Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-23T08:08:17.478Z Has data issue: false hasContentIssue false
  • English
  • Français

Inverse Gas Chromatography Study of Modified Smectite Surfaces

Published online by Cambridge University Press:  28 February 2024

Teresa J. Bandosz ,
Jacek Jagiełło ,
Brannon Andersen  and
James A. Schwarz
Teresa J. Bandosz
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
Jacek Jagiełło*
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
Brannon Andersen
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190 Department of Geology, Heroy Geology Laboratory, Syracuse University
James A. Schwarz*
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
*
1Permanent address: Institute of Energochemistry of Coal and Physicochemistry of Sorbents, University of Mining and Metallurgy, 30-059 Kraków, Poland.
3Author to whom correspondence should be addressed.
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Inverse gas chromatography at infinite dilution, employing alkanes and alkenes as probes, has been used to characterize the surface properties of a series of smectites of varying chemical composition. The results of this study show that the acidic centers and the interlayer distances have a great influence on the specific interaction of the smectite surface with π-bonds of alkenes. High values of the specific interaction parameter, ɛπ, are caused by the existence of strong acidic centers that are connected with interlayer cations as well as with the chemical structure of the mineral sheets. On the other hand, alkanes, whose interaction with the smectites is predominantly dispersive, are unaffected by changes in the clays’ composition and/or structure.

Keywords

SmectiteIntercalationInverse gas chromatographyAlkane and alkene sorptionSurface aciditySurface energy
Type
Research Article
Information
Clays and Clay Minerals , Volume 40 , Issue 3 , June 1992 , pp. 306 - 310
Copyright
Copyright © 1992, The Clay Minerals Society

References

Ashan, T., Colenutt, B. A. and Sing, K. S. W., Gas chromatography of pure and surface modified precipitated calcium carbonate Journal of Chromatography 1989 479 17 – 25 10.1016/S0021-9673(01)83313-6.Google Scholar
Barrer, R. M., Zeolites and Clay Minerals as Sorbents and Molecular Sieves 1978 London Academic Press.Google Scholar
Belyakova, L. D., Kiselev, A. V. and Soloyan, G. A., Specificity of adsorption and chromatographic separation of some cyclic olefins and aromatic hydrocarbons on barium sulfate Chromatographia 1970 3 254 – 259 10.1007/BF02263690.Google Scholar
Brindley, G. W. and Kao, C.-C., Formation, composition and properties of hydroxy-Al- and hydroxy-Mg-montmorillonite Clays & Clay Minerals 1980 28 434 – 443.CrossRefGoogle Scholar
Brindley, G. W. and Sempels, R. E., Preparation and properties of some hydroxy-aluminum beidellites Clay Miner. 1977 12 229 – 236 10.1180/claymin.1977.012.3.05.CrossRefGoogle Scholar
Brindley, G. W. and Yamanaka, S., A study of hydroxy-chromium montmorillonites and the form of the hydroxy-chromium polymers Amer. Miner. 1979 64 830 – 835.Google Scholar
Diddams, A., Thomas, J. T., Jones, W., Ballantine, J. A. and Pumel, I. M., Synthesis, characterization, and catalytic activity of beidellite-montmorillonite layered silicas and their pillared analogues J. Chem. Soc. 1984 1340 – 1342.CrossRefGoogle Scholar
Dorris, G. M. and Gray, D. G., Adsorption of n-alkanes at zero surface coverage on cellulose paper and wood fibres J. Colloid Interface Sci. 1980 77 353 – 362 10.1016/0021-9797(80)90304-5.Google Scholar
Gilbert, S. G., (1984) Advances in Chromatography, Vol. 23: Giddings, J. C., Grushka, E., Cazes, J., Brown, P. R., eds., M. Dekker, New York.Google Scholar
Jagiełło, J., Bandosz, T. J. and Schwarz, J. A., Application of inverse gas chromatography at infinite dilution to study the effects of oxidation of activated carbons Carbon 1992 30 63 – 69 10.1016/0008-6223(92)90107-8.CrossRefGoogle Scholar
Kikutchi, E., Matsuda, T U I and Morita, Y., Conversion of trimethylbenzenes over montmorillonites pillared by aluminium and zirconium oxides Appl. Catal. 1985 16 401 – 410 10.1016/S0166-9834(00)84402-4.CrossRefGoogle Scholar
Kiselev, A. V., (1967) Advances in Chromatography: Giddings, J. C., and Keller, R. A., eds., M. Dekker, New York.Google Scholar
Kiselev, A. V. and Yashin, Y. I., Gas Adsorption Chromatography 1969 New York Plenum Press 10.1007/978-1-4899-6503-5.Google Scholar
Lahav, M., Shani, U. and Shabtai, J., Cross-linked smectites. I. Synthesis and properties of hydroxy-aluminum-montmorillonite Clays & Clay Minerals 1978 26 107 – 115 10.1346/CCMN.1978.0260205.Google Scholar
Ligner, G., Sidqi, M., Jagietto, J., Balard, H. and Papirer, E., Characterization of specific interactions capacity of solid surfaces by adsorption of alkanes and alkenes. Part II: Adsorption on crystalline silica layer surfaces Chromatographia 1990 29 35 – 38 10.1007/BF02261136.Google Scholar
Occelli, M. L. and Tindwa, P. M., Physicochemical properties of montmorillonite interlayered with cationic oxyaluminium pillars Clays & Clay Minerals 1983 31 22 – 28 10.1346/CCMN.1983.0310104.Google Scholar
Pinnavaia, T. J., Intercalated clay catalysts Science 1983 220 365 – 371 10.1126/science.220.4595.365.CrossRefGoogle ScholarPubMed
Sidqi, M., Ligner, G., Jagietto, J., Balard, H. and Papirer, E., Characterization of specific interaction capacity of solid surfaces by adsorption of alkanes and alkenes. Part I: Adsorption on open surface Chromatographia 1989 28 588 – 592 10.1007/BF02260683.Google Scholar
Vaughan, D E W Lussier, R. G. and Magee, J. S. Jr., Pillared interlayered clay materials useful as catalysts and sorbents U.S. Patent 1979.Google Scholar
Yamanaka, S. and Brindley, G. W., High surface area solids obtained by reaction of montmorillonite with zirconyl chloride Clays & Clay Minerals 1979 27 119 – 124 10.1346/CCMN.1979.0270207.Google Scholar
Yamanaka, S., Tadahiro, D., Sako, S. and Hattori, M., High surface area solids obtained by intercalation of iron oxide pillars in montmorillonite Mat. Res. Bull. 1984 19 161 10.1016/0025-5408(84)90086-2.Google Scholar
Zyła, M. and Bandosz, T., Montmorillonite from Milowice intercalated with hydroxy-aluminum oligocations as vapour and gas adsorbent Min. Polon. 1987 18 39 – 50.Google Scholar