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Sorption of Atrazine by Al- and Ca-Saturated Smectite

Published online by Cambridge University Press:  28 February 2024

B. L. Sawhney  and
S. S. Singh
B. L. Sawhney
Affiliation:
The Connecticut Agricultural Experiment Station, New Haven, Connecticut 06504
S. S. Singh
Affiliation:
Land Resource Research Center, Agriculture Canada, Ottawa, Ontario K1AOC6, Canada
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Abstract

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Because of the large surface area and common occurrence of smectites in the clay fractions, they are important in sorption/desorption reactions of organic pollutants entering soils and sediments. Results of sorption and desorption of atrazine by Al- and Ca-saturated smectite reported here showed that Al-saturated smectite sorbed much higher amounts of atrazine than Ca-saturated smectite. Al-saturated smectite sorbed 3820 mg kg−1 as compared to 1902 mg kg−1 by the Ca-saturated smectite during 5 consecutive sorptions from 10 ppm atrazine solution. Sorption isotherms over 2–10 ppm atrazine concentration range were nonlinear in all cases. Freundich coefficients, Kf, obtained from the sorption isotherms were much higher for Al- than Ca-saturated smectite; Kf varied from 405 to 3035 for Al-saturated and 100 to 306 for Ca-saturated. The pH values of Al- and Ca-saturated smectites were 3–4 units higher than the pKa (1.68) of atrazine, which suggests that atrazine was sorbed as neutral molecules. Stronger H-bonding between the more polarized H2O associated with the trivalent Al ion than the divalent Ca ion is likely responsible for the greater sorption by Al-smectite.

Keywords

Cation-PolarizationNonionic OrganicsSmectiteSurface-Hydrophobicity
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 3 , June 1997 , pp. 333 - 338
Copyright
Copyright © 1997, The Clay Minerals Society

References

Ainsworth, C.C. Zachara, J.M. and Schmidt, R.L., (1987) Quinoline sorption on Na-montmorillonite: Contributions of the protonated and neutral species Clays Clay Miner 35 35–128 10.1346/CCMN.1987.0350204.CrossRefGoogle Scholar
Aochi, Y.O. Farmer, W.J. and Sawhney, B.L., (1992) In situ investigation of 1,2-dibromoethane sorption/desorption processes on clay mineral surfaces by diffuse reflectance infrared spectroscopy Environ Sci Technol 26 26–335 10.1021/es00026a013.CrossRefGoogle Scholar
Bailey, S.W. and Bailey, S.W., (1966) The status of clay mineral structures Proc 14th Natl Conf New York Pergamon Pr. 1–23.Google Scholar
Bleam, W.E., (1990) The nature of cation-substitution sites in phyllosilicates Clays Clay Miner 38 38–536.CrossRefGoogle Scholar
Boyd, S.A. and Jaynes, W.E., (1994) Role of layer charge in organic contaminant sorption by organo-clays Layer charge characteristics of 2:1 silicate clay minerals, CMS workshop lectures 6 48–77.Google Scholar
Burchill, S. Hayes, M.B.H. Greenland, D.J., Greenland, D.J. and Hayes, M.H.B., (1981) Adsorption The chemistry of soil processes New York J Wiley 221–400.Google Scholar
Call, F., (1957) The mechanism of sorption of ethylene dibromide on moist soils J Sci Food Agric 8 8–639.CrossRefGoogle Scholar
Chen, N.Y., (1976) Hydrophobic properties of zeolites J Phys Chem 80 80 64 10.1021/j100542a013.CrossRefGoogle Scholar
Chiou, C.T. Porter, P.E. and Schmedding, D.W., (1983) Partition equilibria of nonionic organic compounds between soil organic matter and water Environ Sci Technol 17 17–231 10.1021/es00110a009.CrossRefGoogle Scholar
Chiou, C.T. and Shoup, T.D., (1985) Soil sorption of organic vapors and effects of humidity on sorptive mechanism and capacity Environ Sci Technol 19 19–1200 10.1021/es00131a605.CrossRefGoogle ScholarPubMed
Cox, L. Hermosin, M.C. and Cornejo, J., (1995) Adsorption mechanism of Thiazfluron in mineral soil clay components Eur J Soil Sci 46 46–438 10.1111/j.1365-2389.1995.tb01339.x.CrossRefGoogle Scholar
Farmer, V.C., Greenland, D.J. and Hayes, M.H.B., (1978) Water on particle surfaces The chemistry of soil constituents New York J. Wiley 405–448.Google Scholar
Farrell, J. and Reinhard, M., (1994) Desorption of halogenated or-ganics from model solids, sediments, and soil under unsaturated conditions. I. Isotherms Environ Sci Technol 28 53–62 10.1021/es00050a009.CrossRefGoogle Scholar
Gilchrist, G.F.R. Gamble, D.S. Kodama, H. and Khan, S.U., (1993) Atrazine interaction with clay minerals: Kinetics and equilibria of sorption J Agric Food Chem 41 41–1755 10.1021/jf00034a043.CrossRefGoogle Scholar
Haderlein, S.B. and Schwarzenbach, R.P., (1993) Adsorption of substituted nitrobenzenes and nitrophenols to mineral surfaces Environ Sci Technol 27 27–326 10.1021/es00039a012.CrossRefGoogle Scholar
Hayes, M.H.B. Mingelgrin, U. et al. , Bolt, G.H. 1991 et al. , Interactions between small organic chemicals and soil colloidal constituents Interactions at the soil colloid-soil solution interface Boston Kluwer Academic Publ 323–407 10.1007/978-94-017-1909-4_11.CrossRefGoogle Scholar
Jaynes, W.F. and Boyd, S.A., (1991) Hydrophobicity of siloxane surfaces in smectites as revealed by aromatic hydrocarbon adsorption from water Clays Clay Miner 19 19–436.Google Scholar
Karickhoff, S.W., (1980) Sorption kinetics of hydrophobic pollutants in natural sediments Contaminants and sediments 2 193–205.Google Scholar
Laird, D.A., Meyer, M.T. and Thurman, E.M., (1996) Interactions between atrazine and smectite surfaces Chemistry of herbicides metabolites in surface and groundwater, ACS Symposium Series 630 86–100 10.1021/bk-1996-0630.ch008.Google Scholar
Laird, D.A. Barriuso, E. Dowdy, R.H. and Koskinen, W.C., (1992) Adsorption of atrazine on smectites Soil Sci Soc Am J 56 56–67 10.2136/sssaj1992.03615995005600010010x.CrossRefGoogle Scholar
McBride, M.B. et al. , Bolt, G.H. 1991 et al. , Selected cases of specific binding of ions by soil constituents Interactions at the soil colloid-soil solution interface Boston Kluwer Academic Publ. 147–175.Google Scholar
Mingelgrin, U. and Gerstl, Z., (1983) Reevaluation of partitioning as a mechanism of nonionic chemicals adsorption in soils J Environ Qual 12 12 11 10.2134/jeq1983.00472425001200010001x.CrossRefGoogle Scholar
Mortland, M.M., (1970) Clay-organic complexes and interactions Advances in agronomy 22 75–117 10.1016/S0065-2113(08)60266-7.CrossRefGoogle Scholar
Mortland, M.M. Fripiat, J.J. Chaussidon, J. and Vytterhoven, J., (1963) Interaction between ammonia and expanding lattices of montmorillonite and vermiculite J Phys Chem 67 67–258 10.1021/j100796a009.CrossRefGoogle Scholar
Norris, J. Giese, R. v. Oss, C.J. and Costanzo, D.M., (1992) Hydrophobic nature of organo-clays as Lewis acid/base phenomenon Clays Clay Miner 40 40–334 10.1346/CCMN.1992.0400313.CrossRefGoogle Scholar
Pignatello, J.J. and Xing, B., (1996) Mechanisms of slow sorption of organic chemicals to natural particles J Environ Sci Technol 30 30 11 10.1021/es940683g.CrossRefGoogle Scholar
Rebhun, M. Kalabo, R. Grossman, L. Manka, J. and Rav-Acha, C.H., (1992) Sorption of organics on clay and synthetic humicclay complexes simulating aquifer processes Water Res 26 26–84 10.1016/0043-1354(92)90114-J.CrossRefGoogle Scholar
Sawhney, B.L., (1996) Sorption and desorption of organic contaminants by clays and soils Organic pollutants in the environment, CMS workshop lectures 8 45–68.Google Scholar
Sawhney, B.L. and Gent, M.P.N., (1990) Hydrophobicity of clay surfaces: Sorption of 1,2-dibromoethene and trichloroethane Clays Clay Miner 38 38 20 10.1346/CCMN.1990.0380102.CrossRefGoogle Scholar
Schwarzenbach, R.P. and Westall, J.C., (1981) Transport of nonpolar organic compounds from surface water to ground water. Laboratory sorption studies Environ Sci Technol 15 15–1367 10.1021/es00093a009.CrossRefGoogle Scholar
Siantar, D.P. Feinberg, B.A. and Fripiat, J.J., (1994) Interaction between organic and inorganic pollutants in the clay interlayer Clays Clay Miner 42 42–196 10.1346/CCMN.1994.0420209.CrossRefGoogle Scholar
Singh, S.S. and Kodama, H., (1988) Reactions of polynuclear hydroxyaluminum cations with montmorillonite and the formation of a 28-A° pillared complex Clays Clay Miner 36 36–402 10.1346/CCMN.1988.0360503.CrossRefGoogle Scholar
Sposito, G., (1984) The surface chemistry of soils New York Oxford Univ Pr..Google Scholar
Swoboda, A.R. and Kunze, G.W., (1968) Reactivity of montmorillonite surfaces with weak organic bases Soil Sci Soc Am J 32 32–811 10.2136/sssaj1968.03615995003200060029x.CrossRefGoogle Scholar
Thibaud, C. Erkey, C. and Akgerman, A., (1993) Investigation of the effect of moisture on the sorption and desorption of chlorobenzene and toluene from soil Environ Sci Technol 27 27–2380 10.1021/es00048a010.CrossRefGoogle Scholar
Traina, S.J. and Onken, B.M., (1991) Cosorption of aromatic N-heterocycles and pyrene by smectites in aqueous solutions J Contam Hydrol 7 7–259 10.1016/0169-7722(91)90030-5.CrossRefGoogle Scholar
Ukrainczyk, I. and Smith, K., (1996) Solid state 15N NMR study of pyridine adsorption on clay minerals Environ Sci Technol 30 30–3176 10.1021/es950735h.CrossRefGoogle Scholar
Welhouse, G.J. and Bleam, W.F., (1992) NMR spectroscopic investigation of hydrogen bonding in atrazine Environ Sci Technol 26 26–964 10.1021/es00029a014.CrossRefGoogle Scholar
Yamane, V.K. and Green, R.E., (1972) Adsorption of ametryne and atrazine on anoxisol, montmorillonite, and charcoal in relation to pH and solubility effects Soil Sci Soc Am Proc 36 59–64 10.2136/sssaj1972.03615995003600010013x.CrossRefGoogle Scholar
Zachara, J.M. Ainsworth, C.C. and Smith, S.C., (1990) The sorption of N-heteroyclic compounds on reference and subsurface smectite clay isolates J Contam Hydrol 6 6–305 10.1016/0169-7722(90)90022-9.CrossRefGoogle Scholar