Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-27T00:43:21.869Z Has data issue: false hasContentIssue false

Suction Responses Due to Homogeneous Shear of Dilute Montmorillonite-Water Pastes

Published online by Cambridge University Press:  01 July 2024

Charles D. Ripple*
Affiliation:
Department of Soils and Plant Nutrition, University of California, Berkeley
Paul R. Day
Affiliation:
Department of Soils and Plant Nutrition, University of California, Berkeley
*
Present address: U.S. Geological Survey, 345 Middlofiold Road, Menlo Park, California.
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

A recently described phenomenon, the shear induced decrease of moisture suction in saturated clay—water systems and its subsequent recovery, has been investigated with the aid of a parallel plate shearing device. The apparatus allowed a more quantitative description of the phenomenon than was previously possible. In 4–6% Na-montmorillonite pastes it demonstrated a well defined suction response to shear oven for shear angles as small as one degree. The observed decrease in suction was rapid at first. It terminated within a few minutes and was followed by an approximately exponential, occasionally incomplete recovery. All the tests carried out exhibited the same general features of suction change.

It is postulated that shear induces a displacement or change in configuration of particles and that subsequently they return to their original states due to thermal motion. The shapes of the recovery curves can be interpreted in terms of the relaxation spectrum functions encountered in linear viscoelasticity theory. By utilizing a characteristic relaxation time for these spectra, rate process theory has been employed to interpret the bonding mechanism in terms of the experimental activation free energy. The results suggest that the bonds which are re-established during the recovery are primarily of the Coulombic type.

Shear induced suction changes should be considered when dealing with deformation theories and structural models of wet soils and clays. Indeed they provide a means of testing certain aspects of soil structure.

Type
Research Article
Copyright
Copyright © Clay Minerals Society 1966

Footnotes

*

This investigation was supported in part by Western Regional Projects W-30 and W-66 (Hatch Act).

References

Alfrey, T. Jr. and Gurnee, E. F. (1956) Dynamics of viscoelastic behavior: pp. 387429 in Rheology, Theory and Applications: Academic Press, Inc., New York, I, 761 pp.Google Scholar
Barshad, I. (1962) Personal communication.Google Scholar
Bernal, J. D. (1958) Structure arrangements of macromolecules: Disc. Faraday Soc. 25, 718.10.1039/df9582500007CrossRefGoogle Scholar
Burgers, J. M. and Scott Blair, G. W. (1948) Report on the principles of rheological nomenclature (Joint Committee on Rheology of the International Council of Scientific Unions): Proc. Internat. Rheologie Congress, Amsterdam.Google Scholar
Campanella, R. G. (1965) Effect of temperature and stress on the time-deformation behavior of saturated clay: Ph.D. Thesis, University of California, Berkeley.Google Scholar
Carlson, R. M. (1962) A study of some aspects of cation exchange in soils: Ph.D. Thesis, University of California, Berkeley.Google Scholar
Christensen, R. W. and Wu, T. H. (1964) Analysis of clay deformation as a rate process: Jour. Soil Mech. and Found. Div., Amer. Soc. Civil Engs., Proc. Paper 4147, pp. 125–57.Google Scholar
Day, P. R. (1954-56) Effect of shear on water tension in saturated clay: Reports to Western Regional Technical Committee W-30.Google Scholar
Day, P. R. and Ripple, S. D. (1966) Effect of shear on suction in saturated clays: (Submitted to Proc. Soil Science Soc. Amer.).CrossRefGoogle Scholar
Glasstone, S., Laidler, K. J. and Eyring, H. (1941) The Theory of Rate Processes: Ed. 1, McGraw-Hill, New York, 611 pp.Google Scholar
Kittel, S. (1962) Introduction to Solid-state Physics: John Wiley, New York, 617 pp.Google Scholar
Kolaian, J. H. and Low, P. F. (1962) Thermodynamic properties of water in suspensions of montmorillonite: Clays and Clay Minerals, Proc. 9th Conf., Pergamon Press, New York, 7184.10.1016/B978-1-4831-9842-2.50008-0CrossRefGoogle Scholar
Langmuir, I. (1938) The role of attractive and repulsive forces in the formation of tactoids, thixotropic gels, protein crystals and coacervates: Jour. Chem. Phys. 6, 873–96.Google Scholar
Leonard, R. A. and Low, P. F. (1964) Effect of gelation on the properties of water in clay systems: Clays and Clay Minerals, Proc. 12th Conf., Pergamon Press, New York, 311–25.Google Scholar
Low, P. F. (1960) The viscosity of water in clay systems: Clays and Clay Minerals, Proc. 8th Conf., Pergamon Press, New York, 170–82.Google Scholar
Marvin, R. S. (1962) Derivation of the relaxation spectrum representation of the mechanical response function: Natl. Bur. Stds. Jour. Res. 66A, 349–50.Google Scholar
Maxwell, J. C. (1867) On the dynamical theory of gases: Philos. Trans. 157, 4983.Google Scholar
Mitchell, J. K. (1964) Shearing resistance of soils as a rate process: Jour. Soil Mech. and Found. Div., Amer. Soc. Civil Engs. 90, No. SMI, Proc. Paper 3773, 2961.10.1061/JSFEAQ.0000593CrossRefGoogle Scholar
Mitchell, J. K. and Campanella, R. G. (1963) Creep studies on saturated clays: Symposium on Laboratory Shear Testing of Soils: ASTM-NRC, Ottawa, Canada, ASTM Special Tech. Publ. No. 361.Google Scholar
Muriyama, S. and Shibata, T. (1961) Rheological properties of clays: Proc. Fifth Internat. Conf. Soil Mech. and Found. Eng., 269–73.Google Scholar
Ree, T. and Eyring, H. (1958) The relaxation theory of transport phenomena, pp. 83144 in Rheology, Theory and Applications, II, Eirich, F. R., editor: Academic Press, Inc., New York, 591 pp.Google Scholar
Reece, J. M. (1959) Subaudio tunable amplifier: Electronics, Nov. 6 issue.Google Scholar
Ripple, C. D. (1965) Some physical responses to shear in montmorillonite-water systems: Ph.D. Thesis, University of California, Berkeley.Google Scholar
Shuler, K. E. (1959) Relaxation processes in multistate systems: Physics of Fluids 2, 442–8.Google Scholar
Shuler, K. E., Anderson, Y. and Weiss, G. M. (1962) Studies in non-equilibrium rate processes, V. The relaxation of moments derived from a master equation: Jour. Math. Phys. 3, 550–6.CrossRefGoogle Scholar