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X. On the Preparation of Paracyanogen in large quantities, and on the Isomerism of Cyanogen and Paracyanogen

Published online by Cambridge University Press:  17 January 2013

Extract

The design of the processes described in this memoir was to decompose the bicyanuret of mercury at such a temperature, and under such a degree of pressure, as to secure the simultaneous extrication of the two equivalents of cyanogen, or their elements, in the expectation that they should come off united, and produce the interesting compound of nitrogen and carbon, isomeric with cyanogen, Paracyanogen : And that result was sought in the belief that it would illustrate the chemical theorem of the existence of bodies which, though composed of the same elements in the same proportions, yet differ as widely from each other in chemical properties and mechanical conditions, as one element differs from another.

Type
Transactions
Copyright
Copyright © Royal Society of Edinburgh 1844

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References

page 165 note * Ann. de Ch. 1815.

page 174 note * I have borrowed the phrase “equal and similar” from geometry, because several atoms are equal which are not similar. It implies identity both of atomic weight and of true isomorphism, both of force and of form.

page 175 note * For example, the carbo-hydrogenous series of isomeric bodies would be represented thus :—