Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-26T16:13:12.474Z Has data issue: false hasContentIssue false
  • English
  • Français

Influence of Hydrazine on the Vibrational Modes of Kaolinite

Published online by Cambridge University Press:  02 April 2024

C. T. Johnston  and
D. A. Stone
C. T. Johnston
Affiliation:
Department of Soil Science, University of Florida, Gainesville, Florida 32611
D. A. Stone
Affiliation:
HQ AFESC/RDVS, Tyndall AFB, Florida 32403
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Raman and Fourier-transform-infrared (FTIR) spectroscopic methods and X-ray powder diffraction (XRD) techniques have been used to study the influence of hydrazine on the vibrational modes of kaolinite. Strong vibrational perturbations of the OH-stretching and -deformation bands were observed in the Raman and FTIR spectra on intercalation. The intensities of the Raman- and IR-active OH-stretching bands decreased significantly upon intercalation; the intensities of the Raman bands were reduced to a greater extent than the IR bands. The deformation bands were also strongly perturbed by the presence of hydrazine in the interlamellar region. Upon evacuation of the intercalate, two new bands at 3628 and 912 cm−1 were noted, indicating the presence of a different structural conformation of the complex under vacuum. Similar results were obtained using XRD, on evacuation of the kaolinite-hy-drazine (KH) complex the d(001) value decreased from 10.4 to 9.6 Å. Partial collapse of the intercalate from 10.4 to 9.6 Å was probably due to keying of the -NH2 moiety of hydrazine into the siloxane ditrigonal cavity, as indicated by a blue-shift of the inner-OH band from 3620 to 3628 cm-1. Structural OH vibrational modes may therefore be useful probes of amine interactions with clay mineral surfaces.

Keywords

Fourier-transform infrared spectroscopyHydrazineKaoliniteOH-vibration modesRaman spectroscopyX-ray powder diffraction
Type
Research Article
Information
Clays and Clay Minerals , Volume 38 , Issue 2 , April 1990 , pp. 121 - 128
Copyright
Copyright © 1990, The Clay Minerals Society

References

Adams, J. M. and Waltl, G., 1980 Thermal-decomposition of a kaolinite dimethylsulfoxide intercalate Clays & Clay Minerals 28 130 – 134.CrossRefGoogle Scholar
Anton, O. and Rouxhet, P. G., 1977 Note on the intercalation of kaolinite, dickite, and halloysite by dimethylsulfoxide Clays & Clay Minerals 25 259 – 263.CrossRefGoogle Scholar
Barrios, J., Plançon, A., Cruz, M. I. and Tchoubar, C., 1977 Qualitative and quantitative study of stacking faults in a hydrazine-treated kaolinite. Relationship with the infrared spectra Clays & Clay Minerals 25 422 – 429.CrossRefGoogle Scholar
Bell, A. T., 1980 Applications of Fourier-transform infrared spectroscopy to studies of adsorbed species Vibrational Spectroscopies for Adsorbed Species 137 13 – 35.CrossRefGoogle Scholar
Bell, A. T., Yates, J. T. and Madey, T. E., 1987 Infrared spectroscopy of high-area catalytic surfaces Vibrational Spectroscopy of Molecules on Surfaces New York Plenum Press 105 – 134.CrossRefGoogle Scholar
Breen, C. and Lynch, S., 1988 Reexamination of the kinetics of the thermal desorption of dimethysulfoxide and N-methyl-formamide from a Greensplatt kaolinite Clays & Clay Minerals 36 19 – 24.CrossRefGoogle Scholar
Brindley, G. W., Kao, C., Harrison, J. L., Lipsicas, M. and Raythatha, R., 1986 Relation between structural disorder and other characteristics of kaolinites and dickites Clays & Clay Minerals 34 239 – 249.CrossRefGoogle Scholar
Costanzo, P. M. and Giese, R. F., 1985 Dehydration of synthetic hydrated kaolinites: A model for the dehydration of hallosite(10A) Clays & Clay Minerals 33 415 – 423.CrossRefGoogle Scholar
Costanzo, P. M., Giese, R. F. and Lipsicas, M., 1984 Static and dynamic structures of water in hydrated kaolinites. I. The static structure Clays & Clay Minerals 32 419 – 428.CrossRefGoogle Scholar
Costanzo, P. M., Giese, R. F., Lipsicas, M. and Straley, C., 1982 Synthesis of a quasi-stable kaolinite and heat-capacity of interlayer water Nature 296 549 – 551.CrossRefGoogle Scholar
Durig, J. R., Bush, S. F. and Mercer, E. E., 1966 Vibrational spectrum of hydrazine-d4 and a Raman study of hydrogen bonding in hydrazine J. Chem. Phys. 44 4238 – 4247.CrossRefGoogle Scholar
Fripiat, J. J. and Toussaint, F., 1963 Dehydroxylation of kaolinite. II. Conductometric measurements and infrared spectroscopy J. Phys. Chem. 67 30 – 36.CrossRefGoogle Scholar
Griffiths, P. R. and de Haseth, J. A., 1986 Fourier-Transform Infrared Spectrometry New York Wiley.Google Scholar
Johnston, C. T., Sposito, G. and Birge, R. R., 1985 Raman spectroscopic study of kaolinite in aqueous suspension Clays & Clay Minerals 33 483 – 489.CrossRefGoogle Scholar
Johnston, C. T., Sposito, G., Bocian, D. F. and Birge, R. R., 1984 Vibrational spectroscopic study of the interlamellar kaolinite-dimethylsulfoxide complex J. Phys. Chem. 88 5959 – 5964.CrossRefGoogle Scholar
Ledoux, R. L. and White, J. L., 1964 Infrared study of selective deuteration of kaolinite and halloysite at room temperature Science 145 47 – 49.CrossRefGoogle ScholarPubMed
Ledoux, R. L. and White, J. L., 1966 Infrared studies of hydrogen bonding interaction between kaolinite surfaces and intercalated potassium acetate, hydrazine, formamide, and urea J. Colloid and Interface Sciences 21 127 – 152.CrossRefGoogle Scholar
Maiti, G. C. and Freund, F., 1981 Dehydration-related proton conductivity in kaolinite Clay Miner. 16 395 – 413.CrossRefGoogle Scholar
Miyazawa, T., Shimanouchi, T. and Mizushima, S., 1958 Normal vibrations of N-methylacetamide J. Chem. Phys. 29 611 – 616.CrossRefGoogle Scholar
Olejnik, S., Aylmore, L. A. G. Posner, A. M. and Quirk, J. P., 1968 Infrared spectra of kaolin mineral-dimethyl sulfoxide complexes J. Phys. Chem. 72 241 – 249.CrossRefGoogle Scholar
Raupach, M., Barron, P. F. and Thompson, J. G., 1987 Nuclear magnetic resonance, infrared, and X-ray powder diffraction study of dimethylsulfoxide and dimethylselenoxide intercalates with kaolinite. Clays & Clay Minerals. 35 208 – 219.CrossRefGoogle Scholar
Rouxhet, D. G., Samudacheata, N., Jacobs, H. and Anton, O., 1977 Attribution of the OH-stretching bands of kaolinite Clay Miner. 12 171 – 178.CrossRefGoogle Scholar
Sposito, G., Prost, R. and Gaultier, J. P., 1983 Infrared spectroscopic study of adsorbed water on reduced-charge Na/Li montmorillonites Clays & Clay Minerals 31 9 – 16.CrossRefGoogle Scholar
Suitch, P. R. and Young, R. A., 1983 Atom positions in highly ordered kaolinite Clays & Clay Minerals 31 357 – 366.CrossRefGoogle Scholar
Thompson, J. G., 1985 Interpretation of solid state 13C and 29Si nuclear magnetic resonance spectra of kaolinite intercalates Clays & Clay Minerals 33 173 – 180.CrossRefGoogle Scholar
Thompson, J. G. and Barron, P. F., 1987 Further consideration of the 29Si nuclear magnetic resonance spectrum of kaolinite Clays & Clay Minerals 35 38 – 42.CrossRefGoogle Scholar
Thompson, J. G. and Cuff, C., 1985 Crystal structure of kaolinite: dimethylsulfoxide intercalate Clays & Clay Minerals 33 490 – 500.CrossRefGoogle Scholar
van Olphen, H. and Fripiat, J. J., 1979 Data Handbook for Clay Materials and other Non- metallic Minerals Oxford Pergamon Press.Google Scholar
Wada, K., 1967 A study of hydroxyl groups in kaolin minerals utilizing selective-deuteration and infrared spectroscopy Clay Miner. 7 51 – 61.CrossRefGoogle Scholar
Weiss, A., Thielepape, W., Goring, G., Ritter, W., Schafer, H., Rosenqvist, I. Th. and Graff-Petersen, P., 1963 Kaolinit Einlagerungs-Verbindungen Proc. Intl. Clay Conf. Stockholm Vol. 1 Oxford Pergamon Press 287 – 305.Google Scholar
White, J. L., 1968 Proton migration in kaolinite 9th Intl. Congr. of Soil Sci. Trans. 701 – 707.Google Scholar
White, J. L., Laycock, A. and Cruz, M. I., 1970 Infrared studies of proton delocalization in kaolinite Bull. Groupe. Franc. Argiles 22 157 – 165.CrossRefGoogle Scholar
Wieckowski, T. and Wiewiora, A., 1976 New approach to the problem of the interlayer bonding in kaolinite Clays & Clay Minerals 24 219 – 223.CrossRefGoogle Scholar
Wiewiora, A., Wieckowski, T. and Sokolowska, A., 1979 The Raman spectra of kaolinite sub-group minerals and of pyrophyllite Archiwum Mineralogiczne 35 5 – 14.Google Scholar