Hostname: page-component-848d4c4894-sjtt6 Total loading time: 0 Render date: 2024-07-08T00:02:53.109Z Has data issue: false hasContentIssue false
  • English
  • Français

A Study on the Cation Exchange of [Co(NH3)6]3+ from H-Co (NH3)6-Vermiculite by Inorganic and Quaternary Ammonium Ions

Published online by Cambridge University Press:  01 July 2024

J. L. Das Kanungo
J. L. Das Kanungo*
Affiliation:
Department of Chemistry, University of North Bengal, P.O. North Bengal University, Dist. Darjeeling, West Bengal, India
*
*Present address: Department of Soil Science, University of Reading, Reading, England
Get access Rights & Permissions [Opens in a new window]

Abstract

The exchange of [Co(NH3)6]3+ from its vermiculite complex has been carried out with a number of inorganic and alkyl quaternary ammonium ions of varying ionic sizes. The distribution and selectivity coefficients of the desorbing ions increase in the order: Li<Na<NH4<K<Rb<H<Cs for the monovalent, Ca<Mg for the bivalent and (C2H5)4N<(CH3)4N≪CTA (cetyl trimethyl ammonium) <CP (cetyl pyridinium) for the organic ions. The ΔG° values of some of the cation exchange reactions have been calculated by an equation of Kielland (1935).

Type
Research Article
Information
Clays and Clay Minerals , Volume 23 , Issue 5 , October 1975 , pp. 361 - 364
Copyright
Copyright © 1975, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

†

Permanent address.

References

Barrer, R. M. Buser, W. and Grütter, W. F., (1956) Synthetic “faujasit”—I: Properties and base exchange character Helv. Chim. Acta. 39 518–530.CrossRefGoogle Scholar
Barrer, R. M. and Falconer, J. D., (1956) Ion exchange in felspathoids as a solid state reaction Proc. R. Soc. A236 227–249.Google Scholar
Barshad, I., (1954) Cation exchange in micaceous minerals —II. Replaceability of ammonium and potassium from vermiculite, biotite, and montmorillonite Soil Sci. 78 57–76.CrossRefGoogle Scholar
Beckett, P. H. T., (1964) Soil potassium—I: Confirmation of the ratio law: measurement of potassium potential J. Soil Sci. 15 1–8.CrossRefGoogle Scholar
Conway, B. E., (1952) Electro-chemical Data 76–78.Google Scholar
Das Kanungo, J. L. and Chakravarti, S. K., (1971) Evaluation of thermodynamic quantities etc. in the cation exchange of Mg2+ from magnesium saturated bentonite and vermiculite Kolloid Z. 248 953–958.CrossRefGoogle Scholar
Das Kanungo, J. L. and Chakravarti, S. K., (1971) Behavior of quaternary ammonium ions in the desorption of [Coen3]3+ from H-Coen3-bentonite J. Colloid Interface Sci. 35 295–299.CrossRefGoogle Scholar
De, D. K., (1968) Studies on sorption and desorption of dyes on aluminosilicates India Ph.D. Thesis, University of Kalyani.Google Scholar
Garrett, W. G. and Walker, G. F., (1962) Swelling of some vermiculite organic complexes in water Proc. Nat. Conf. Clays and Clay Minerals 9 557–567.CrossRefGoogle Scholar
Ghosal, D. N. and Mukherjee, S. K., (1972) Studies on the sorption and desorption of crystal violet on and from bentonite and kaolinite J. Ind. Chem. Soc. 49 569–572.Google Scholar
Gruner, J. W., (1934) The structures of vermiculites and their collapse by dehydration Am. Miner. 19 557–575.Google Scholar
Helfferich, F., (1962) Ion Exchange New York McGraw-Hill.Google Scholar
Hendricks, S. B. and Alexander, L. T., (1940) Semi quantitative estimation of montmorillonite in clays Soil Sci. Soc. Am. Proc. 5 95–99.CrossRefGoogle Scholar
Jenkins, I. L. and Monk, C. B., (1951) The conductivities of some complex chlorides and sulphates J. Chem. Soc. 68–73.CrossRefGoogle Scholar
Kielland, J., (1935) Thermodynamics of base exchange equilibria of some different clays J. Soc. Chem. Ind. 54 232–247.Google Scholar
Kielland, J., (1937) Individual coefficient of ion in aqueous solution J. Am. Chem. Soc. 59 1675–1678.CrossRefGoogle Scholar
Peterson, F. F. Rhoades, J. Arca, M. and Coleman, N. T., (1965) Selective adsorption of Magnesium ions by vermiculite Soil Sci. Soc. Am. Proc. 29 327–328.CrossRefGoogle Scholar
Ram, G. and Rastogi, A. K., (1966) Abnormal partial ionic volumes of some tetra alkyl ammoniun ions in water J. Ind. Chem. Soc. 43 269–271.Google Scholar
Sutherland, H. H. and MacEwan, D. M. C., (1961) Organic complexes of vermiculite Clay Min. Bull. 4 229–233.CrossRefGoogle Scholar
Weiss, A. Mehler, A. and Hofmann, U., (1956) Zur Kenntnis von organophilem vermikulit Z. Naturf. 11b 431–434.CrossRefGoogle Scholar
Wild, A. and Keay, J., (1964) Cation exchange equilibria with vermiculite J. Soil Sci. 15 135–144.CrossRefGoogle Scholar