Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-23T06:48:50.416Z Has data issue: false hasContentIssue false

XVI.—Distribution in some Scottish Soils of an Inorganic Gel System related to “Allophane”*

Published online by Cambridge University Press:  06 July 2012

J. H. Kirkman
Affiliation:
The Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen.
B. D. Mitchell
Affiliation:
The Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen.
R. C. Mackenzie
Affiliation:
The Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen.

Synopsis

Samples from the various horizons of five soil profiles representative of diverse types widely occurring in north-east Scotland were intensively examined, after separation into particle-size fractions, by appropriate instrumental and chemical techniques including optical examination, X-ray diffraction, electron microscopy and diffraction, infra-red absorption spectroscopy, thermal analysis procedures, chemical analysis and selective chemical dissolution. The results obtained are presented and assessed with respect to quantitative estimation of the mixed SiO2-Al2O3-Fe2O3 gel system occurring in these soils. At best results can be only semiquantitative, but interesting trends are observable in each profile and marked differences are noted between profiles on different parent materials, although this effect is somewhat obscured under impeded drainage conditions. The maturity of the soil is also a significant factor. Results in general can be explained in terms of current concepts on pedogenesis.

Type
Research Article
Copyright
Copyright © Royal Society of Edinburgh 1966

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

References to Literature

Antipov-Karataev, I. N., 1963. Personal communication.Google Scholar
Aomine, S., and Miyauchi, N., 1965. “Imogolite of Imogo-layers in Kyushu”, Soil Sci. Plant Nutr., Tokyo, 11, 212219.CrossRefGoogle Scholar
Aomine, S., and Wada, K., 1962. “Differential weathering of volcanic ash and pumice, resulting in formation of hydrated halloysite”, Amer. Min., 47, 10241048.Google Scholar
Brongniart, A., and Malaguti, J., 1841. “Second mémoire sur les kaolins ou argiles à porcelaine”, Arch. Mus. Hist. Nat., 2, 217256.Google Scholar
Brown, G., 1954. “Report of the Clay Minerals Group Sub-Committee on Nomenclature of Clay Minerals”, Clay Miner. Bull, 2, 249302.Google Scholar
Brunauer, S., Emmett, P. H., and Teller, E., 1938. “Adsorption of gases in multimolecular layers”, J. Amer. Chem. Soc., 60, 309319.CrossRefGoogle Scholar
Damour, A., and Salvétat, L. A., 1847. “Notice et analyses sur un hydrosilicate d'alumine trouvé à Montmorillon (Vienne)”, Ann. Chim. (Phys.), 21, 376383.Google Scholar
Dixon, J. B., and Jackson, M. L., 1959. “Dissolution of interlayers from intergradient soil clays after preheating to 400°C”, Science, 129, 16161617.CrossRefGoogle Scholar
Duff, R. B., Webley, D. M., and Scott, R. O., 1963. “The solubilization of minerals and related materials by 2-ketogluconic acid-producing bacteria”, Soil Sci., 95, 105114.CrossRefGoogle Scholar
Farmer, V. C., and Mitchell, B. D., 1963. “Occurrence of oxalates in soil clays following hydrogen peroxide treatment”, Soil Sci., 96, 221229.CrossRefGoogle Scholar
Farmer, V. C., and Russell, J. D., 1964. “The infra-red spectra of layer silicates”, Spectrochim. Acta, 20, 11491173.CrossRefGoogle Scholar
Fieldes, M., 1955. “Clay mineralogy of New Zealand soils, Part II. Allophane and related mineral colloids”, N.Z. J. Sci. Tech., 37B, 336350.Google Scholar
Fieldes, M., and Taylor, N. H., 1961. “Clay mineralogy of New Zealand soils, Part V. Mineral colloids and genetic classification”, N.Z. J. Sci., 4, 679706.Google Scholar
Follett, E. A. C., McHardy, W. J., Mitchell, B. D., and Smith, B. F. L., 1965 a. “Chemical dissolution techniques in the study of clays: Part I”, Clay Miner., 6, 2334.CrossRefGoogle Scholar
Follett, E. A. C., 1965 b. “Chemical dissolution techniques in the study of clays: Part II”, Clay Miner., 6, 3543.CrossRefGoogle Scholar
Foster, M. D., 1953. “Geochemical studies of clay minerals. III. The determination of free silica and free alumina in montmorillonites”, Geochim. et Cosmoch. Acta, 3, 143154.CrossRefGoogle Scholar
Glentworth, R., 1954. The soils of the country round Banff, Huntly and Turriff. Edinburgh: H.M.S.O.Google Scholar
Glentworth, R., and Muir, J. W., 1963. The soils of the country round Aberdeen, Inverurie and Fraserburgh. Edinburgh: H.M.S.O.Google Scholar
Gradwell, M., and Birrell, K. S., 1954. “Physical properties of certain volcanic clays”, N.Z. J. Sci. Tech., 36B, 108122.Google Scholar
Hashimoto, I., and Jackson, M. L., 1960. “Rapid dissolution of allophane and kaolinite-halloysite after dehydration”, Clays Clay Miner., 7, 102113.CrossRefGoogle Scholar
Henderson, M. E. K., and Duff, R. B., 1963, “The release of metallic and silicate ions from minerals, rocks and soils by fungal activity”, J. Soil Sci., 14, 236245.CrossRefGoogle Scholar
Jackson, M. L., 1956. Soil chemical analysis—Advanced course. Madison, Wisconsin: Professor M. L. Jackson.Google Scholar
Jackson, M. L., 1963. “Interlayering of expansible layer silicates in soils by chemical weathering”, Clays Clay Miner., 11, 2946.CrossRefGoogle Scholar
Kanno, I., 1959. “Clay minerals of volcanic ash soils and pumices in Japan”, Adv. Clay Sci., Tokyo, 1, 213233.Google Scholar
Mackenzie, R. C., 1951. “A micromethod for determination of cation-exchange capacity of clay”, J. Colloid Sci., 6, 219222.Google Scholar
Mackenzie, R. C., 1956. “Methods for separation of soil clays in use at the Macaulay Institute for Soil Research”, Clay Miner. Bull., 3, 36.CrossRefGoogle Scholar
Mackenzie, R. C., 1957. The differential thermal investigation of clays (Mackenzie, R. C., Ed.). Ch. XII, 299328. London: Mineralogical Society.Google Scholar
Martin, R. T., 1954. “Calcium oxalate formation in soils from hydrogen peroxide treatment”, Soil Sci., 77, 143145.CrossRefGoogle Scholar
Mitchell, B. D., and Farmer, V. C., 1962. “Amorphous clay minerals in some Scottish soil profiles”, Clay Miner. Bull., 5, 128144.CrossRefGoogle Scholar
Mitchell, B. D., and Mackenzie, R. C., 1954. “The removal of free iron oxides from soil clays”, Soil Sci., 77, 175184.CrossRefGoogle Scholar
Mitchell, B. D., and Mackenzie, R. C., 1959. “An apparatus for differential thermal analysis under controlled-atmosphere conditions”, Clay Miner. Bull., 4, 3143.CrossRefGoogle Scholar
Mitchell, B. D., Farmer, V. C., and McHardy, W. J., 1964. “Amorphous inorganic material in soil”, Adv. Agron., 16, 327383.CrossRefGoogle Scholar
Mitchell, W. A., 1955. “A review of the mineralogy of Scottish soil clays”, J. Soil Sci., 6, 9498.CrossRefGoogle Scholar
Mitchell, W. A., 1966. “Methods of mineralogical analysis of soils”, Proc. Int. Study Group on Soils, Cambridge, 1964. (In press).Google Scholar
Riemann, W. A., 1809. See Hoffman, C. A. S., 1818. Handbuch der Mineralogie, IV–2, 182.Google Scholar
Robertson, G., 1950. “The colorimetric determination of aluminium in silicate materials”, J. Sci. Fd Agric., 1, 5963.CrossRefGoogle Scholar
Robertson, R. H. S., 1963. “Allophanic soil from Trail Bridge, Oregon, with notes on mosaic growth in clay minerals”, Clay Miner. Bull., 5, 237247.CrossRefGoogle Scholar
Salvétat, L. A., 1851. “Analyses de quelques hydrosilicates d'alumine”, Ann. Chim. (Phys.), 31, 102116.Google Scholar
Scott, R. O., 1941. “The colorimetric estimation of iron with sodium salicylate”, Analyst, Lond., 66, 142148.CrossRefGoogle Scholar
Shapiro, L., and Brannock, W. W., 1952. “Rapid analysis of silicate rocks”, Circ. U.S. Geol. Surv., 165.Google Scholar
Shapiro, L., 1956. “Rapid analysis of silicate rocks”, Bull. U.S. Geol. Surv., 1036C.Google Scholar
(Stromeyer, F.), 1816. Gotting. Gelehr. Anz., p. 1251.Google Scholar
Sudo, T., 1954. “Clay mineralogical aspects of the alteration of volcanic glass in Japan”, Clay Miner. Bull., 2, 96106.CrossRefGoogle Scholar
Sudo, T., 1956. “X-ray and thermal data for clay minerals formed by the alteration of volcanic materials”, Sci. Rep. Tokyo Kyoiku Daig., C5, 3955.Google Scholar
Tamura, T., Jackson, M. L., and Sherman, G. D., 1953. “Mineral content of low humic, humic, and hydrol humic latosols of Hawaii”, Proc. Soil Sci. Soc. Amer., 17, 343346.CrossRefGoogle Scholar
White, W. A., 1953. “Allophanes from Lawrence County, Indiana”, Amer. Min., 38, 634642.Google Scholar