Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-23T02:31:40.440Z Has data issue: false hasContentIssue false
  • English
  • Français

The Interaction of Polysaccharides with Silver Hill Illite

Published online by Cambridge University Press:  28 February 2024

Baohua Gu  and
Harvey E. Doner
Baohua Gu
Affiliation:
Department of Soil Science, University of California, Berkeley, California 94720
Harvey E. Doner
Affiliation:
Department of Soil Science, University of California, Berkeley, California 94720
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The clay-polysaccharide interaction is of practical importance in the formation and stabilization of soil aggregates. This study examined the adsorption of three synthetic polysaccharides (PSS) and one soil PSS on Silver Hill illite. The adsorption of PSS was influenced by both the adsorbed cations on the adsorbents and the charge characteristics of the polymers. The adsorbed cations formed different surface complexes with the clay surfaces, with varying ability to screen the surface negative charge and thereby influenced the adsorption of charged polymers. Na-illite adsorbed substantially higher amounts of the cationic PSS, but lower amounts of the anionic PSS, than hydroxy-Al illite. The adsorption of the nonionic PSS was, however, little influenced by those adsorbed cations. The adsorption of the soil PSS resembled that of anionic PSS. However, it yielded linear adsorption isotherms due to the heterogeneous nature of the soil PSS. The adsorption of the three synthetic PSS on Na-illite was in the general order: cationic > nonionic > anionic, confirming that electrostatic forces played a role in the adsorption of charged polymers. pH and ionic strength influenced the adsorption of the charged PSS, because of their influences on the charge characteristics of both the polymer and the clay, and on polymer conformation. This study indicates that surface charge properties of both clays and organic polymers and the presence of polyvalent cations in the system are important factors influencing the complexation between soil clays and organic constituents.

Keywords

AdsorptionIlliteIonic strengthpHPolysaccharidesPolyvalent cations
Type
Research Article
Information
Clays and Clay Minerals , Volume 40 , Issue 2 , April 1992 , pp. 151 - 156
Copyright
Copyright © 1992, The Clay Minerals Society

References

Aly, S. M. and Letey, J., Polymer and water quality effects on flocculation of montmorillonite Soil Sci. Soc. Am. J. 1988 52 1453 – 1458 10.2136/sssaj1988.03615995005200050047x.CrossRefGoogle Scholar
Bartoli, F., Philippy, R. and Burtin, G., Aggregation in soils with small amounts of swelling clays. I. Aggregate stability J. Soil Sci. 1988 39 593 – 616 10.1111/j.1365-2389.1988.tb01243.x.CrossRefGoogle Scholar
Chaney, K. and Swift, R. S., Studies on aggregate stability. I. Techniques for reforming soil aggregates J. Soil Sci. 1986 37 329 – 335 10.1111/j.1365-2389.1986.tb00035.x.CrossRefGoogle Scholar
Chenu, C., Pons, C. H., Robert, M., Schultz, L. G., van Olphen, H. and Mumpton, F. A., Interaction of kaolinite and montmorillonite with neutral polysaccharides Proc. Intl. Clay Conf., Denver 1985 1987 375 – 381.Google Scholar
Cheshire, M. V., Nature and Origin of Carbohydrates in Soils 1979 London Academic Press 68 – 124.Google Scholar
Cheshire, M. V. and Mundie, C. M., The fractionation of soil polysaccharide by electrofocusing J. Soil Sci. 1986 37 567 – 575 10.1111/j.1365-2389.1986.tb00388.x.CrossRefGoogle Scholar
Clapp, C. E. and Emerson, W. W., Reactions between Ca-montmorillonite and polysaccharides Soil Sci. 1972 114 210 – 216 10.1097/00010694-197209000-00008.CrossRefGoogle Scholar
Cohen Stuart, M. A., Scheutjens, J M H M and Fleer, G. J., Polydispersity effects and the interpretation of polymer adsorption isotherms J. Polymer Sci. 1980 18 559 – 573.Google Scholar
Finch, P., Hayes, M H B and Stacey, M., Studies on soil polysaccharides and their interactions with clay preparations Intl. Soil Sci. Soc. Trans. Commissions: II and IV 1967 Scotland Aberdeen 19 – 32.Google Scholar
Gill, R I S and Herrington, T. M., The effect of surface charge on the flocculation of kaolin suspensions with cationic Polyacrylamides of varying molar mass but similar cationic character Coll. Surf. 1987 25 297 – 310 10.1016/0166-6622(87)80310-4.CrossRefGoogle Scholar
Gill, R I S and Herrington, T. M., The flocculation of kaolin suspensions using polyethylenimine and cationic Polyacrylamides of the same molar mass but different charge density Coll. Surf. 1987 28 41 – 52 10.1016/0166-6622(87)80165-8.CrossRefGoogle Scholar
Gu, B., Interactive effects of hydroxy-Al polycations, polysaccharides and humic acid on soil/clay suspension and aggregate stability 1991 Berkeley, California Doctoral dissertation, University of California 38 – 61.Google Scholar
Gu, B. and Doner, H. E., Adsorption of hydroxy-Al polycations and destabilization of illite and montmorillonite suspensions Clays & Clay Minerals 1990 38 493 – 500 10.1346/CCMN.1990.0380505.CrossRefGoogle Scholar
Lowe, L. E., Fractionation of acid-soluble components of soil organic matter using PVP Can. J. Soil Sci. 1975 55 109 – 126.CrossRefGoogle Scholar
Lowe, L. E., Monosaccharide distribution in selected coniferous forest humus layers in British Columbia and its relationship to vegetation and degree of decomposition Can. J. Soil Sci. 1978 58 19 – 25 10.4141/cjss78-002.CrossRefGoogle Scholar
Markovitz, H. and Kimball, G. E., The effect of salts on the viscosity of solutions of polyacrylic acid J. Coll. Sci. 1950 5 115 – 139 10.1016/0095-8522(50)90014-6.CrossRefGoogle Scholar
Mitchell, A. R., Polyacrylamide application in irrigation water to increase infiltration Soil Sci. 1986 141 353 – 358 10.1097/00010694-198605000-00010.CrossRefGoogle Scholar
Mortensen, J. L., Adsorption of hydrolyzed polysaccharide on kaolinite: II. Effect of solution electrolytes Soil Sci. Soc. Amer. Proc. 1959 23 199 – 202 10.2136/sssaj1959.03615995002300030014x.CrossRefGoogle Scholar
Nadler, A. and Letey, J., Organic polyanions’ effect on aggregation of structurally disrupted soil Soil Sci. 1989 148 346 – 354 10.1097/00010694-198911000-00005.CrossRefGoogle Scholar
Olness, A. and Clapp, C. E., Influence of polysaccharide structure on dextran adsorption by montmorillonite Soil Biol. Biochem. 1975 7 113 – 118 10.1016/0038-0717(75)90008-5.CrossRefGoogle Scholar
Parfitt, R. L., Adsorption of charged sugars by montmorillonite Soil Sci. 1972 113 417 – 421 10.1097/00010694-197206000-00005.CrossRefGoogle Scholar
Parfitt, R. L. and Greenland, D. J., Adsorption of polysaccharide by montmorillonite Soil Sci. Soc. Amer. Proc. 1970 34 862 – 866 10.2136/sssaj1970.03615995003400060016x.CrossRefGoogle Scholar
Reid, J. B., Goss, M. J. and Robertson, P. D., Relationship between the decreases in soil stability affected by the growth of maize roots and changes in organically bound iron and aluminum J. Soil Sci. 1982 33 397 – 410 10.1111/j.1365-2389.1982.tb01776.x.CrossRefGoogle Scholar
Ruehrwein, R. A. and Ward, D. W., Mechanism of clay aggregation by polyelectrolytes Soil Sci. 1952 73 485 – 492 10.1097/00010694-195206000-00007.CrossRefGoogle Scholar
Saini, G. R. and MacLean, A. A., Adsorption-flocculation reactions of soil polysaccharides with kaolinite Soil Sci. Soc. Amer. Proc. 1966 30 697 – 699 10.2136/sssaj1966.03615995003000060015x.CrossRefGoogle Scholar
Sposito, G., The Surface Chemistry of Soils 1984 New York Oxford Univ. Press 113 – 122.Google Scholar
Sposito, G., Notes, W. and Güven, N., The diffuse-ion swarm near smectite particles suspended in 1:1 electrolyte solutions Rheology of Clay/Water Systems 1989 Sacramento, California Clay Minerals Society 1 – 30.Google Scholar
Theng, B. K. G., Interactions between montmorillonite and fulvic acid Geoderma 1976 15 243 – 251 10.1016/0016-7061(76)90078-1.CrossRefGoogle Scholar
Theng, B. K. G., Formation and Properties of Clay-Polymer Complexes 1979 Amsterdam Elsevier 243 – 273.Google Scholar
Theng, B. K. G., Clay-polymer interactions: Summary and perspectives Clays & Clay Minerals 1982 30 1 – 10 10.1346/CCMN.1982.0300101.CrossRefGoogle Scholar
Wallace, A., A polysaccharide (guar) as a soil conditioner Soil Sci. 1986 141 371 – 373 10.1097/00010694-198605000-00014.CrossRefGoogle Scholar