Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-22T15:25:47.646Z Has data issue: false hasContentIssue false

Lead-210 Derived Sedimentation Rates from a North Louisiana Paper-Mill Effluent Reservoir

Published online by Cambridge University Press:  28 February 2024

William N. Pizzolato
Affiliation:
U.S. Army Corps of Engineers, Waterways Experiment Station Geotechnical Laboratory, CEWES-GG-YH, 3909 Halls Ferry Road, Vicksburg, Mississippi 39180
René A. De Hon
Affiliation:
Department of Geosciences, Northeast Louisiana University, Monroe, Louisiana 71209
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Lower Wham Brake is a cypress, rim-swamp artificially enclosed in 1950 as a 22 km2 industrial reservoir by the International Paper Company (IPC)-Bastrop Mill, for regulating downstream water quality. Sediment cores were examined by XRD to differentiate paper-mill effluent deposition from the underlying detrital sediments and by 210Pb decay spectroscopy to determine sediment accretion rates.

Anatase and kaolin from the IPC paper-mill effluent delineated a well-defined, anthropic, silty-clay, A horizon above a clay, 2Ag horizon. Anatase concentrations were no greater than 1.7% in the A horizon and was absent in the underlying 2Agl horizon. Kaolin deposition was significantly correlated to the A horizon by an average increase of 84% above the kaolinite detrital background. Pyrite was detected in the A horizon as a transformation mineral following sulfur reduction of the paper-mill effluent.

Five of the six sediment cores showed an inflection in the excess 210Pb activity profile consistent with a present-day reduction in sediment supply. The average modern sedimentation rate was 0.05 cm yr−1. Average sedimentation observed during historic accretion was 0.22 cm yr−1, about 4.4 times greater than the modern rate of accretion. Reduction in sediment accretion can be attributed to upstream levees completed in 1934 and loss of organic accumulation following the 1950 reservoir impoundment. However, radiometric dating could not precisely correlate the geochronology of kaolin/anatase introduction due to complex oxidation/reduction cycles concurrent with the modern accretion regime.

Type
Research Article
Copyright
Copyright © 1995, The Clay Minerals Society

References

Benoit, G., 1988. The biogeochemistry of 210Pb and 210Po in fresh waters and sediments: Ph.D. dissertation. Massachusetts Institute of Technology at Cambridge, 304 pp.Google Scholar
Benoit, G., and Hemond, H. F. 1990. 210Pb and 210Po re-mobilization from lake sediments in relation to iron and manganese cycling. Environ. Sci. Technol. 24: 12241234.Google Scholar
Benoit, G., and Hemond, H. F. 1991. Evidence for diffusive redistribution of 210Pb in lake sediments. Geochim. Cosmochim. Acta 55: 19631975.Google Scholar
Berner, R. A., 1970. Sedimentary pyrite formation. Am. J. Sci. 268: 123.CrossRefGoogle Scholar
Connell, W. E., and Patrick, W.H. Jr. 1968. Sulfate reduction in soil: Effects of redox potential and pH. Science 159: 8687.Google Scholar
Flynn, W. W., 1968. The determination of low levels of polonium-210 in environmental materials. Anal. Chim. Acta 43: 221227.Google Scholar
Folk, R. L., 1974. Petrology of Sedimentary Rocks. Austin, Texas: Hemphill Publishing Company, 184 pp.Google Scholar
Gambrell, R. P., Khalid, R. A., and Patrick, W. H. Jr. 1976. Physiochemical parameters that regulate mobilization and immobilization of toxic heavy metals. In Proceedings of the Specialty Conference on Dredging and its Environmental Effects. American Society of Civil Engineers, New York, 418-434 pp.Google Scholar
Gotoh, S., and Patrick, W. H. Jr. 1974. Transformation of iron in a waterlogged soil as influenced by redox potential and pH. Soil Sci. Soc. Amer. Proc. 38: 6671.Google Scholar
Goldberg, E. D., 1963. Geochronology with 210Pb in Radioactive Dating. Vienna: International Atomic Energy Agency, 121131.Google Scholar
Jackson, M. L., 1969. Soil Chemical Analysis-Advanced Course. M. L. Jackson ed. Madison, Wisconsin: 895 pp.Google Scholar
Koide, M., Bruland, K. W., and Goldberg, E. D. 1973. Th-228/Th-232 and Pb-210 geochronologies in marine and lake sediments Geochim. Cosmochim. Acta 37: 11711187.Google Scholar
Kearney, M. S., Ward, L. G., Cofta, C. M., Helz, G. R., and Church, T. M. 1985. Sedimentology, geochronology and trace metals in the Nanticoke and Choptank Rivers, Chesapeake Bay. In Tech. Rep. No. 84. College Park: University of Maryland, 94 pp.Google Scholar
Krishnaswamy, S., Lal, D., Martin, J. M., and Meybeck, M. 1971. Geochronology of lake sediments. Earth Planet. Sci. Lett. 11: 407414.Google Scholar
National Technical Committee for Hydric Soils 1991. Hydric Soils of the United States, 3rd ed. Washington, D.C.: USDA-Soil Conservation Service.Google Scholar
Nittrouer, C. A., Sternberg, R. W., Carpenter, R., and Bennet, J. T. 1979. The use of Pb-210 geochronology as a sedimentological tool: application to the Washington continental shelf. Mar. Geol. 31: 297316.Google Scholar
Nittrouer, C. A., DeMaster, D. J., McKee, B. A., Cutshall, N. H., and Larson, I. L. 1984. The effect of sediment mixing on Pb-210 accumulation rates for the Washington continental shelf. Mar. Geol. 54: 210221.Google Scholar
Oldfield, F., and Appleby, P. G. 1984. Empirical testing of 210Pb-dating models for lake sediments. In Lake Sediments and Environmental History. Hayworth, E. Y., and Lund, J. W. G., eds. University of Minnesota Minneapolis: Press, 93124.Google Scholar
Orson, R. A., Simpson, R. L., and Good, R. E. 1990. Rates of sediment accumulation in a tidal freshwater marsh. J. of Sedimentary Petrology 60 (6): 859869.Google Scholar
Pizzolato, W. N., 1994. X-ray diffraction study of sediments from a paper-mill effluent reservoir, Ouachita and Morehouse Parishes, Louisiana. The Compass, 70: 4.Google Scholar
Reynolds, E. F., Allen, E. T., May, T. L., and Weems, T. A. 1985. Soil Survey of Morehouse Parish Louisiana: Washington D.C.: USDA-Soil Conservation Service, 175 pp.Google Scholar
Richardson, J., Straub, P. A., Ewel, K. C., and Odum, H. T. 1983. Sulfate-enriched water effects on a floodplain forest in Florida. Envir. Management 74: 321326.Google Scholar
Robbins, J. A., 1978. Geochemical and geophysical applications of radioactive lead. In The Biogeochemistry of Lead in the Environment. Nriagu, J., ed. Amsterdam: Elsevier, 284393.Google Scholar
Robbins, J. A., and Edgington, D. N. 1975. Determination of recent sedimentation rates in Lake Michigan using Pb-210 and Cs-137. Geochim. Cosmochim. Acta 39: 285304.Google Scholar
Satawathananont, S., Patrick, W. H. Jr., and Moore, P. A. Jr. 1991. Effect of controlled redox conditions on metal solubility in acid sulfate soils. Plant and Soil 133: 281290.Google Scholar
Saucier, R., 1967. Geological investigation of the Boeuf-Tensas Basin, Lower Mississippi Valley. Technical Report 3-757. Vicksburg: U.S. Army Corps of Engineer WES, 57 pp.Google Scholar
Schultz, L. G., 1964. Quantitative interpretation of miner-alogical composition from x-ray and chemical data for the Pierre Shale: Professional Paper 391-C, U.S. Geological Survey, Washington D. C., 31 pp.Google Scholar
Shukla, B. S., and Joshi, S. R. 1989. An evaluation of the CIC model of 210Pb dating of sediments. Environ. Geol. Water Sci. 14(1): 7376.Google Scholar
Soil Survey Staff 1992. Keys to Soil Taxonomy: 5th ed., SMSS Technical Monograph No. 19, Pocahontas Press, Blacksburg, Virginia, 541 pp.Google Scholar
Spoljaric, N., 1971. Quick preparation of slides of well-oriented clay minerals for x-ray diffraction analysis. J. Sed. Petrol. 41: 589590.Google Scholar
Spoljaric, N., 1972. Reply to Comment on ‘Quick preparation of slides of well-oriented clay minerals for x-ray diffraction analysis’. J. Sed. Petrol. 42: 249250.Google Scholar
Vepraskas, M. J., 1992. Redoximorphic features for identifying aquic conditions. In Tech. Bull. 301. North Carolina State University at Raleigh, 33 pp.Google Scholar
Whitcomb, J. H., DeLaune, R. D., and Patrick, W. H. Jr. 1989. Chemical oxidation of sulfide to elemental sulfur: Its possible role in marsh energy flow. Mar. Geol. 26: 205214.Google Scholar
Wise, S. M., 1980. Caesium-137 and Lead-210: a review of the techniques and some applications in geomorphology. In Timescales in Geomorphology. Cullingford, R. A., Davidson, D. A., and Lewin, J., eds. New York: John Wiley & Sons, 110127.Google Scholar