The thermal equilibrium state of a bipolar, isothermal quantum fluid
confined to a bounded domain Ω⊂ℝd,
d = 1, 2 or d = 3 is the minimizer of the total energy
[Escr ]ελ; [Escr ]ελ involves
the squares of the scaled Planck's constant ε and
the scaled minimal Debye length λ. In
applications one frequently has λ2[Lt ]1.
In these cases the zero-space-charge approximation is rigorously justified. As
λ → 0, the particle densities converge to the minimizer of a limiting
quantum zero-space-charge functional exactly in those cases where the doping profile satisfies
some compatibility conditions. Under natural additional assumptions on the internal energies
one gets an differential-algebraic system for the limiting
(λ = 0) particle densities, namely
the quantum zero-space-charge model. The analysis of the subsequent limit
ε → 0 exhibits the importance of quantum gaps. The semiclassical
zero-space-charge model is, for small ε,
a reasonable approximation of the quantum model if and only if the quantum gap vanishes.
The simultaneous limit ε = λ → 0 is analyzed.