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Structural Investigations of Natural and Synthetic Chlorite Minerals by X-ray Diffraction, Mössbauer Spectroscopy and Solid-State Nuclear Magnetic Resonance

Published online by Cambridge University Press:  01 January 2024

Åsa Zazzi ,
Tomas K. Hirsch ,
Ekaterina Leonova ,
Andrei Kaikkonen ,
Jekabs Grins ,
Hans Annersten  and
Mattias Edén
Åsa Zazzi
Affiliation:
Department of Chemistry, Royal Institute of Technology, SE-100 44 Stockholm, Sweden
Tomas K. Hirsch*
Affiliation:
Physical Chemistry Division, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden
Ekaterina Leonova
Affiliation:
Physical Chemistry Division, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden
Andrei Kaikkonen
Affiliation:
Physical Chemistry Division, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden
Jekabs Grins
Affiliation:
Inorganic Chemistry Division, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden
Hans Annersten
Affiliation:
Department of Earth Sciences, Uppsala University, SE-752 36 Uppsala, Sweden
Mattias Edén*
Affiliation:
Physical Chemistry Division, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden
*
†Present address: Stanford Synchrotron Radiation Laboratory, 2575 Sand Hill Road, MS 69, Menlo Park, California, 94025-7015, USA
*E-mail address of corresponding author: [email protected]
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Abstract

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The structures of one synthetic and two natural chlorites of the chlinochlore type were explored using X-ray diffraction, magic-angle spinning nuclear magnetic resonance (NMR) and Mössbauer spectroscopy. Rietveld refinements indicated that all structures are of the trioctahedral ordered IIb polytype. Mössbauer spectra provided the ratio IIFe/IIIFe but gave no evidence for the presence of IIIFe in the brucite-like sheet. We also report unit-cell parameters, Mössbauer isomeric shifts, Si NMR chemical shifts as well as 27Al isotropic shifts and quadrupolar coupling parameters. Very broad 29Si NMR peaks from the natural samples prevented us from obtaining accurate information on the Si-Al ordering in the tetrahedral sheets; the limitations of 29Si NMR as applied to natural chlorites are discussed. High-resolution 3QMAS NMR resolved the 27Al signal of the M4 octahedral site in the brucite-like sheet from the other three Al signals of crystallographically inequivalent octahedral positions.

Keywords

27Al NMRCation DistributionsChloriteLayered MineralMineral StructureMössbauer Spectroscopy29Si NMRXRD
Type
Research Article
Information
Clays and Clay Minerals , Volume 54 , Issue 2 , April 2006 , pp. 252 - 265
Copyright
Copyright © 2006, The Clay Minerals Society

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