Published online by Cambridge University Press: 01 May 2009
The Llanrwst Pb–Zn and Llanfair–Talhaiarn Cu–Pb–Zn orefields contain vein mineralization similar to Lower Palaeozoic-hosted base metal deposits elsewhere in the British Isles, which are believed to have formed in the late Palaeozoic. K–Ar and Rb–Sr data on intensely sericitized wallrock material indicate that the main phase of mineralization at both orefields occurred between the mid-Devonian and theTournasian (386–350 Ma). The latest veins at Llanrwst formed in Visean–Westphalian times. Gangue mineral Sr isotope compositions indicate a mixture of radiogenic wallrock-derived Sr with less radiogenic Sr, with a poorly-defined trend to more radiogenic compositions with time.
The age of the main mineralization precludes dewatering of Carboniferous basins as a source of ore fluid. More generally Sr isotopes rule out unmodified basinal brines or metamorphic fluids as mineralizing agents, since their Sr content would be too radiogenic. Local sources of unradiogenic Sr are available at Llanrwst in metadolerites and calcareous sandstones and at Llanfair–Talhaiarn in thin Ludlow Limestone beds.