Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-26T16:41:29.720Z Has data issue: false hasContentIssue false
  • English
  • Français

Mössbauer Spectra of Dioctahedral Smectites

Published online by Cambridge University Press:  01 July 2024

I. Rozenson  and
L. Heller-Kallai
I. Rozenson
Affiliation:
Department of Geology, Hebrew University, Jerusalem, Israel
L. Heller-Kallai
Affiliation:
Department of Geology, Hebrew University, Jerusalem, Israel
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Mössbauer spectra of 15 smectites were investigated. In these samples, ferric iron occupies both M(1) and M(2) octahedral sites, the distribution being partly determined by the relative covalency of the bonds formed.

The quadrupole splittings are linearly related to b−3. They show that Fe3+ octahedra are much more distorted in montmorillonite and beidellite than in nontronite and volkonskoite and that M(1) sites are more prone to change than M(2). Ferrous iron occurs in relatively undistorted octahedra in some otherwise distorted octahedral sheets and vice versa.

Type
Research Article
Information
Clays and Clay Minerals , Volume 25 , Issue 2 , April 1977 , pp. 94 - 101
Copyright
Copyright © Clay Minerals Society 1977

References

Bailey, S. W. (1975) Cation ordering and pseudosymmetry in layer silicates: Am. Miner. 60, 175–187.Google Scholar
Bancroft, G. M. (1974) Mössbauer Spectroscopy—An Introduction for Inorganic Chemists and Geochemists: McGraw-Hill, New York.Google Scholar
Besnus, Y., Fusil, G., Janet, C., Pinta, M. and Sieffermann, G. (1975) Characteristics of some ultrabasic rocks in Bahia State, Brazil: nontronites, chlorites and chromiferous talc: Proc. Int. Clay Conf. Mexico City, Mexico, 27–34.Google Scholar
Brunot, B. (1973) Application of the Mössbauer effect to the study of clay minerals. Hydrothermal nontronite and nontronite from Lake Malawi: Neues Jahrb. Mineral. Monatsh. 452–461.Google Scholar
Bystrom-Brusewitz, A. M. (1975) Studies of the Li test to distinguish between beidellite and montmorillonite: Proc. Int. Clay Conf. Mexico City, Mexico, 419–428.Google Scholar
Coey, J. M. D. (1975) Iron in a post-glacial lake sediment core: a Mössbauer effect study: Geochim. Cosmochim. Acta 39, 401–415.CrossRefGoogle Scholar
Cousins, D. R. and Dharmawordena, K. G. (1969) Use of Mössbauer spectroscopy in the study of ancient pottery: Nature 223, 732–733.CrossRefGoogle Scholar
Ernst, W. G. and Wai, C. M. (1970) Mössbauer, infrared, X-ray and optical study of cation ordering and dehydrogenation in natural and heat-treated sodic amphiboles: Am. Miner. 55, 1226–1258.Google Scholar
Frenkel, M. (1975) The minerological and chemical properties of the bentonite from Makhtesh Ramon: Ph.D. thesis, The Hebrew University, Jerusalem.Google Scholar
Goodman, B. A., Russell, J. D., Fraser, A. R. and Woodhams, F. W. D. (1976) A Mössbauer and i.r. spectroscopic study of the structure of nontronite: Clays & Clay Minerals 24, 53–59.CrossRefGoogle Scholar
Güven, N. and Burnham, C. W. (1967) The crystal structure of 3T muscovite: Z. Kristallogr. 18, 502–510.Google Scholar
Güven, N. and Pease, R. V. (1975) Selected area electron diffraction studies on beidellite: Clay Minerals 10, 427–435.Google Scholar
Hogg, C. S. and Meads, R. E. (1970) The Mössbauer spectra of several micas and related minerals: Miner. Mag. 37, 606–614.CrossRefGoogle Scholar
Kohyama, N. and Hayashi, H. (1972) Oxygen consumption of clay minerals in the Quarry at Oya. Utsunomiya City, Tochigi Prefecture, Japan: Ind. Health 10, 24–51.CrossRefGoogle Scholar
Malathi, M. and Puri, S. P. (1969) Mössbauer studies of iron in illite and montmorillonite: J. Phys. Soc. Japan 26, 680–683.CrossRefGoogle Scholar
Mering, J. and Oberlin, A. (1971) The Electron Optical Investigation of Clays (Edited by Gard, J. A.) , pp. 193–230: Mineralogical Society, London.CrossRefGoogle Scholar
Mitchell, B. D. and Mackenzie, R. C. (1954) Removal of free iron oxide from clays: Soil Sci. 77, 173–183.CrossRefGoogle Scholar
O'Nions, R. K. and Smith, D. G. W. (1973) Bonding in silicates: an assessment of bonding in orthopyroxene: Geochim. Cosmochim. Acta 37, 249–257.CrossRefGoogle Scholar
Radoslovich, E. W. and Norrish, K. (1962) The cell dimensions and symmetry of layer lattice silicates. Some structural considerations: Am. Miner. 47, 599–616.Google Scholar
Rozenson, I. and Heller-Kallai, L. (1976) Reduction and oxidation of Fe3+ in dioctahedral smectites. Part I: reduction with hydrazine and dithionite: Clays & Clay Minerals 24, 271–282.CrossRefGoogle Scholar
Taylor, G. L., Ruotsala, A. P. and Keeling, R. O. Jr. (1968) Analysis of iron in layer silicates by Mössbauer spectroscopy: Clays & Clay Minerals 16, 381–391.CrossRefGoogle Scholar
Tennakoon, D. T. B., Thomas, J. M. and Tricker, M. J. (1974) The surface and intercalate chemistry of layered silicates—II: A 57Fe Mössbauer study of the role of lattice-substituted iron in benzidine-blue reaction of montmorillonite: J. Chem. Soc. Dalton, 2211–2215.CrossRefGoogle Scholar
Wardle, R. and Brindley, G. W. (1972) The crystal structure of pyrophyllite, 1Tc, and of its dehydroxylate: Am. Miner. 57, 732–750.Google Scholar
Weaver, C. E., Wampler, J. M. and Pecuil, T. E. (1967) Mössbauer analysis of iron in clay minerals: Science 156, 504–508.CrossRefGoogle ScholarPubMed