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Investigating the Anisotropic Features of Particle Orientation in Synthetic Swelling Clay Porous Media

Published online by Cambridge University Press:  01 January 2024

Fabien Hubert ,
Isabelle Bihannic ,
Dimitri Prêt ,
Emmanuel Tertre ,
Benoit Nauleau ,
Manuel Pelletier ,
Bruno Demé  and
Eric Ferrage
Fabien Hubert*
Affiliation:
Université de Poitiers, CNRS IC2MP-HydrASA UMR 7285, 86022 Poitiers cedex, France
Isabelle Bihannic
Affiliation:
CNRS, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR7360, Vandoeuvre lès Nancy, F-54500, France Université de Lorraine, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR7360, Vandoeuvre lès Nancy, F-54500, France
Dimitri Prêt
Affiliation:
Université de Poitiers, CNRS IC2MP-HydrASA UMR 7285, 86022 Poitiers cedex, France
Emmanuel Tertre
Affiliation:
Université de Poitiers, CNRS IC2MP-HydrASA UMR 7285, 86022 Poitiers cedex, France
Benoit Nauleau
Affiliation:
Université de Poitiers, CNRS IC2MP-HydrASA UMR 7285, 86022 Poitiers cedex, France
Manuel Pelletier
Affiliation:
CNRS, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR7360, Vandoeuvre lès Nancy, F-54500, France Université de Lorraine, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR7360, Vandoeuvre lès Nancy, F-54500, France
Bruno Demé
Affiliation:
Institut Laue-Langevin, 6 rue Jules Horowitz, BP156, F-38042 Grenoble, France
Eric Ferrage
Affiliation:
Université de Poitiers, CNRS IC2MP-HydrASA UMR 7285, 86022 Poitiers cedex, France
*
*E-mail address of corresponding author: [email protected]
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Abstract

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The present study investigated the anisotropy in the orientation of particles in synthetic swelling clay media prepared from the sedimentation of particle-sized fractions of vermiculite. The different size fractions (<0.1, 0.1–0.2, 1–2, and 10–20 μm) were chosen because they represent the wide range of particle sizes of swelling clay minerals encountered in natural environments. Small-angle neutron scattering (SANS) and neutron diffraction measurements allowed the characteristic scattering/diffraction features to be derived and the quantitative information about the particle orientation distributions along two directions with respect to the sedimentation plane to be extracted. The results obtained confirmed that the increase in particle size was associated with the development of a random orientation for the particles, whereas the hydration state had a negligible impact on the organization of the porous media. For finer vermiculite particles, the rocking curves demonstrated an anisotropy of the systems that is similar to those reported previously on natural montmorillonite minerals. This result suggests that the location of the layer charge has little or no impact on the anisotropy features of particle orientation. For the coarsest fraction (10–20 μm), quantitative information about the particle orientation revealed that the relative proportion of the isotropic contribution represents up to 85% of the material. The anisotropy in the 2D SANS patterns revealed a pore-network anisotropy that was consistent with the particle size.

Keywords

DehydrationHydrationParticle OrientationRocking CurveSmall-angle Neutron Scattering
Type
Article
Information
Clays and Clay Minerals , Volume 61 , Issue 5 , October 2013 , pp. 397 - 415
Copyright
Copyright © Clay Minerals Society 2013

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