In examining the light reflected from the surface of calcareous spar, when in contact with different fluids, I observed several phenomena, both of light and colour, which led me to make the same experiments on the natural and artificial surfaces of the precious stones and other minerals. In these experiments, the intensity of the reflected pencil varied, as might have been expected, with the refractive power of the fluid; but I was not prepared for the curious fact, that when the reflective power of the surface was reduced almost to nothing, the surface was no longer able to reflect white light, but reflected pencils of different colours, depending on the approximation of the refractive power of the fluid to that of the solid. When the crystal had much double refraction, the colour of the reflected light varied with the inclination of the plane of reflection to the plane passing through the axis of the crystal.