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XV.—On the Thermal Energy of Molecular Vortices

Published online by Cambridge University Press:  17 January 2013

Extract

§ 1. Object of this Paper.—In a paper on the Mechanical Action of Heat, which I sent to the Royal Society of Edinburgh in December 1849, and which was read in February 1850, it was shown, that if sensible or thermometric heat consists in the motion of molecular vortices supposed to be arranged in a particular way, and combined in a particular way with oscillatory movements, the principles of thermodynamics, and various relations between heat and elasticity, are arrived at by applying the laws of dynamics to that hypothesis. The object of the present paper is to show how the general equation of thermodynamics, and other propositions, are deduced from the hypothesis of molecular vortices, when freed from all special suppositions as to the figure and arrangement of the vortices, and the properties of the matter that moves in them, and reduced to the following form:—That thermometric heat consists in a motion of the particles of bodies in circulating streams, with a velocity either constant or fluctuating periodically. This, of course, implies that the forces acting amongst those particles are capable of transmitting that motion.

Type
Research Article
Copyright
Copyright © Royal Society of Edinburgh 1869

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References

page 557 note * Transactions of the Royal Society of Edinburgh, 1850, vol. xx.Google Scholar

page 559 note * There is a well-known integration by which it is easily proved, that for a number of directions equally distributed round a point, the mean value of cos2θ is ⅓.

page 559 note † Called by Thomson and Tait the “Kinetic Energy.”

page 562 note * According to the nomenclature used by Clausius, the phrase “real specific heat” is applied to that part only of the specific heat which is necessarily constant for a given substance in all conditions. Hence, if that nomenclature were adapted to the hypothesis of molecular vortices, the term real specific heat would be applied to the coefficient given in equation (10) only, and that given in equation (11) would be considered as part of the apparent specific heat.

page 565 note * See Philos. Mag. for December 1865.

page 566 note * See Phil. Mag. December 1865.