Over the first half of the nineteenth century, the Prussian-German customs union known as the Zollverein gradually unified a scattered confederation of sovereign states under an internal free trade agreement. This article uses grain prices to quantify the differential effect of the Zollverein for market integration among Zollverein members versus European powers that were not part of the Zollverein, including France, Switzerland, and the Habsburg Empire of Austria. Overall, this border effect is consistently and substantially less than border effect estimates from contemporary samples. For the 1834 liberalisation round, the implied border effect, calculated as the implied decrease in distance that comes about as the result of the customs border being eliminated, is between 140 and 160 kilometres, with the smaller distance for non-German speaking cities, and the larger distance for German–speaking cities. Thus, common language in this sample provides an additional benefit of lowering trade barriers by 11–15 percent in distance, making border elimination more valuable among German-speaking cities than for mixed-language-speaking cities. The article offers a few reasons for why I estimate smaller border effects than are found in studies on twentieth century economies, and the analysis gives a new historical perspective on what drives trade costs and changes in market integration.