomatism in the Tuscan Magmatic Province, Italy. Earth and Planetary Science Letters 205, 4556.CrossRefGoogle Scholar
Gale, JE (1982) Assessing the permeability characteristics of fractured rock. In Recent Trends in Hydrogeology (ed. Narasimhan, TN), pp. 163–82. Geological Society of America, Special Paper 189. doi: 10.1130/SPE189-p163.CrossRefGoogle Scholar
Gilliéron, F (1959) Osservazioni sulla geologia dei giacimenti di ferro dell’Elba orientale. Industria Mineraria 10, 110.Google Scholar
Giuntoli, F and Viola, G (2021) Cyclic brittle-ductile oscillations recorded in exhumed high-pressure continental units: a record of deep episodic tremor and slow slip events in the Northern Apennines. Geochemistry, Geophysics, Geosystems 22, e2021GC009805. doi: 10.1029/2021GC009805.CrossRefGoogle Scholar
Gray, DR (1977) Morphological classification of crenulation cleavage. The Journal of Geology 85, 229–35.CrossRefGoogle Scholar
Hantsche, AL, Kouzmanov, K, Milenkov, G, Vezzoni, S, Vassileva, R, Dini, A, Sheldrake, T, Laurent, O and Guillong, M (2021) Metasomatism and cyclic skarn growth along lithological contacts: physical geochemical evidence from a distal Pb-Zn skarn. Lithos 400–401, 106408. doi: 10.1016/j.lithos.2021.106408.CrossRefGoogle Scholar
Hobbs, BE, Means, WD and Williams, PF (1976) An Outline of Structural Geology . New York: John Wiley and Sons, 571 pp.Google Scholar
Jolie, E, Moeck, I and Faulds, JE (2015) Quantitative structural–geological exploration of fault-controlled geothermal systems—a case study from the Basin-and-Range Province, Nevada (USA). Geothermics 54, 5467.CrossRefGoogle Scholar
Keller, JVA and Pialli, G (1990) Tectonics of the Island of Elba: a reappraisal. Bollettino della Società Geologica Italiana 109, 413–25.Google Scholar
Kretz, R (1983) Symbols for rock-forming minerals. American Mineralogist 68, 277–9.Google Scholar
Lattanzi, P, Benvenuti, M, Costagliola, P and Tanelli, G (1994) An overview on recent research on the metallogeny of Tuscany, with special reference to the Apuane Alps. Memoria della Società Geologica Italiana 48, 613–25.Google Scholar
Lattanzi, P, Benvenuti, M, Gale, N, Hansmann, W, Köppel, V and Stos-Gale, Z (1997) Pb-isotope Data on Ore Deposits of Southern Tuscany. Bellaria: Convegno Nazionale FIST, 2.Google Scholar
Leung, CTO and Zimmermann, RW (2012) Estimating the hydraulic conductivity of two-dimensional fracture networks using network geometric properties. Transport in Porous Media 93, 777–97.CrossRefGoogle Scholar
Liotta, D (2002) D2 asymmetric folds and their vergence meaning in the Montagnola Senese metamorphic rocks (inner northern Apennines, central Italy). Journal of Structural Geology 24, 1479–90.CrossRefGoogle Scholar
Liotta, D and Brogi, A (2020) Pliocene–Quaternary fault kinematics in the Larderello geothermal area (Italy): insights for the interpretation of the present stress field. Geothermics 83, 101714. doi: 10.1016/j.geothermics.2019.101714.CrossRefGoogle Scholar
Liotta, D, Brogi, A, Meccheri, M, Dini, A, Bianco, C and Ruggieri, G (2015) Coexistence of low-angle normal and high-angle strike- to oblique-slip faults during Late Miocene mineralization in eastern Elba Island (Italy). Tectonophysics 660, 1734.CrossRefGoogle Scholar
Liotta, D, Brogi, A, Ruggieri, G, Rimondi, V, Zucchi, M, Helgadóttir, HM, Montegrossi, G and Friðleifsson, (2020) Fracture analysis, hydrothermal mineralization and fluid pathways in the Neogene Geitafell central volcano: insights for the Krafla active geothermal system, Iceland. Journal of Volcanology and Geothermal Research 391, 106502. doi: 10.1016/j.jvolgeores.2018.11.023.CrossRefGoogle Scholar
Liotta, D, Brogi, A, Ruggieri, G and Zucchi, M (2021) Fossil vs. active geothermal systems: a field laboratory method to disclose the relationships between geothermal fluid flow and geological structures at depth. Energies 14, 933. doi: 10.3390/en14040933.CrossRefGoogle Scholar
Liotta, D, Cernobori, L and Nicolich, R (1998) Restricted rifting and its coexistence with compressional structures: results from the CROP 3 traverse (Northern Apennines, Italy). Terra Nova 10, 1620.CrossRefGoogle Scholar
Lippolt, HJ, Wernicke, RS and Bahr, R (1995) Paragenetic specularite and adularia (Elba, Italy): concordant (U+Th)-He and K-Ar ages. Earth and Planetary Science Letters 132, 4351.CrossRefGoogle Scholar
Locardi, E and Nicolich, R (1992) Geodinamica del Tirreno e dell’Appennino centro-meridionale: la nuova carta della Moho. Memoria della Società Geologica Italiana 41, 121–40.Google Scholar
Maineri, C, Benvenuti, M, Costagliola, P, Dini, A, Lattanzi, P, Ruggieri, G and Villa, I (2003) Sericitic alteration at the La Crocetta deposit (Elba Island, Italy): interplay between magmatism, tectonics and hydrothermal activity. Mineralium Deposita 38, 6786.CrossRefGoogle Scholar
Manning, CE (1994) The solubility of quartz in H2O in the lower crust and upper mantle. Geochimica et Cosmochimica Acta 58, 4831–9.CrossRefGoogle Scholar
Mazzarini, F, Musumeci, G, Viola, G, Garofalo, PS and Mattila, J (2019) Structural and lithological control on fluid circulation, dilation and ore mineralization (Rio Albano mine, Island of Elba, Italy). Journal of Structural Geology 126, 210–30.CrossRefGoogle Scholar
McLaughlin, RJ and Donnelly-Nolan, J (1981) Research in the Geysers-Clear Lake Geothermal Area, Northern California. Professional Paper 1141. Washington, DC: U.S. Geological Survey.CrossRefGoogle Scholar
Moeller, S, Grevemeyer, I, Ranero, CR, Berndt, C, Klaeschen, D, Sallares, V, Zitellini, N and De Franco, R (2013) Early-stage rifting of the northern Tyrrhenian Sea Basin: results from a combined wide-angle and multichannel seismic study. Geochemistry, Geophysics, Geosystems 14, 3032–52. doi: 10.1002/ggge.20180.CrossRefGoogle Scholar
Molli, G (2008) Northern Apennine–Corsica orogenic system: an updated overview. In Tectonic Aspects of the Alpine-Dinaride-Carpathian System (eds Siegesmund, S, Fügenschuh, B and Froitzheim, N), pp. 413–42. Geological Society of London, Special Publication no. 298.Google Scholar
Molli, G, Conti, P, Giorgetti, G, Meccheri, M and Oesterling, N (2000) Microfabric study on the deformational and thermal history of the Alpi Apuane marbles (Carrara marbles), Italy. Journal of Structural Geology 22, 1809–25.CrossRefGoogle Scholar
Molli, G, Giorgetti, G and Meccheri, M (2002) Tectono-metamorphic evolution of the Alpi Apuane Metamorphic Complex: new data and constraints for geodynamic models. Bollettino della Società Geologica Italiana 1, 789800.Google Scholar
Montomoli, C, Ruggieri, G, Boiron, MC and Cathelineau, M (2001) Pressure fluctuation during uplift of the Northern Apennines (Italy): a fluid inclusion study. Tectonophysics 341, 121–39.CrossRefGoogle Scholar
Nicholl, MJ, Rajaram, H, Glass, RJ and Detwiler, R (1999) Saturated flow in a single fracture: evaluation of the Reynolds equation in measured aperture fields. Water Resources Research 35, 3361–73.CrossRefGoogle Scholar
Oliver, NHS and Bons, PD (2001) Mechanism of fluid flow and fluid-rock interaction in fossil metamorphic hydrothermal system inferred from vein-wall-rock patterns, geometry and microstructure. Geofluids 1, 137–62.CrossRefGoogle Scholar
Orlando, A, Ruggieri, G, Chiarantini, L, Montegrossi, G and Rimondi, V (2017) Experimental investigation of biotite-rich schist reacting with B-bearing fluids at upper crustal conditions and correlated tourmaline formation. Minerals 7, 155. doi: 10.3390/min7090155.CrossRefGoogle Scholar
Passchier, CW and Trouw, RAJ (1996) Microtectonics. Berlin: Springer, 289 pp.Google Scholar
Peccerillo, A (2003) Plio-Quaternary magmatism in Italy. Episodes 26, 222–6.CrossRefGoogle Scholar
Pertusati, PC, Raggi, G, Ricci, CA, Duranti, S and Palmeri, R (1993) Evoluzione post-collisionale dell’Elba centro-orientale. Memorie della Società Geologia Italiana 49, 297312.Google Scholar
Puxeddu, M (1984) Structure and late Cenozoic evolution of the upper lithosphere in southwest Tuscany (Italy). Tectonophysics 101, 357–82.CrossRefGoogle Scholar
Ramsay, JG (1967) Folding and Fracturing of Rocks . New York: McGraw-Hill, 568 pp.Google Scholar
Rickard, MJ (1961) A note on cleavages in crenulated rocks. Geological Magazine 98, 324–32.CrossRefGoogle Scholar
Rocchi, S, Westerman, DS, Dini, A and Farina, F (2010) Intrusive sheets and sheeted intrusions at Elba Island, Italy. Geosphere 6, 225–36.CrossRefGoogle Scholar
Romagnoli, P, Arias, A, Barelli, A, Cei, M and Casini, M (2010) An updated numerical model of the Larderello–Travale geothermal system, Italy. Geothermics 39, 292313.CrossRefGoogle Scholar
Rossetti, F, Faccenna, C, Jolivet, L, Funiciello, R, Tecce, F and Brunet, C (1999) Syn- versus post-orogenic extension: the case study of Giglio Island (Northern Tyrrhenian Sea, Italy). Tectonophysics 304, 7193.CrossRefGoogle Scholar
Rossetti, F, Faccenna, C, Jolivet, L, Goffé, B and Funiciello, R (2002) Structural signature and exhumation P–T–t paths of the blueschist units exposed in the interior of the Northern Apennine chain, tectonic implication. Bollettino della Società Geologica Italiana 1, 829–42.Google Scholar
Rowland, JV and Sibson, RH (2004) Structural controls on hydrothermal flow in a segmented rift system, Taupo Volcanic Zone, New Zealand. Geofluids 4, 259–83.CrossRefGoogle Scholar
Rowland, JV and Simmons, SF (2012) Hydrologic, magmatic, and tectonic controls on hydrothermal flow, Taupo Volcanic Zone, New Zealand: implications for the formation of epithermal vein deposits. Economic Geology 107, 427–57. doi: 10.2113/econgeo.107.3.427.CrossRefGoogle Scholar
Ryan, E, Papeschi, S, Viola, G, Musumeci, G, Mazzarini, F, Torgersen, E, Sørensen, BE and Ganerød, M (2021) Syn-orogenic exhumation of high-P units by upward extrusion in an accretionary wedge: insights from the Eastern Elba Nappe Stack (Northern Apennines, Italy). Tectonics 40, e2020TC006348. doi: 10.1029/2020TC006348.CrossRefGoogle Scholar
Serri, G, Innocenti, F and Manetti, P (1993) Geochemical and petrological evidence of the subduction of delaminated Adriatic continental lithosphere in the genesis of the Neogene–Quaternary magmatism of central Italy. Tectonophysics 223, 117214.CrossRefGoogle Scholar
Shmulovich, KI, Yardley, BWD and Graham, CM (2006) Solubility of quartz in crustal fluids: experiments and general equations for salt solutions and H2O–CO2 mixtures at 400–800°C and 0.1–0.9 GPa. Geofluids 6, 154–67. doi: 10.1111/j.1468-8123.2006.00140.x.Google Scholar
Sibson, RH (2000) Fluid involvement in normal faulting. Journal of Geodynamics 29, 469–99. doi: 10.1016/S0264-3707(99)00042-3.CrossRefGoogle Scholar
Sirevaag, H, Jacobs, J, Ksienzyk, AK, Rocchi, S, Paoli, G, Jørgensen, H and Košler, J (2016) From Gondwana to Europe: the journey of Elba Island (Italy) as recorded by U–Pb detrital zircon ages of Paleozoic metasedimentary rocks. Gondwana Research 38, 273–88. doi: 10.1016/j.gr.2015.12.006.CrossRefGoogle Scholar
Smith, SAF, Holdsworth, RE and Collettini, RE (2011) Interactions between plutonism and low-angle normal faults in the upper crust: insights from the Island of Elba, Italy. Geological Society of America Bulletin 123, 329–46. doi: 10.1130/B30200.1.CrossRefGoogle Scholar
Sommerfeld, RA (1967) Quartz solution reaction: 400°–500 °C, 1000 bars. Journal of Geophysical Research 72, 4253–7.CrossRefGoogle Scholar
Spiess, R, Langone, A, Caggianelli, A, Stuart, FM, Zucchi, M, Bianco, C, Brogi, A and Liotta, D (2021) Unveiling ductile deformation during fast exhumation of a granitic pluton in a transfer zone. Journal of Structural Geology 147, 104326. doi: 10.1016/j.jsg.2021.104326.CrossRefGoogle Scholar
Spiess, R, Langone, A, Caggianelli, A, Stuart, FM, Zucchi, M, Bianco, C, Brogi, A and Liotta, D (2022) Reply to Mazzarini et al. comment on ‘Unveiling ductile deformation during fast exhumation of a granitic pluton in a transfer zone’. Journal of Structural Geology 155, 104498. doi: 10.1016/j.jsg.2021.104498.CrossRefGoogle Scholar
Spina, A, Capezzuoli, E, Brogi, A, Cirilli, S and Liotta, D (2019) Mid- to late Permian microfloristic evidence in the metamorphic successions of Northern Apennines: insights for age-constraining and palaeogeographical correlations. Journal of the Geological Society, London 176, 1262–72. doi: 10.1144/jgs2018-202.CrossRefGoogle Scholar
Stanley, WD and Blakely, RJ (1995) The Geyser-Clear Lake geothermal area, California–an updated geophysical perspective of heat sources. Geothermics 24, 187221. doi: 10.1016/0375-6505(94)00048-H.CrossRefGoogle Scholar
Tanelli, G, Benvenuti, M, Costagliola, P, Dini, A, Lattanzi, P, Manieri, C, Mascaro, I and Ruggieri, G (2001) The iron mineral deposits of Elba Island: state of the art. Ofioliti 26, 239–48.Google Scholar
Theye, T, Reinhardt, J, Goffé, B, Jolivet, L and Brunet, C (1997) Ferro and magnesiocarpholite from Mt. Argentario (Italy): first evidence for high-pressure metamorphism of the metasedimentary Verrucano sequence, and significance for P–T path reconstruction. European Journal of Mineralogy 9, 859–73.CrossRefGoogle Scholar
Townend, J and Zoback, MD (2000) How faulting keeps the crust strong. Geology 28, 399402.2.0.CO;2>CrossRefGoogle Scholar
Vai, GB and Martini, IP (2001) Anatomy of an Orogen: the Apennines and Adjacent Mediterranean Basins. Dordrecht: Kluwer Academic, 632 pp.Google Scholar
Vezzoni, S, Dini, A and Rocchi, S (2016) Reverse telescoping in a distal skarn system (Campiglia Marittima, Italy). Ore Geology Review 77, 176–93. doi: 10.1016/j.oregeorev.2016.03.001.CrossRefGoogle Scholar
Viti, C, Brogi, A, Liotta, D, Mugnaioli, E, Spiess, R, Dini, A, Zucchi, M and Vannuccini, G (2016) Seismic slip recorded in tourmaline fault mirrors from Elba Island (Italy). Journal of Structural Geology 86, 112.CrossRefGoogle Scholar
Westerman, DS, Dini, A, Innocenti, F and Rocchi, S (2004) Rise and fall of a nested Christmas-tree laccolith complex, Elba Island, Italy. In Physical Geology of High-level Magmatic Systems (eds Breitkreuz, C and Petford, N), pp. 195213. Geological Society of London, Special Publication no. 234.Google Scholar
Wibberley, CAJ and Shimamoto, J (2003) Internal structure and permeability of major strike-slip fault zones: the Median Tectonic Line in Mie Prefecture, Southwest Japan. Journal of Structural Geology 25, 5978.CrossRefGoogle Scholar
Williams, PF (1972) Development of metamorphic layering and cleavage in low grade metamorphic rocks at Bermagui, Australia. American Journal of Science 272, 147.CrossRefGoogle Scholar
Williams, PF, Means, WD and Hobbs, BE (1977) Development of axial-plane slaty cleavage and schistosity in experimental and nature materials. Tectonophysics 42, 139–58.CrossRefGoogle Scholar
Wu, LY, Stuart, MF, Heizler, M, Benvenuti, M and Hu, RZ (2019) Multi-aliquot method for determining (U + Th)/He ages of hydrothermal hematite: returning to Elba. Chemical Geology 504, 151–7.CrossRefGoogle Scholar
Yasuhara, H, Polak, A, Mitani, Y, Grader, AS, Halleck, PM and Elsworth, D (2006) Evolution of fracture permeability through fluid-rock reaction under hydrothermal conditions. Earth and Planetary Science Letters 244, 186200.CrossRefGoogle Scholar
Zhang, R (1986) Sulfur isotopes and pyrite-anhydrite equilibria in a volcanic basin hydrothermal system of the middle to lower Yangtze River Valley. Economic Geology 81, 3245.CrossRefGoogle Scholar
Zimmerman, RW and Bodvarsson, GS (1996) Hydraulic conductivity of rock fractures. Transport in Porous Media 23, 130.CrossRefGoogle Scholar
Zucchi, M (2020) Faults controlling geothermal fluid flow in low permeability rock volumes: an example from the exhumed geothermal system of eastern Elba Island (northern Tyrrhenian Sea, Italy). Geothermics 85, 101765. doi: 10.1016/j.geothermics.2019.101765.CrossRefGoogle Scholar
Zucchi, M, Brogi, A, Liotta, D, Rimondi, V, Ruggieri, G, Montegrossi, G, Caggianelli, A and Dini, A (2017) Permeability and hydraulic conductivity of faulted micaschist in the eastern Elba Island exhumed geothermal system (Tyrrhenian sea, Italy): insights from Cala Stagnone. Geothermics 70, 125–45.CrossRefGoogle Scholar
Zuffardi, P (1990) The Iron Deposits of the Elba Island (Italy): Remarks for a Metallogenic Discussion. Memorie Lincee Scienze Fisiche e Naturali Serie IX 1, pp. 97128. Rome: Accademia Nazionale dei Lincei.Google Scholar