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Laser Shadow Analysis of Particle-Size Distribution of Montmorillonites in Aqueous Suspensions

Published online by Cambridge University Press:  01 January 2024

S. Yariv  and
I. Lapides
S. Yariv
Affiliation:
Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel
I. Lapides*
Affiliation:
Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel
*
*E-mail address of corresponding author: [email protected]
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Abstract

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Particle-size analysis (obtained by Galai CIS 1) was used to determine the following statistical parameters of aqueous suspensions of Na-, Ca- and Mn-montmorillonite: the size distributions, the diameters of the largest and of the median and mean particles, and the percentage of particles with diameters <1.5 µm. Dilution or shaking had almost no effect on the particle-size distribution curves and statistical parameters of Ca- and Mn-montmorillonites but the curves and the statistical parameters of Na-montmorillonite were very much affected by these treatments. The median and mean diameters of Na-montmorillonite range from 0.8 to 10.5 µm and 0.8 to 11.6 µm, respectively, the median and mean diameters of Ca-montmorillonite range from 1.5 to 3.6 µm and 2.12 to 4.2 µm, respectively, and those for Mn-montmorillonite from 1.2 to 2.3 µm and 1.5 to 2.5 µm, respectively. The presence of large particles of Na-montmorillonite was attributed to the extensive swelling of this clay in aqueous suspensions by osmotic water adsorption. The median and mean diameters of aged Na-montmorillonite suspensions indicate that swelling increases with dilution. The swelling of Ca- and Mn-montmorillonite, on the other hand, is limited and their particle size does not increase with dilution.

Keywords

HydrationLaser-based Size AnalysisMontmorilloniteParticle-size DistributionSwelling
Type
Research Article
Information
Clays and Clay Minerals , Volume 51 , Issue 1 , February 2003 , pp. 23 - 32
Copyright
Copyright © 2003, The Clay Minerals Society

References

Banin, A. and Lahav, N., (1968) Particle size and optical properties of montmorillonite in suspension Israel Journal of Chemistry 6 235–250 10.1002/ijch.196800034.Google Scholar
Bérend, I. Cases, J.M. Besson, G. François, M. Uriot, J.P. Michot, L.J. Maison, A. and Thomas, F., (1996) Mechanism of adsorption and desorption of water vapor by homoionic montmorillonite. 2. The Li+, Na+, K+, Rb+ and Cs+ exchanged form Clays and Clay Minerals 43 324–336 10.1346/CCMN.1995.0430307.Google Scholar
Cancela, G.D. Huertas, F.J. Taboada, E.R. Sanchez Rasero, F. and Laguna, A.H., (1997) Adsorption of water vapor by homoionic montmorillonites. Heats of adsorption and desorption Journal of Colloid and Interface Science 185 469 474.Google Scholar
Cases, J.M. Bérend, I. Besson, G. François, M. Uriot, J.P. Thomas, F. and Poirier, J.E., (1992) Mechanism of adsorption and desorption of water vapor by homoionic montmorillonite. 1. The sodium exchanged form Langmuir 8 2730–2739 10.1021/la00047a025.Google Scholar
Cases, J.M. Bérend, I. François, M. Uriot, J.P. Michot, L.J. and Thomas, F., (1997) Mechanism of adsorption and desorption of water vapor by homoionic montmorillonite. 3. The Mg2+, Ca2+, Sr2+ and Ba2+ exchanged form Clays and Clay Minerals 45 8–22 10.1346/CCMN.1997.0450102.Google Scholar
Chang, F.R.C. Skipper, N.T. and Sposito, G., (1997) Monte Carlo and molecular dynamics simulations of interfacial structure in lithium-montmorillonite hydrates Langmuir 13 2074–2082 10.1021/la9603176.Google Scholar
Chiou, C.T. and Rutherford, D.W., (1997) Effects of exchanged cation and layer charge on the sorption of water and EGME vapors on montmorillonite hydrates Clays and Clay Minerals 45 867–880 10.1346/CCMN.1997.0450611.Google Scholar
Eckstein, Y. Yaalon, D.H. and Yariv, S., (1970) The effect of lithium on the cation exchange behavior of crystalline and amorphous clays Israel Journal of Chemistry 8 335–342 10.1002/ijch.197000040.Google Scholar
Lahav, N. and Banin, A., (1968) Effect of various treatments on the optical properties of montmorillonite suspensions Israel Journal of Chemistry 6 285–294 10.1002/ijch.196800038.Google Scholar
Low, P.F., Schutz, L.G. van Olphen, H. and Mumpton, F.A., (1987) The clay-water interface Proceedings of the International Clay Conference, Denver, 1985 Bloomington, Indiana The Clay Minerals Society 247 256.Google Scholar
Lurie, D. and Yariv, S., (1968) Hetrometric titration of sodium montmorillonite with calcium nitrate Israel Journal of Chemistry 6 203–211 10.1002/ijch.196800032.Google Scholar
Norrish, K., (1954) The swelling of montmorillonite Discussions of the Faraday Society 18 120–134 10.1039/df9541800120.Google Scholar
Quirk, J.P., (1968) Particle interaction and soil swelling Israel Journal of Chemistry 6 213–234 10.1002/ijch.196800033.Google Scholar
Schramm, L.I. and Kwak, J.C.T., (1982) Influence of exchangeable cation composition on the size and shape of montmorillonite particles in dilute suspension Clays and Clay Minerals 30 40–48 10.1346/CCMN.1982.0300105.Google Scholar
Shainberg, I. and Otoh, H., (1968) Size and shape of montmorillonite particles saturated with Na/Ca ions, inferred from viscosity and optical methods Israel Journal of Chemistry 6 251–259 10.1002/ijch.196800035.Google Scholar
Skipper, N.T. Chang, F.R.C. and Sposito, G., (1995) Monte Carlo simulation of interlayer molecular structure in swelling clay minerals. 1. Methodology Clays and Clay Minerals 43 285–293 10.1346/CCMN.1995.0430303.Google Scholar
Skipper, N.T. Sposito, G. and Chang, F.R.C., (1995) Monte Carlo simulation of interlayer molecular structure in swelling clay minerals. 1. Monolayer hydrates Clays and Clay Minerals 43 294–303 10.1346/CCMN.1995.0430304.Google Scholar
Sposito, G. and Prost, R., (1982) Structure of water adsorbed on smectites Chemistry Review 82 553–573 10.1021/cr00052a001.Google Scholar
Xu, W. Johnston, C.T. Parker, P. and Angew, S.F., (2000) Infrared study of water sorption on Na-, Li, Ca-, and Mg- exchanged (SWy-1 and SAz-1) montmorillonite Clays and Clay Minerals 48 120–131 10.1346/CCMN.2000.0480115.Google Scholar
Whalley, W.R. and Mullins, C.E., (1991) Effect of saturating cation on tactoids size distribution in bentonite suspensions Clay Minerals 26 11–17 10.1180/claymin.1991.026.1.02.Google Scholar
Weiner, W.B. Tscharnuter, W.W. Karasikov, N. and Proveder, T., (1998) Improvements in accuracy and speed using the time-of-transition method and dynamic image analysis for particle sizing Particle Size Distribution III. Assessment and Characterization Washington, D.C. American Chemical Society 88–102 10.1021/bk-1998-0693.ch008.Google Scholar
Yariv, S., Schrader, M.E. and Loevb, G., (1992) Wettability of clay minerals Modern Approaches to Wettability: Theory and Applications New York Plenum Press 279–326 10.1007/978-1-4899-1176-6_11.Google Scholar
Yariv, S., (1992) The effect of tetrahedral substitution of Si by Al on the surface acidity of the oxygen plane of clay minerals International Reviews in Physical Chemistry 11 345–375 10.1080/01442359209353275.Google Scholar
Yariv, S. Ovadyahu, D. Nasser, A. Shuali, U. and Lahav, N., (1992) Thermal analysis study of heat of dehydration of tributylammonium smectites Thermochimica Acta 207 103–113 10.1016/0040-6031(92)80128-J.Google Scholar