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Reaction Pathways of Clay Minerals in Tropical Soils: Insights from Kaolinite-Smectite Synthesis Experiments

Published online by Cambridge University Press:  01 January 2024

Peter C. Ryan  and
F. Javier Huertas
Peter C. Ryan*
Affiliation:
Geology Department, Middlebury College, Middlebury, Vermont 05753, USA Instituto Andaluz de Ciencias de la Tierra (CSIC-Universidad of Granda), 18100, Armilla, Granada, Spain
F. Javier Huertas
Affiliation:
Instituto Andaluz de Ciencias de la Tierra (CSIC-Universidad of Granda), 18100, Armilla, Granada, Spain
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Pedogenic smectite from a young (Holocene) tropical soil was reacted in Al-rich solution at 150ºC for a range of reaction times (3 to 120 days) in orderto study mechanisms and rates associated with the transformation of smectite to kaolinite via interstratified kaolinite-smectite (K-S). As has been observed in tropical soils, the overall reaction rate is logarithmic, with rapid initial transformation of smectite to K-S with ~50% smectite layers, followed by progressively slower transformation of intermediate K-S to kaolinite-rich K-S and eventually Fe-kaolinite. Sub-micron hexagonal non-Fe-bearing kaolinite forms in the final stage (after 120 days) as a minor mineral in an assemblage dominated by Fe-kaolinite. The pedogenic smectite used as starting material consisted of two end-members, Fe-beidellite and Al-smectite, enabling comparison of reaction pathways. Fe-beidellite transforms to K-S or Fe-kaolinite within 3 days, whereas Al-smectite transforms much more slowly, appearing to reach a maximum rate in intermediate stages. This difference is probably due to hydrolysis of relatively weak Mg-O and Fe-O bonds (relative to Al-O bonds) in Fe-beidellite octahedral sheets, which drives rapid reaction, whereas the driving force behind transformation of Al-smectite is more likely to be related to stripping of tetrahedral sheets which reaches its maximum rate at intermediate stages. Multiple analytical approaches have indicated that Al is rapidly fixed from solution into smectite interlayers within K-S, and that K-S and Fe-kaolinite inherit octahedral Fe and Mg from precursor smectite; as the reaction progresses, octahedral sheets become progressively more Al-rich and Fe and Mg are lost to solution. These results demonstrate that: (1) early-formed pedogenic smectite in tropical soils is expected to transform to kaolinite via interstratified K-S; (2) K-S has a strong potential to sequester plant-toxic Al in tropical soil; and (3) the presence in tropical soils of Fe-kaolinites with relatively large cation exchange capacities may be related to inheritance of octahedral sheets from precursor smectite and K-S.

Keywords

BeidelliteFe-kaoliniteInterstratifiedKaolinite-smectiteMixed-layerPedogenicSmectiteSoilSynthesisTransformationTropical
Type
Article
Information
Clays and Clay Minerals , Volume 61 , Issue 4 , August 2013 , pp. 303 - 318
Copyright
Copyright © The Clay Minerals Society 2013

References

Altschuler, Z.S. Dwornik, E.J. and Kramer, H., 1963 Transformation of montmorillonite to kaolinite during weathering Science 141 148–152.CrossRefGoogle ScholarPubMed
Amouric, M. and Olives, J., 1998 Transformation mechanisms and interstratification in conversion of smectite to kaolinite; an HRTEM study Clays and Clay Minerals 46 521–527.CrossRefGoogle Scholar
Anda, M. Shamshuddin, J. Fauziah, C.I. and Syed Omar, S.R., 2008 Mineralogy and factors controlling charge development of three Oxisols developed from different parent materials Geoderma 143 153–167.CrossRefGoogle Scholar
Aspiandar, M.F. and Eggleton, R.E., 2002 Weathering of chlorite: I. Reactions and products in microsystems controlled by the primary mineral Clays and Clay Minerals 50 685–698.CrossRefGoogle Scholar
Barnhisel, R.I. Bertsch, P.M., Dixon, J.B. and Weed, S.B., 1989 Chlorites and hydroxy-interlayered vermiculite and smectite Minerals in Soil Environments 2nd Madison, Wisconsin, USA Soil Science Society of America 729–788.Google Scholar
Bravard, S. and Righi, D., 1988 Characteristics of clays in an Oxisol-Spodosol toposequence in Amazonia (Brazil) Clay Minerals 23 279–289.CrossRefGoogle Scholar
Chadwick, O.A. Derry, L.A. Vitousek, P.M. Huebert, B.J. and Hedin, L.O., 1999 Changing sources of nutrients during four million years of ecosystem development Nature 397 491–497.CrossRefGoogle Scholar
Churchman, G.J. Slade, P.G. Self, P.G. and Janik, L.J., 1994 Nature of interstratified kaolin-smectites in some Australian soils Australian Journal of Soil Research 32 805–822.CrossRefGoogle Scholar
Cliff, G. and Lorimer, G.W., 1975 The quantitative analysis of thin specimens Journal of Microscopy 103 203–207.CrossRefGoogle Scholar
Cornu, S. Ambrosi, J.P. Lucas, Y. and Fevrier, D., 1997 A comparative study of the soil solution chemistry of two Amazonian forest soils (Central Amazonia, Brazil) Hydrology and Earth System Sciences 1 313–324.CrossRefGoogle Scholar
Cradwick, P.D. and Wilson, M.J., 1972 Calculated X-ray diffraction profiles for interstratified kaolinite-montmorillonite Clay Minerals 9 395–405.CrossRefGoogle Scholar
Cuadros, J. Delgado, A. Cardenete, A. Reyes, E. and Linares, J., 1994 Kaolinite/montmorillonite resembles smectite Clays and Clay Minerals 42 643–651.CrossRefGoogle Scholar
Cuadros, J. Nieto, F. and Wing-Dudek, T., 2009 Crystalchemical changes of kaolinite-smectite mixed-layer with progressive kaolinization, as investigated by TEM-AEM and HRTEM Clays and Clay Minerals 57 742–750.CrossRefGoogle Scholar
Delvaux, B. Mestdagh, M.M. Vielvoye, L. and Herbillon, A.J., 1989 XRD, IR and ESR study of experimental alteration of Al-nontronite into mixed-layer kaolinitesmectite Clay Minerals 24 617–630.CrossRefGoogle Scholar
Delvaux, B. Herbillon, A.J. Vielvoye, L. and Mestdagh, M.M., 1990 Surface properties of clay mineralogy of hydrated halloysitic soil clays. II: Evidence for the presence of halloysite/smectite (H/Sm) mixed-layer clays Clay Minerals 25 141–160.CrossRefGoogle Scholar
Drits, V.A. Besson, G. and Muller, F., 1995 An improved model for structural transformations of heat-treated aluminous dioctahedral 2:1 layer silicates Clays and Clay Minerals 43 718–731.CrossRefGoogle Scholar
Dudek, T. Cuadros, J. and Fiore, S., 2006 Interstratified kaolinite-smectite: nature of the layers and mechanism of smectite kaolinization American Mineralogist 91 159–170.CrossRefGoogle Scholar
Dudek, T. Cuadros, J. and Huertas, F.J., 2007 Structure of mixed-layer kaolinite-smectite and smectite-to-kaolinite transformation mechanism from synthesis experiments American Mineralogist 92 179–192.CrossRefGoogle Scholar
Eswaran, H. and de Coninck, F., 1971 Clay mineral formations and transformations in basaltic soils in tropical environments Pedologie 21 181–210.Google Scholar
Etame, J. Gerard, M. Suh, C.E. and Bilong, P., 2009 Halloysite neoformation during the weathering of nephelinitic rocks under humid tropical conditions at Mt Etinde, Cameroon Geoderma 154 59–68.CrossRefGoogle Scholar
Fiore, S. Huertas, F.J. Huertas, F. and Linares, J., 2001 Mechanism of smectite formation in volcanic glass as inferred by microscopic (SEM-TEM-AEM) investigation Clay Minerals 36 489–500.CrossRefGoogle Scholar
Fisher, G.B. and Ryan, P.C., 2006 The smectite to disordered kaolinite transition in a tropical soil chronosequence, Pacific Coast, Costa Rica Clays and Clay Minerals 54 571–586.CrossRefGoogle Scholar
Hart, R.D. Gilkes, R.J. Siradz, S. and Singh, B., 2002 The nature of soil kaolins from Indonesia and western Australia Clays and Clay Minerals 50 198–207.CrossRefGoogle Scholar
Herbillon, A.J. Mestdagh, M.M. Vielvoye, L. and Derouane, E.G., 1976 Iron in kaolinite with special reference to kaolinite from tropical soils Clay Minerals 11 201–220.CrossRefGoogle Scholar
Hillier, S. and Ryan, P.C., 2002 Identification of halloysite (7Å) by ethylene glycol solvation: the ‘MacEwan effect’ Clay Minerals 37 487–496.CrossRefGoogle Scholar
Hong, H. Churchman, G.J. Gu, Y. Yin, K. and Wang, C., 2012 Kaolinite-smectite mixed-layer clays in the Jiujiang red soils and their climate significance Geoderma 75–83.CrossRefGoogle Scholar
Hughes, R.E. Moore, D.M. Reynolds, R.C. Jr., Murray, H.H. Bundy, W.M. and Harvey, C.C., 1993 The nature, detection and occurrence, and origin of kaolinite/smectite Kaolin Genesis and Utilization Boulder, Colorado The Clay Minerals Society 291–323.Google Scholar
Kanket, W. Suddhiprakarn, A. Kheoruenromne, I. and Gilkes, R.J., 2005 Chemical and crystallographic properties of kaolin from Ultisols in Thailand Clays and Clay Minerals 53 478–489.CrossRefGoogle Scholar
Kantor, W. and Schwertmann, U., 1974 Mineralogy and genesis of clays in red-black toposequences in Kenya Journal of Soil Science 25 67–78.CrossRefGoogle Scholar
Korning, J. Thomsen, K. Dalsgaard, K. and Nørnberg, P., 1994 Characters of three udults and their relevance to the composition and structure of virgin rain forest of Amazonian Ecuador Geoderma 63 145–164.CrossRefGoogle Scholar
Mackenzie, R.C., 1970.Simple phyllosilicates based on gibbsite- and brucite-like sheets. Pp. 498–537 in Differential Thermal AnalysisGoogle Scholar
Mestdagh, M.M. Vielvoye, L. and Herbillon, A.J., 1980 Iron in kaolinite: II. The relationship between kaolinite crystallinity and iron content Clay Minerals 15 1–13.CrossRefGoogle Scholar
Moore, D.M. Reynolds, R.C. Jr, Moore, D.M. and Reynolds, R.C., 1997 Identification of mixed-layer minerals X-ray Diffraction and the Identification and Analysis of Clay Minerals New York Oxford University Press 261–297.Google Scholar
Muggler, C.C. Buurman, P. and van Doesburg, J.D.J., 2007 Weathering trends and parent material characteristics of polygenetic oxisols from Minas Gerais, Brazil: I. Mineralogy Geoderma 138 39–48.CrossRefGoogle Scholar
NAP National Academy Press, 1982 Ecological Aspects of Development in the Humid Tropics Washington D.C National Academy Press.Google Scholar
Ndayiragije, S. and Delvaux, B., 2003 Coexistence of allophone, gibbsite, kaolinite and hydroxy-Al-interlayered 2:1 clay minerals in a perudic Andosol Geoderma 117 203–214.CrossRefGoogle Scholar
Petschick, R., 2000.MacDiffGoogle Scholar
Quantin, P. Balesdent, J. Bouleau, A. Delaune, M. and Feller, C., 1991 Premiers stades d’altèration de ponces volcaniques en climat tropical humide (Montagne Pelèe, Martinique) Geoderma 50 125–148.CrossRefGoogle Scholar
Righi, D. Terribile, F. and Petit, S., 1999 Pedogenic formation of kaolinite-smectite mixed layers in a soil toposequence developed from basaltic parent material in Sardinia (Italy) Clays and Clay Minerals 47 505–514.CrossRefGoogle Scholar
Rozalén, M.L. Huertas, F.J. and Brady, P.V., 2009 Experimental study of the effect of pH and temperature on the kinetics of montmorillonite dissolution Geochimica et Cosmochimica Acta 73 3752–3766.CrossRefGoogle Scholar
Russell, J.D. and Fraser, A.R., 1994.Infrared methods. Pp. 11 —67 in Clay Mineralogy: Spectroscopic and Chemical Determinative MethodsCrossRefGoogle Scholar
Ryan, P.C. and Huertas, F.J., 2009 The temporal evolution of pedogenic Fe-smectite to Fe-kaolin via interstratified kaolin-smectite in a moist tropical soil chronosequence Geoderma 151 1–15.CrossRefGoogle Scholar
Srodon, J., 1980 Synthesis of mixed-layer kaolinite/smectite Clays and Clay Minerals 26 419–424.CrossRefGoogle Scholar
Srodon, J., 1999 Nature of mixed-layer clays and mechanisms of their formation and alteration Annual Review of Earth and Planetary Sciences 27 19–53.CrossRefGoogle Scholar
Thanachit, S. Suddhiprakarn, A. Kheoruenromne, I. and Gilkes, R.J., 2006 The geochemistry of soils on a catena on basalt at Khon Buri, northeast Thailand Geoderma 135 81–96.CrossRefGoogle Scholar
Vitousek, P.M. and Sanford, R.L. Jr., 1986 Nutrient cycling in moist tropical forest Annual Review of Ecological Systematics 17 137–167.CrossRefGoogle Scholar
Wada, K. Kakuto, Y. and Ikawa, H., 1990 Clay minerals of two Eutrandepts of Hawaii, having isohyperthermie temperature and ustic moisture regimes Soil Science Society of America Journal 54 1173–1178.CrossRefGoogle Scholar
Wilson, M.J., Schultz, L.G. van Olphen, H. and Mumpton, F., 1987 Soil smectites and related interstratified minerals: recent developments Proceedings of the International Clay Conference, Denver Colorado, USA The Clay Minerals Society 167–173.Google Scholar