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A Polarized Infrared and X-Ray Study of Lysine-Vermiculite

Published online by Cambridge University Press:  01 July 2024

M. Raupach
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
P. G. Slade
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
L. Janik
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
E. W. Radoslovich*
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
*
*Division of Soils, C.S.I.R.O., Adelaide, Australia

Abstract

Lysine and vermiculite form a stable, ordered, interlamellar complex which has a well defined superlattice structure with respect to the ab-plane of vermiculite. The lysine molecules lie at a low angle to the silicate surfaces and establish a double layer network between such surfaces. I.R. and chemical data for the complex are given. The possible role of hydrogen bonds in linking the system together is considered.

Type
Research Article
Copyright
Copyright © 1975, The Clay Minerals Society

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