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Influence of Mn(III) availability on the phase transformation from layered buserite to tunnel-structured todorokite

Published online by Cambridge University Press:  01 January 2024

Haojie Cui ,
Xiangwen Liu ,
Wenfeng Tan ,
Xionghan Feng ,
Fan Liu  and
Huada Daniel Ruan
Haojie Cui
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, People's, Republic of China
Xiangwen Liu
Affiliation:
China University of Geosciences, Wuhan 430074, People's, Republic of China
Wenfeng Tan
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, People's, Republic of China
Xionghan Feng*
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, People's, Republic of China
Fan Liu
Affiliation:
Key Laboratory of Subtropical Agricultural Resources and Environment, Ministry of Agriculture, Huazhong Agricultural University, Wuhan 430070, People's, Republic of China
Huada Daniel Ruan
Affiliation:
Environmental Science Program, Division of Science and Technology, United International College, Beijing Normal University-Hong Kong Baptist University, Zhuhai 519085, People's, Republic of China
*
* E-mail address of corresponding author: [email protected]
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Abstract

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Todorokite is a common Mn oxide mineral in terrestrial and ocean-floor environments, and it is commonly synthesized from layered Na-buserite. Pyrophosphate, which is known to form strong complexes with Mn(III) at a pH range of 1–8, was added to a suspension of Na-buserite in order to sequester the available Mn(III) in Na-buserite. No Mn(III)-pyrophosphate complex was formed in solution at pH 10, and the treated Na-buserites were converted completely to todorokite. Significant transformation reductions were observed when Na-buserite was treated with pyrophosphate solution at pH 7. The presence of Mn(III) within the MnO6 octahedral sheets of Na-buserite is critical for the transformation from layered buserite to tunnel-structured todorokite at atmospheric pressure. At lower pH, two effects are combined to reduce the amount of Mn(III) in the layers: (1) the complexing power of pyrophosphate is increased; and (2) the transformation from Na-buserite to H-birnessite, which is concomitant with the migration of Mn(III) from layers to the interlayer, and the partial disproportionation of Mn(III). The results showed that Mn(III) played a key role in the transformation of layered Na-buserite to tunnel-structured todorokite at atmospheric pressure.

Keywords

BuseriteMn OxideTodorokiteTransformationRefluxing
Type
Article
Information
Clays and Clay Minerals , Volume 56 , Issue 4 , August 2008 , pp. 397 - 403
Copyright
Copyright © 2008, The Clay Minerals Society

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