Microstructured surfaces with pillar arrays are widely used to control the wetting morphology and spreading dynamics of droplets. In both simulations and experiments, it is shown that fabricating the surface with various microstructures is a very effective method for achieving the desired symmetry of the moving contact line. However, the method for characterizing miscellaneous pillar-arrayed microstructured surfaces is still insufficient. This paper presents the configurational entropy to characterize the microstructured surfaces with pillar arrays. By calculating the configurational entropy of pillar-arrayed microstructured surfaces, the relationship between the configurational entropy and the wetting morphology of droplets is obtained. For pillar-arrayed microstructured surfaces with the configurational entropy S > 0, the droplet wetting morphology may be much more complex than those with S = 0. The relationship is found to be consistent with the previous results. Furthermore, the wetting dynamics has been analysed. This study may be useful to understand the mechanism of droplet wetting on pillar-arrayed microstructured surfaces and provide insights for the design and manufacture of microstructured surfaces.

The steady-state current–voltage response of ion-selective systems varies as the number of ion-selective components is varied. For the highly investigated unipolar system, including only one ion-selective component, it has been shown that above a supercritical voltage, an electroosmotic instability is triggered, leading to overlimiting currents. In contrast, the effects of this instability on the current–voltage response of the second most common system of a bipolar system, including two oppositely charged permselective regions, have yet to be reported. Using numerical simulations, we investigate the steady-state electrical response of bipolar systems as we vary the ratio of the charge within the two oppositely charged regions. The responses are divided into those with an internal symmetry related to the surface charge and those without. In contrast to the unipolar systems, bipolar systems with the internal symmetry do not exhibit overlimiting currents and their steady-state response is identical to the convectionless steady-state response. In contrast, the systems without the internal symmetry exhibit much more complicated behaviour. For positive voltages, they have overlimiting currents, while for negative voltages, they do not have overlimiting currents. Our findings contribute to a more profound understanding of the behaviour of the current–voltage response in bipolar systems.

The most common method to characterize the electrical response of a nanofluidic system is through its steady-state current–voltage response. In Part 1, we demonstrated that this current–voltage response depends on the geometry, the layout of the surface charge and the effects of advection. We demonstrated that each configuration has a unique steady-state signature. Here, we will elucidate the behaviour of the time-transient response. Similar to the steady-state response, we will show that each configuration has its own unique time-transient signature when subjected to electroosmotic instability. We show that bipolar systems behave differently than unipolar systems. In unipolar systems, the instability appears only at one end of the system. In contrast, in bipolar systems the instability will either appear on both sides of the nanochannel or not at all. If it does appear on both sides, the instability will eventually vanish on one or both sides of the system. In Part 1, these phenomena were explained using steady-state considerations of the behaviour of the fluxes. Here, we will examine the time-transient behaviour to reveal the governing principles that are, on the one hand, not so different from unipolar systems and, on the other hand, remarkably different.

We model the slip length tribometer (SLT), originally presented by Pelz et al. (J. Fluid Mech., vol. 948, 2022, p. A8) in OpenFOAM. The plate tribometer is especially designed to simultaneously measure viscosity and slip length for lubrication gaps in the range of approximately 10 $\mathrm {\mu }$m at temperatures and surface roughnesses relevant to technical applications, with a temperature range of $-30$ to $100\,^\circ \mathrm {C}$ and surface roughness ranging from $10\ \mathrm {nm}$ to $1\ \mathrm {\mu }\mathrm {m}$. A simplified analytical model presented by Pelz et al. (J. Fluid Mech., vol. 948, 2022, p. A8) infers the slip length of the plate from the experimentally measured torque and the plate gap height. The present work verifies the analytical model using axisymmetric flow simulations and presents the effect of inlet on the numerical velocity profiles. The simulation results are in very good agreement with the results of the analytical model. The main conclusion drawn from this study is the validation of the Navier-slip boundary condition as an effective model for partial slip in computational fluid dynamics simulations and the negligible influence of the inlet on the fluid flow between the SLT's plates.