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Transmission and Analytical Electron Microscopic Study of Mixed-Layer Illite/Smectite Formed as an Apparent Replacement Product of Diagenetic Illite

Published online by Cambridge University Press:  02 April 2024

Wei-Teh Jiang ,
Donald R. Peacor ,
R. J. Merriman  and
B. Roberts
Wei-Teh Jiang
Affiliation:
Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109
Donald R. Peacor
Affiliation:
Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109
R. J. Merriman
Affiliation:
British Geological Survey, Keyworth, Nottingham NG12 5GG, United Kingdom
B. Roberts
Affiliation:
Geology Department, Birkbeck College, 7-15, Gresse Street, London W1P 1PA, United Kingdom
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Abstract

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Ordered illite/smectite (I/S) and illite in a pelitic rock from a prograde metamorphic sequence in North Wales were observed by transmission electron microscopy. The dominant phyllosilicate noted was diagenetic-metamorphic illite, occurring as subparallel packets of layers, each about a few hundred Ångstroms thick. It exhibited two-layer polytypism (presumably 2M1) and numerous strain features and had a composition of (K1.21Na0.12)(Al3.36Fe0.31Mg0.33)(Si6.28Al1.72)O20(OH)4.

I/S occurred as thick packets of wavy layers having 10-Å subperiodicity and sharp differences in contrast in successive lattice fringes. All stages in a replacement series were noted, from one or two layers of smectite within illite, through thin packets of I/S, to thick packets that contained inherited deformation textures of diagenetic-metamorphic illite. Deformed illite was replaced by I/S more commonly than was undeformed illite. The I/S replacing undeformed original illite had significantly greater order, primarily of R1 type (ISISIS…), than that replacing deformed illite. R> 1 I/S occurred as small crystallites and contained relatively less smectite than the ordered I/S, Single smectite layers were spaced within several illite layers, forming curved packets of layers. IISIIS… (R2) and IIISIIIS… (R3) ordering were present locally, as was discrete smectite. Analytical electron microscopic analyses indicated that the I/S, (K0.46Na0.43)(Al3.75Fe0.06Mg0.19)(Si6.26Al1.74)O20(OH)4, was rectorite-like in composition and had smaller (Mg + Fe) contents and greater Al/Si ratios than the coexisting illite, which was also anomalous in terms of general crystal-chemical relationships between coexisting illite and I/S in burial diagenesis environments. The I/S appears to have formed by replacement of diagenetic-metamorphic illite, presumably at very low temperatures under hydrous conditions via dissolution and crystallization.

Keywords

Analytical electron microscopyDiagenesisIlliteIllite/smectiteMixed layerSmectiteTransmission electron microscopy
Type
Research Article
Information
Clays and Clay Minerals , Volume 38 , Issue 5 , October 1990 , pp. 449 - 468
Copyright
Copyright © 1990, The Clay Minerals Society

Footnotes

1

Contribution No. 471 from the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109.

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