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Smectite-Illite Transition in Barbados Accretionary Wedge Sediments: Tem and Aem Evidence for Dissolution/Crystallization at Low Temperature

Published online by Cambridge University Press:  28 February 2024

Martine D. Buatier ,
Donald R. Peacor  and
James R. O'Neil
Martine D. Buatier*
Affiliation:
Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109
Donald R. Peacor
Affiliation:
Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109
James R. O'Neil
Affiliation:
Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109
*
1Present address: Université des Sciences et Techniques de Lille, Laboratoire de dynamique sédimentaire et structurale, 596555 Villeneuve d'Ascq Cedex, France.
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Abstract

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Sediments from depths to 670 m in the Barbados accretionary complex and transecting the décollement zone have been studied by transmission and analytical electron microscopy (TEM/AEM). The sediments consist of claystone and mudstone intercalated with layers of volcanic ash. Smectite comprises the bulk of the noncalcareous sediments and forms a continuous matrix enveloping sparse, irregular, large grains of illite, chlorite, kaolinite and mixed-layer illite/chlorite of detrital origin at all depths. The detrital origin of illite is implied by illite-smectite textural relations, well-ordered 2M polytypism, and a muscovite-like composition. K is the dominant interlayer cation in smectite at all depths, in contrast to the Na and Ca that are normally present in similar rocks.

Deeper samples associated with the décollement zone contain small (up to 100 Å thick) illite packets included within still-dominant subparallel layers of contiguous smectite. AEM analyses of these packets imply illite-like compositions. Selected area electron diffraction (SAED) patterns show that this illite is the 1Md polytype. Packets display step-like terminations like those seen in illite of hydrothermal origin. The data collectively demonstrate that smectite transforms progressively to illite via a dissolution-recrystallization process within a depleting matrix of smectite, and not by a mechanism of layer replacement. This illite seems to form at depths as shallow as 500 m and temperatures of 20°-30°C, which is in marked contrast to the much higher temperature conditions normally assumed for this transformation. This implies that the high water/rock ratios associated with the décollement zone are significant in promoting reaction.

Keywords

Accretionary wedgeAEM analysesBarbadosElectron diffractionFluid-sediment interactionIlliteMixed-layerSmectiteTEM images
Type
Research Article
Information
Clays and Clay Minerals , Volume 40 , Issue 1 , February 1992 , pp. 65 - 80
Copyright
Copyright © 1992, The Clay Minerals Society

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