Hostname: page-component-848d4c4894-xfwgj Total loading time: 0 Render date: 2024-07-04T18:21:46.175Z Has data issue: false hasContentIssue false
  • English
  • Français

Note on the Intercalation of Kaolinite, Dickite and Halloysite by Dimethyl-Sulfoxide

Published online by Cambridge University Press:  01 July 2024

Octavian Anton  and
Paul G. Rouxhet
Octavian Anton
Affiliation:
Groupe de Physico-Chimie Minérale et de Catalyse, Université Catholique de Louvain, Place Croix du Sud 1, 1348, Louvain-la-Neuve, Belgium
Paul G. Rouxhet
Affiliation:
Groupe de Physico-Chimie Minérale et de Catalyse, Université Catholique de Louvain, Place Croix du Sud 1, 1348, Louvain-la-Neuve, Belgium
Get access Rights & Permissions [Opens in a new window]

Abstract

Various kaolinites, a dickite and halloysites have been treated by DMSO in presence of D2O and subsequently washed by D2O. This procedure allowed to record OD stretching bands which are due specifically to the intercalated fraction and, for the washed samples, to the fraction of the solid which has been intercalated and has subsequently collapsed.

No structural difference is found between the intercalated materials prepared from the various minerals. Washing usually restores the starting mineral; however, for a non-tubular halloysite, DMSO intercalation and subsequent washing gave a product similar to kaolinite.

Type
Research Article
Information
Clays and Clay Minerals , Volume 25 , Issue 4 , August 1977 , pp. 259 - 263
Copyright
Copyright © Clay Minerals Society 1977

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Alietti, A. (1970) Notes on the expandability of kaolinitic minerals: Miner. Petrogr. Acta 16, 213–220.Google Scholar
Farmer, V. C. (1974) The Infrared Spectra of Minerals (Edited by Farmer, V. C.) , Chapter 15. Mineralogical Society, London.CrossRefGoogle Scholar
Farmer, V. C. and Russell, J. D. (1964) The infrared spectra of layer silicates: Spectrochim. Acta 20, 1149–1173.CrossRefGoogle Scholar
Garcia, Gonzalez and Sanchez Camazano, M. (1965) Complejos de adsorcion de los minerales de la arcilla con dimetilsulfoxido: An. Edaf. Agrobiol. 24, 495–520.Google Scholar
Herbillon, A. J., Mestdagh, M. M., Vielvoye, L. and Derouane, E. G. (1976) Iron in kaolinite with special reference to kaolinite from tropical soils: Clay Minerals 11, 201–220.CrossRefGoogle Scholar
Jacobs, H. and Sterckx, M. (1970) Contribution à l'étude de l'intercalation du diméthylsulfoxyde dans le réseau de la kaolinite: Reunion Hispano-Belga de Minerales de la Arcilla (Edited by Serratosa, J. M.) pp. 154–160. Consejo Sup. Invest. Cient., Madrid.Google Scholar
Jones, J. P. E., Angell, B. R. and Hall, P. L. (1974) Electron spin resonance studies of doped synthetic kaolinite II: Clay Minerals 10, 257–270.CrossRefGoogle Scholar
Olejnik, S., Aylmore, L. A. G., Posner, A. M. and Quirk, J. P. (1968) Infrared spectra of kaolin mineral dimethylsulfoxide complexes: J. Phys. Chem. 72, 241–249.CrossRefGoogle Scholar
Olejnik, S., Posner, A. M. and Quirk, J. P. (1970) The intercalation of polar organic compounds into kaolinite: Clay Minerals 8, 421–434.CrossRefGoogle Scholar
Range, K. J., Range, A. and Weiss, A. (1969) Fire-clay type kaolinite or fire clay minerals? Experimental classification of kaolinite–halloysite minerals: Proc. Int. Clay Conf. Tokyo, pp. 3–13. Israel Univ. Press.Google Scholar
Rouxhet, P. G. (1969) The Beer–Lambert law in the infrared: derivation from wave mechanics and application to solids: Optica Pura Applic. 2, 75–81.Google Scholar
Rouxhet, P. G., Ngo, Samudacheata, Jacobs, H. and Anton, O. (1977) Attribution of the OH stretching bands of kaolinite: Clay Minerals 12, 171–179.CrossRefGoogle Scholar
Rowland, R. A. (1973) Anomalous infrared absorption in a hydrated halloysite: 22nd Clay Minerals Conf., Banff, Canada, Program and Abstracts.Google Scholar
Sanchez Camazano, M. and Gonzalez Garcia, S. (1966) Complejos interlaminares de caolinita y haloisita con liquidos polares: An. Edaf. Agrobiologia 25, 9–25.Google Scholar
Yariv, S. (1975) Infrared study of the interaction between cesium chloride and kaolinite: J. Chem. Soc. Faraday Trans. I 71, 674–684.CrossRefGoogle Scholar