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IX. Farther Researches on the Voltaic Decomposition of Aqueous and Alcoholic Solutions

Published online by Cambridge University Press:  17 January 2013

Extract

Since my last communication to the Society on this subject, I have continued my experimental investigation of the proposed law which limited the direct action of the voltaic current to the solvent, in solutions of primary combinations of elementary bodies in the more important solvents. All my farther researches have confirmed the rule in regard to aqueous solutions; and I feel now fully convinced of its truth, although, in the mean time, I have had occasion to see a different view advocated by some other experimenters, to whose opinions I shall afterwards advert. Neither have I seen any grounds for altering my views in regard to alcoholic solutions. In regard to ether, some experiments which I shall afterwards mention, have satisfied me that it would be improper at present to include that solvent in any general rule.

Type
Transactions
Copyright
Copyright © Royal Society of Edinburgh 1844

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References

page 151 note * Edin. Trans, vol. xiii. p. 339, and xiv. p. 116.

page 151 note † Ibid. xiv. p. 119.

page 151 note ‡ Ibid. xiii. 338.

page 151 note § Fig. 1, Pl. II. vol. xiv. Edin. Trans., bottom of Plate.

page 152 note * Edin. Trans, vol. xiv. p. 127.

page 153 note * Edin. Trans, xiii. 344, and xiv. 118.

page 154 note * Bib. Univ.

page 155 note * Fig. 2. Plate II., Ed. Trans, xiv.

page 156 note * The zinc pole usually gets slightly blackened both in alcoholic and aqueous solutions, but this darkish matter was carefully examined and found to be merely oxidated zinc.

page 157 note * Fig. 1, Pl. II., Edin. Trans. vol. xiv.

page 158 note * Edin. Trans, xiv. 127.

page 159 note * Fig. 3, Pl. II. Edin. Trans. xiv.

page 161 note * Edin. Trans, xiv. Plate II.

page 163 note * Long after these experiments were made, and conclusions drawn, I observed that M. Becquerel had also found that bromine and iodine, in solution, unite with hydrogen under Galvanic Agency. L'Institut. Juin, 1840.