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Fine-scale chemical zonation in small mafic dykes, Kestiö Island, SW Finland

Published online by Cambridge University Press:  12 November 2008

SOFYA CHISTYAKOVA*
Affiliation:
Department of Geosciences, University of Oulu, Oulu, Finland
RAIS LATYPOV
Affiliation:
Department of Geosciences, University of Oulu, Oulu, Finland Geological Institute, Kola Science Centre, Apatity, Russia
*
Author for correspondence: [email protected]

Abstract

Detailed centimetre-scale sampling across two small dolerite dykes (7 and 21 cm wide) of Kestiö Island, SW Finland, has revealed a well-developed internal zonation, with surprisingly systematic compositional variations. From the margins inwards, the dykes exhibit a steady decrease in whole-rock MgO, Mg number (100Mg/(Mg+Fetotal)) and normative Opx (indicating a normal fractionation trend) with simultaneous increase in normative An (100An/(An+Ab)) and decrease in incompatible Zr, Y, TiO2 and P2O5 (indicating a reverse fractionation trend). In addition, marginal rocks of dykes contain normative corundum that is apparently associated with their significant depletion in whole-rock CaO. The extent of margin-to-centre differentiation of dykes in terms of most components is slight to modest, although in some petrochemical parameters it is quite high (e.g. 15 mol. % of normative An). The dykes are almost glassy and uncontaminated by host rocks, suggesting that their compositional profiles are primary and most likely reflect temporal changes in composition of magma filling the dykes. A mechanism responsible for the systematic changes in composition of inflowing magma remains elusive, however, since no known processes are able to force magma to evolve simultaneously along both normal and reverse fractionation trends. The study thus appears to indicate some not yet specified process of magma differentiation.

Type
Original Article
Copyright
Copyright © Cambridge University Press 2008

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References

Ariskin, A. A., Barmina, G. S., Frenkel, M. Ya., & Nielsen, R. L. 1993. COMAGMAT: a Fortran program to model magma differentiation processes. Computers and Geosciences 19, 1155–70.CrossRefGoogle Scholar
Bergman, L. 1986. Structure and mechanism of intrusion of postorogenic granites in the archipelago of southwestern Finland. Acta Academiae Aboensis (Series B) 46 (5), 74 pp.Google Scholar
Bowen, N. L. 1928. The Evolution of the Igneous Rocks. Princeton University Press, 334 pp.Google Scholar
Campbell, I. H. 1978. Some problems with the cumulus theory. Lithos 11, 311–23.CrossRefGoogle Scholar
Cawthorn, R. G. (ed.) 1996. Layered Intrusions. Developments in Petrology, vol. 15. Elsevier Science B. V., 531 pp.Google Scholar
Cherepanov, A. N., Sharapov, V. N. & Krivenko, A. P. 1982. A possible mechanism for antidromic differentiation in basic plutons. Dokladi Academii Nauk USSR 267, 1204–7 (in Russian).Google Scholar
Cherepanov, A. N., Sharapov, V. N. & Krivenko, A. P. 1983. The dynamic model of disequilibrium crystallization differentiation of magmas in basic plutons. Russian Geologiya i Geofizica 3, 2836 (in Russian).Google Scholar
Delaney, P. T. 1987. Heat transfer during emplacement and cooling of mafic dykes. In Mafic dyke swarms (eds Halls, H. C. & Fahrig, W. F..), pp. 3146. Geological Association of Canada, Special Paper no. 34.Google Scholar
Delong, S. E. & Chatelain, C. 1990. Trace-element constraints on accessory-phase saturation in evolved MORB magma. Earth and Planetary Science Letters 101, 206–15.CrossRefGoogle Scholar
Ehlers, C. & Ehlers, M. 1977. Shearing and multiple intrusions in the diabases of Åland archipelago, SW Finland. Geological Survey of Finland, Bulletin 289, 31 pp.Google Scholar
Eklund, O., Fröjdö, S. & Lindberg, B. 1994. Magma mixing, the petrogenetic link between anorthositic suites and rapakivi granites, Åland, SW Finland. Mineralogy and Petrology 50, 319.CrossRefGoogle Scholar
Gibb, F. G. F. 1968. Flow differentiation in the xenolithic ultrabasic dykes of the Cuillins and the Strathaird Peninsula, Isle of Skye, Scotland. Journal of Petrology 9, 441–3.CrossRefGoogle Scholar
Govindaraju, K. 1994. 1994 compilation of working values and sample descriptions for 383 geostandards. Geostandard Newletter 18, 1158.CrossRefGoogle Scholar
Helz, R. T. 1987. Differentiation behavior of Kilauea Iki lava lake, Kilauea Volcano, Hawaii: an overview of past and current work. In Magmatic Processes: Physicochemical Principles (ed. Mysen, B. O.), pp. 241–58. Geochemical Society, Special Publication no. 1.Google Scholar
Irvine, T. N. 1980. Magmatic infiltration metasomatism, double-diffusive fractional crystallization, and adcumulus growth in the Muskox Intrusion and other layered intrusions. In Physics of magmatic processes (ed. Hargraves, R. B.), pp. 325–84. Princeton University Press.CrossRefGoogle Scholar
Karhunen, R. 2004. Bedrocks of the Iniö and Turku map-sheet areas. Espoo: Geological Survey of Finland, 77 pp. (in Finnish).Google Scholar
Latypov, R. M. 2003. The origin of marginal compositional reversals in basic–ultrabasic sills and layered intrusions by Soret fractionation. Journal of Petrology 44, 15791618.CrossRefGoogle Scholar
Latypov, R. M., Chistyakova, S. Yu. & Alapieti, T. T. 2007. Revisiting problem of chilled margins related to marginal reversals in mafic–ultramafic intrusive bodies. Lithos 99, 178206.CrossRefGoogle Scholar
Lesher, C. E. & Walker, D. 1991. Thermal diffusion in petrology. In Diffusion, atomic ordering, and mass transport: selected topics in geochemistry (ed. Ganguly, J.), pp. 396451. Advances in Physical Geochemistry no. 8. New York: Springer.CrossRefGoogle Scholar
Lindberg, B. & Eklund, O. 1990. The relation between Subjotnian diabases and rapakivi intrusions in southwestern Finland. Geologi 3, 44–7 (in Swedish).Google Scholar
Lindberg, B., Eklund, O. & Suominen, V. 1991. Middle Proterozoic, Subjotnian diabases and related mafic rocks in the archipelago of southwestern Finland. In IGCP-257 Fennoscandian Meeting and Excursion on Precambrian Dyke Swarms (ed. I. Laitakari), pp. 18–30. IGCP-257 Technical Report no. 4.Google Scholar
McBirney, A. R. & Nakamura, Y. 1973. Immiscibility in late-stage magmas of the Skaergaard Intrusion. Carnegie Institution of Washington Yearbook 72, 348–52.Google Scholar
McBirney, A. R. & Naslund, H. R. 1990. The differentiation of the Skaergaard Intrusion. A discussion of Hunter and Sparks. Contributions to Mineralogy and Petrology 104, 235–40.CrossRefGoogle Scholar
McBirney, A. R. & Noyes, R. M. 1979. Crystallization and layering of the Skaergaard Intrusion. Journal of Petrology 20, 487564.CrossRefGoogle Scholar
Miller, J. D. & Ripley, E. M. 1996. Layered intrusions of the Duluth Complex, Minnesota, USA. In Layered Intrusions (ed. Cawthorn, R. G.), pp. 257301. Developments in Petrology no. 5. Elsevier Science B. V.CrossRefGoogle Scholar
Parsons, I. (ed.) 1987. Origin of igneous layering. Dordrecht: D. Reidel Publishing Company, 666 pp.CrossRefGoogle Scholar
Petersen, J. S. 1987. Solidification contraction: another approach to cumulus processes and the origin of igneous layering. In Origins of igneous layering (ed. Parsons, I.), pp. 505–26. Dordrecht: D. Reidel Publishing Company.CrossRefGoogle Scholar
Philpotts, A. R. & Asher, P. M. 1993. Wallrock melting and reaction effects along the Higganum diabase dike in Connecticut: contamination of a continental flood basalt feeder. Journal of Petrology 34, 1029–58.CrossRefGoogle Scholar
Platten, I. M. 2000. Incremental dilation of magma filled fractures: evidence from dyke on the Isle of Skye, Scotland. Journal of Structural Geology 22, 1153–64.CrossRefGoogle Scholar
Platten, I. M. & Watterson, J. 1987. Magma flow and crystallization in dyke fissures. In Mafic dyke swarms (eds Halls, H. C. & Fahrig, W. F.), pp. 6573. Geological Association of Canada, Special Paper no. 34.Google Scholar
Raedeke, L. D. & McCallum, I. S. 1984. Investigations in the Stillwater complex: Part II. Petrology and petrogenesis of the ultramafic series. Journal of Petrology 25, 395420.CrossRefGoogle Scholar
Rämö, O. T. & Haapala, I. 2005. Rapakivi granites. In Precambrian Geology of Finland – Key to the Evolution of the Fennoscandian Shield (eds Lehtinen, M., Nurmi, P. A. & Rämö, O. T.), pp. 533–62. Amsterdam: Elsevier B. V.CrossRefGoogle Scholar
Suominen, V. 1987. Mafic dyke rocks in southwestern Finland. In Diabases and other mafic dyke rocks in Finland (eds Aro, K. & Laitakari, I.), pp. 151–72. Geological Survey of Finland, Report Investigation 76 (in Finnish).Google Scholar
Suominen, V. 1991. The chronostratigraghy of southwestern Finland with special reference to Postjotnian and Subjotnian diabases. Geological Survey of Finland, Bulletin 356, 100 pp.Google Scholar
Toplis, M. J. & Carroll, M. R. 1995. An experimental study of the influence of oxygen fugacity on Fe–Ti oxide stability, phase relations, and mineral–melt equilibria in ferro-basaltic systems. Journal of Petrology 36, 1137–70.CrossRefGoogle Scholar
Toplis, M. J., Libourel, G. & Carroll, M. R. 1994. The role of phosphorus in crystallization processes of basalt: an experimental study. Geochimica et Cosmochimica Acta 58, 797810.CrossRefGoogle Scholar
Vander Auwera, J. & Longhi, J. 1994. Experimental study of jotunite (hypersthene monzodiorite): constraints on the parent magma composition and crystallization conditions (P, T, fO2) of the Bjerkeim-Sokndal layered intrusion (Norway). Contributions to Mineralogy and Petrology 118, 6078.CrossRefGoogle Scholar
Vander Auwera, J., Longhi, J. & Duchesne, J. C. 1998. A liquid line of descent of the jotunite (hypersthene monzodiorite) suite. Journal of Petrology 39, 439–68.CrossRefGoogle Scholar
Wager, L. R. 1960. The major element variation of the layered series of the Skaergaard intrusion and a re-estimation of the average composition of the hidden layered series and of the successive residual magmas. Journal of Petrology 1, 364–98.CrossRefGoogle Scholar
Wager, L. R. & Brown, G. M. 1968. Layered Igneous Rocks. Edinburgh and London: Oliver and Boyd, 588 pp.Google Scholar
Walker, D. & Delong, S. E. 1982. Soret separation of mid-ocean ridge basalt magma. Contributions to Mineralogy and Petrology 79, 231–40.CrossRefGoogle Scholar
Wilson, J. R. & Engell-Sørensen, O. 1986. Marginal reversals in layered intrusions are evidence for emplacement of compositionally stratified magma. Nature 323, 616–18.CrossRefGoogle Scholar