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Synthesis and Properties of Sn-Containing Magadiite

Published online by Cambridge University Press:  01 January 2024

Wojciech Supronowicz ,
Frank Roessner ,
Wilhelm Schwieger ,
Mikhail Meilikhov  and
Daniel Esken
Wojciech Supronowicz*
Affiliation:
Faculty of Natural Sciences, Carl von Ossietzky University, Faculty of Natural Sciences, Industrial Chemistry II, D-26-111 Oldenburg, Germany
Frank Roessner
Affiliation:
Faculty of Natural Sciences, Carl von Ossietzky University, Faculty of Natural Sciences, Industrial Chemistry II, D-26-111 Oldenburg, Germany
Wilhelm Schwieger
Affiliation:
Lehrstuhl für Chemische Reaktionstechnik Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, D-91-058 Erlangen, Germany
Mikhail Meilikhov
Affiliation:
Lehrstuhl für Anorganische Chemie II NC 2, Universitaetstrasse 150 D-44-801 Bochum, Germany
Daniel Esken
Affiliation:
Lehrstuhl für Anorganische Chemie II NC 2, Universitaetstrasse 150 D-44-801 Bochum, Germany
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Hydrothermal syntheses of the magadiite, a layered silicate structure, were conducted in the presence of a heteroatom source (SnCl4.5H2O) with the intention of investigating its influence on the resulting material, as well as the possibility of isomorphous replacement of Si by Sn atoms in the abovementioned structure. For comparison, unmodified magadiite, Al-containing magadiite, and impregnated magadiite were synthesized. The magadiite structure was identified for samples with Sn/Si ratios up to 0.015. Synthetic methods applied to Sn-modified materials were found to be unsuitable for the introduction of Al. The characterization methods used were X-ray diffraction, temperature-programmed reduction, and 29Si magic angle spinning nuclear magnetic resonance and these revealed the substitution of Si by Sn in the silica layers. No additional acid centers on the surfaces of the modified samples were detected, suggesting the presence of the desired four-coordinate Sn in the silica layers.

Keywords

H2-TPRMagadiite29Si MAS NMRTextural PropertiesTin SilicateXRD
Type
Article
Information
Clays and Clay Minerals , Volume 60 , Issue 3 , June 2012 , pp. 254 - 264
Copyright
Copyright © Clay Minerals Society 2012

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