Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-25T08:21:45.622Z Has data issue: false hasContentIssue false
  • English
  • Français

Refined Relationships between Chemical Composition of Dioctahedral Fine-Grained Mica Minerals and Their Infrared Spectra within the OH Stretching Region. Part I: Identification of the OH Stretching Bands

Published online by Cambridge University Press:  28 February 2024

G. Besson  and
V. A. Drits
G. Besson
Affiliation:
CRMD-CNRS-Université, B.P. 6759, 45067 Orleans Cedex 2, France
V. A. Drits
Affiliation:
Geological Institute of the Russian Academy of Science, Pyzhevsky Street 7, 109017 Moscow, Russia
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

A large and representative collection of clay-size dioctahedral mica minerals differing in their chemical compositions has been studied by infrared (IR) spectroscopy in the OH stretching vibration region. Decomposition of the IR spectra in the individual OH bands has provided unambiguous identification of the band positions for each defined pair of octahedral cations bonded to OH groups. The presence of pyrophyllite-like local structural environments in samples having a deficiency of K in interlayers has been established. A set of the relationships between the OH frequencies corresponding to pairs of cations having different valency and mass has been found.

Keywords

CeladoniteGlauconiteIlliteIR SpectraLeucophylliteOH Stretching Frequency
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 2 , April 1997 , pp. 158 - 169
Copyright
Copyright © 1997, The Clay Minerals Society

References

Besson, G. and Drits, V.A.. 1997. Refined relationships between chemical composition of dioctahedral fine-grained micaceous minerals and their infrared spectra within the OH stretching region. Part II: The main factors affecting OH vibrations and quantitative analysis. Clays Clay Miner 45: 170–183.CrossRefGoogle Scholar
Besson, G. Drits, V.A., Dainyak, L.G. and Smoliar, B.B.. 1987. Analysis of cation distribution in dioctahedral micaceous minerals on the basis of IR spectroscopy data. Clay Miner 22: 465–478.CrossRefGoogle Scholar
Brindley, G.W. and Kao, C.C.. 1984. Structural and IR relations among brucite-like divalent metal hydroxides. Phys Chem Miner 10: 187–191.CrossRefGoogle Scholar
Chukhrov, F.V., Zvyagin, B.B., Drits, V.A., Gorshkov, A.I., Ermilova, L.P., Goilo, E.A. and Rudnitskaya, E.S.. 1978. The ferric analogue of pyrophyllite and related phases. In: Mortland, M., Farmer, V.C., editors. Proc Int Clay Conf Oxford 1978. Amsterdam: Elsevier Science. p 55–64.Google Scholar
Dainyak, L.G., Bookin, A.S. and Drits, V.A.. 1984. Interpretation of the Mössbauer spectra of dioctahedral Fe3+-layer silicates. 3 Celadononite. Kristallographiya 29: 312–321 (in Russian).Google Scholar
Drits, V.A., Kameneva, M.Y.u., Sakharov, B.A., Dainyak, L.G., Tsipursky, S.I., Smoliar, B.B., Bookin, A.S. and Salyn, A.L.. 1993. Determination of real crystal structure of glauconites and related phyllosilicates. Novosibirsk: Nauka. 200 p (in Russian).Google Scholar
Drits, V.A. and Kossovskaya, A.G.. 1991. Clay minerals: Micas, chlorites. Moscow: Nauka. 175 p (in Russian).Google Scholar
Eberl, D.D., Środoń, J., Lee, M., Nadeau, P.H. and Northrop, H.R.. 1987. Sericite from Silverston Caldera Colorado: Correlation among structure, composition, origin, and particle thickness. Amer Mineral 72: 914–934.Google Scholar
Farmer, V.C.. 1974. The layer silicate. In: Farmer, V.C., editor. The infrared spectra of minerals. Monograph 4. London: Mineral Soc p 331–364.CrossRefGoogle Scholar
Ivanovskaya, T.A.. 1986. Mineralogy of dioctahedral glauconites from sedimentary rocks of different ages [Ph.D. thesis.], Moscow: Moscow Univ. 25 p (in Russian).Google Scholar
Ivanovskaya, T.A., Tsipursky, S.I. and Yakovleva, O.V.. 1989. Mineralogy of globular glauconites from Vendian and Rephean of the Ural and Siberia. Litologiya and poleznye iskopaemye 3: 83–99 (in Russian).Google Scholar
Kimbara, K. and Shimoda, S.. 1973. A ferric celadonite in amygdales of dolerite at Taiheizan, Akita Prefecture. Japan Clay Sci 4: 143–150.Google Scholar
Langer, K., Chatterjee, N.D. and Abraham, K.. 1981. Infrared studies of some synthetic and natural 2M1 dioctahedral micas. N Jb Miner Abh 142: 91–110.Google Scholar
Lipkina, M.I., Drits, V.A., Tsipursky, S.I. and Ustinov, V.I.. 1987. Highly ferric dioctahedral layer silicates in hydrothermal rocks and sediments of volcanic formations of Japan sea. Izvestiya Akad Nauk, Seriya Geol 10: 92–111 (in Russian).Google Scholar
Malkova, K.M.. 1956. On the celadonite of Pobuzhye. Collected papers on mineralogy. Lvov: Lvov Geol Soc 10: 305–318 (in Russian).Google Scholar
Nikolaeva, I.V.. 1977. Minerals of the Glauconite Group in Sedimentary Formation. Moscow: Nauka. 321 p (in Russian).Google Scholar
Pavlishin, V.I., Platonov, A.N., Polshin, E.V., Semenova, T.F. and Starova, G.K.. 1978. Micas with iron in quadrupol coordination. Trans All-Union Min Soc 107: 165–175 (in Russian).Google Scholar
Raskazov, A.A.. 1984. Clay Minerals in potassium deposit. Moscow: Nauka. 73 p (in Russian).Google Scholar
Robert, J.L. and Kodama, H.. 1988. Generalization of the correlations between hydroxyl-stretching wavenumbers and composition of micas in the system K2O-Mg2O-Al2O3-SiO2-H2O: A single model for trioctahedral and dioctahedral micas. Amer J Sci 228 A: 196–212.Google Scholar
Russell, J.D.. 1987. Infrared methods. In: Wilson, M.J., editor. A handbook of determinative methods in clay mineralogy. New York: Chapman and Hall. p 133–173.Google Scholar
Saksena, B.D.. 1964. Infrared hydroxyl frequencies of muscovite, phlogopite and biotite micas in relation to their structures. Trans Farad Soc 60: 1715–1725.CrossRefGoogle Scholar
Shutov, V.D., Drits, V.A. and Kats, M.Y.a.. 1975. Crystal chemistry of glauconites as indicator of facial conditions of formation and postsedimental transformation of these minerals. In: Kossovskaya, A.G., editor. Crystal chemistry of minerals and geological problems. Moscow: Nauka. p 74-81 (in Russian).Google Scholar
Slonimskaya, M.V., Besson, G., Daynyak, L.G., Tchoubar, C. and Drits, V.A.. 1986. Interpretation of the IR spectra of celadonites, glauconites in the region of OH-stretching frequencies. Clay Miner 21: 377–388.CrossRefGoogle Scholar
Slonimskaya, M.V., Drits, V.A. and Finko, V.I.. 1978. Multistage dehydation of muscovites. Izvestiya Akad Nauk SSSR, Seriya Geolog 11: 98–105 (in Russian).Google Scholar
Sokolova, T.N., Drits, V.A., Sokolova, A.L. and Stepanova, K.A.. 1976. Structural and mineralogical characterization and formation conditions of leucophyllite from saliferous deposits of Inder. Litologiya and Poleznye Iskopaemye 6: 80–95 (in Russian).Google Scholar
Vedder, W.. 1964. Correlations between infrared spectrum and chemical composition of mica. Am Mineral 49: 736–768.Google Scholar
Velde, B.. 1978. Infrared spectra of synthetic micas in the series muscovite-Mg-Al celadonite. Am Mineral 63: 343–349.Google Scholar
Velde, B.. 1983. Infrared OH-stretch bands in potassic micas, talc, and saponite; Influence of electronic configuration and site of charge compensation. Am Mineral 68: 1169–1173.Google Scholar